| 540 |
|
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% |
| 541 |
|
% RESIDENCE TIME |
| 542 |
|
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% |
| 543 |
< |
\subsection{Mobility for solvent in the interfacial layer} |
| 543 |
> |
\subsection{Mobility of solvent in the interfacial layer} |
| 544 |
|
|
| 545 |
|
We use a simple survival correlation function, $C(t)$, to quantify the |
| 546 |
|
residence time of a solvent molecule in the long thiolate chain |
| 560 |
|
the rate at which solvent molecules entangled in the thiolate layer |
| 561 |
|
can escape into the bulk. As $k_{escape} \rightarrow \infty$, the |
| 562 |
|
solvent has become permanently trapped in the thiolate layer. In |
| 563 |
< |
figure \ref{figure:Gstacks} we show that interfacial solvent mobility |
| 563 |
> |
figure \ref{fig:Gstacks} we show that interfacial solvent mobility |
| 564 |
|
decreases as the percentage of long thiolate chains increases. |
| 565 |
|
|
| 566 |
|
\begin{figure} |