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\usepackage{graphicx} |
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\usepackage{multirow} |
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\usepackage{multicol} |
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+ |
\usepackage{epstopdf} |
| 24 |
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|
| 25 |
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\usepackage[version=3]{mhchem} % this is a great package for formatting chemical reactions |
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% \usepackage[square, comma, sort&compress]{natbib} |
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\usepackage{url} |
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\pagestyle{plain} \pagenumbering{arabic} \oddsidemargin 0.0cm |
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\evensidemargin 0.0cm \topmargin -21pt \headsep 10pt \textheight |
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< |
9.0in \textwidth 6.5in \brokenpenalty=10000 |
| 30 |
> |
9.0in \textwidth 6.5in \brokenpenalty=1110000 |
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|
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% double space list of tables and figures |
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%\AtBeginDelayedFloats{\renewcomand{\baselinestretch}{1.66}} |
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|
| 473 |
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%Evolution of surface |
| 474 |
|
\begin{figure}[H] |
| 475 |
< |
\includegraphics[width=\linewidth]{ProgressionOfDoubleLayerFormation_yellowCircle.png} |
| 475 |
> |
\includegraphics[width=\linewidth]{EPS_ProgressionOfDoubleLayerFormation.pdf} |
| 476 |
|
\caption{The Pt(557) / 50\% CO system at a sequence of times after |
| 477 |
|
initial exposure to the CO: (a) 258~ps, (b) 19~ns, (c) 31.2~ns, and |
| 478 |
|
(d) 86.1~ns. Disruption of the (557) step-edges occurs quickly. The |
| 531 |
|
|
| 532 |
|
%Diffusion graph |
| 533 |
|
\begin{figure}[H] |
| 534 |
< |
\includegraphics[width=\linewidth]{DiffusionComparison_errorXY_remade_20ns.pdf} |
| 534 |
> |
\includegraphics[width=\linewidth]{Portrait_DiffusionComparison_1.pdf} |
| 535 |
|
\caption{Diffusion constants for mobile surface atoms along directions |
| 536 |
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parallel ($\mathbf{D}_{\parallel}$) and perpendicular |
| 537 |
|
($\mathbf{D}_{\perp}$) to the (557) step-edges as a function of CO |
| 672 |
|
|
| 673 |
|
%energy graph corresponding to sketch graphic |
| 674 |
|
\begin{figure}[H] |
| 675 |
< |
\includegraphics[width=\linewidth]{stepSeparationComparison.pdf} |
| 675 |
> |
\includegraphics[width=\linewidth]{Portrait_SeparationComparison.pdf} |
| 676 |
|
\caption{The energy curves directly correspond to the labeled model |
| 677 |
|
surface in Figure \ref{fig:SketchGraphic}. All energy curves are relative |
| 678 |
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to their initial configuration so the energy of a and h do not have the |
| 705 |
|
|
| 706 |
|
%lambda progression of Pt -> shoving its way into the step |
| 707 |
|
\begin{figure}[H] |
| 708 |
< |
\includegraphics[width=\linewidth]{lambdaProgression_atopCO_withLambda.png} |
| 708 |
> |
\includegraphics[width=\linewidth]{EPS_rxnCoord.pdf} |
| 709 |
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\caption{ Various points along a reaction coordinate are displayed in the figure. |
| 710 |
|
The mechanism of edge traversal is examined in the presence of CO. The approximate |
| 711 |
|
barrier for the displayed process is 20~kcal/mol. However, the $\Delta E$ of this process |
| 749 |
|
|
| 750 |
|
%breaking of the double layer upon removal of CO |
| 751 |
|
\begin{figure}[H] |
| 752 |
< |
\includegraphics[width=\linewidth]{doubleLayerBreaking_greenBlue_whiteLetters.png} |
| 752 |
> |
\includegraphics[width=\linewidth]{EPS_doubleLayerBreaking.pdf} |
| 753 |
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\caption{(A) 0~ps, (B) 100~ps, (C) 1~ns, after the removal of CO. The presence of the CO |
| 754 |
|
helped maintain the stability of the double layer and its microfaceting of the double layer |
| 755 |
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into a (111) configuration. This microfacet immediately reverts to the original (100) step |
