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Hull. This was done at pressures of 1, 2, 5, 10, 20, 50, 100 and 200 atm |
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in order to observe the effects of pressure on the ordering of water |
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ordering at the surface. In Fig. \ref{fig:RhoR} we show the density |
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< |
of water adjacent to the surface as a function of pressure, as well as |
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< |
the orientational ordering of water at the surface of the |
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nanoparticle. |
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of water adjacent to the surface and |
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the density of gold at the surface as a function of pressure. |
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|
|
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\begin{figure} |
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Higher applied pressures de-structure the outermost layer of the gold nanoparticle and the water at the metal/water interface. Simulations at increased pressures have greater overlap of the gold and water densities, indicating a less well-defined interfacial surface. |
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|
|
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\caption{Higher applied pressures de-structure both the gold nanoparticle and water at the metal/water interface.} |
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\begin{figure} |
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\includegraphics[width=\linewidth]{RhoR} |
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\caption{Densities of gold and water at the nanoparticle surface. Higher applied pressures de-structure both the gold nanoparticle surface and water at the metal/water interface.} |
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\label{fig:RhoR} |
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\end{figure} |
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|
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At higher pressures, problems with the gold - water interaction |
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Indeed, at even higher pressures, problems with the gold - water interaction |
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|
potential became apparent. The model we are using (due to Spohr) was |
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intended for relatively low pressures; it utilizes both shifted Morse |
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and repulsive Morse potentials to model the Au/O and Au/H |