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3605 y(tional)25 b(e\016ciency)h(is)g(esp)r(ecially)f(delicate,)h(and)f |
| 1372 |
< |
(it)h(has)g(resulted)-150 3700 y(in)31 b(a)g(v)-5 b(ariet)n(y)31 |
| 1373 |
< |
b(of)g(di\013eren)n(t)g(w)n(ater)f(mo)r(dels.)1238 3670 |
| 1374 |
< |
y Fn(1{3)1373 3700 y Fu(Man)n(y)g(of)h(these)-150 3796 |
| 1371 |
> |
3610 y(tional)25 b(e\016ciency)h(is)g(esp)r(ecially)f(delicate,)h(and)f |
| 1372 |
> |
(it)h(has)g(resulted)-150 3706 y(in)31 b(a)g(v)-5 b(ariet)n(y)31 |
| 1373 |
> |
b(of)g(di\013eren)n(t)g(w)n(ater)f(mo)r(dels.)1238 3676 |
| 1374 |
> |
y Fn(1{3)1373 3706 y Fu(Man)n(y)g(of)h(these)-150 3801 |
| 1375 |
|
y(mo)r(dels)22 b(get)g(sp)r(eci\014c)g(prop)r(erties)f(correct)f(or)h |
| 1376 |
< |
(b)r(etter)h(than)g(their)-150 3891 y(predecessors,)38 |
| 1376 |
> |
(b)r(etter)h(than)g(their)-150 3897 y(predecessors,)38 |
| 1377 |
|
b(but)h(this)f(is)g(often)g(at)g(a)f(cost)h(of)g(some)f(other)-150 |
| 1378 |
< |
3987 y(prop)r(erties)g(or)g(of)g(computer)g(time.)68 |
| 1379 |
< |
b(As)38 b(an)f(example,)j(com-)-150 4082 y(pare)27 b(TIP3P)f(or)h |
| 1378 |
> |
3992 y(prop)r(erties)g(or)g(of)g(computer)g(time.)68 |
| 1379 |
> |
b(As)38 b(an)f(example,)j(com-)-150 4088 y(pare)27 b(TIP3P)f(or)h |
| 1380 |
|
(TIP4P)f(to)h(TIP5P)-7 b(.)26 b(TIP5P)h(succeeds)g(in)g(im-)-150 |
| 1381 |
< |
4178 y(pro)n(ving)j(the)j(structural)e(and)g(transp)r(ort)g(prop)r |
| 1382 |
< |
(erties)g(o)n(v)n(er)f(its)-150 4273 y(predecessors,)36 |
| 1381 |
> |
4183 y(pro)n(ving)j(the)j(structural)e(and)g(transp)r(ort)g(prop)r |
| 1382 |
> |
(erties)g(o)n(v)n(er)f(its)-150 4279 y(predecessors,)36 |
| 1383 |
|
b(y)n(et)g(this)g(comes)g(at)g(a)f(greater)g(than)h(50\045)f(in-)-150 |
| 1384 |
< |
4369 y(crease)30 b(in)h(computational)g(cost.)919 4339 |
| 1385 |
< |
y Fn(3)o(,4)1039 4369 y Fu(One)f(recen)n(tly)h(dev)n(elop)r(ed)-150 |
| 1386 |
< |
4464 y(mo)r(del)36 b(that)g(succeeds)f(in)g(b)r(oth)h(retaining)f |
| 1387 |
< |
(accuracy)f(of)h(sys-)-150 4560 y(tem)j(prop)r(erties)e(and)i |
| 1388 |
< |
(simplifying)f(calculations)f(to)i(increase)-150 4655 |
| 1384 |
> |
4374 y(crease)30 b(in)h(computational)g(cost.)919 4344 |
| 1385 |
> |
y Fn(3)o(,4)1039 4374 y Fu(One)f(recen)n(tly)h(dev)n(elop)r(ed)-150 |
| 1386 |
> |
4470 y(mo)r(del)36 b(that)g(succeeds)f(in)g(b)r(oth)h(retaining)f |
| 1387 |
> |
(accuracy)f(of)h(sys-)-150 4565 y(tem)j(prop)r(erties)e(and)i |
| 1388 |
> |
(simplifying)f(calculations)f(to)i(increase)-150 4661 |
| 1389 |
|
y(computational)30 b(e\016ciency)g(is)h(the)f(Soft)h(Stic)n(ky)g(Dip)r |
| 1390 |
< |
(ole)f(w)n(ater)-150 4751 y(mo)r(del.)92 4720 y Fn(5)-67 |
| 1391 |
< |
4846 y Fu(The)e(Soft)h(Stic)n(ky)f(Dip)r(ole)h(\(SSD\))g(w)n(ater)f(mo) |
| 1392 |
< |
r(del)g(w)n(as)f(dev)n(el-)-150 4942 y(op)r(ed)37 b(b)n(y)h(Ic)n(hiy)n |
| 1390 |
> |
(ole)f(w)n(ater)-150 4756 y(mo)r(del.)92 4726 y Fn(5)-67 |
| 1391 |
> |
4852 y Fu(The)e(Soft)h(Stic)n(ky)f(Dip)r(ole)h(\(SSD\))g(w)n(ater)f(mo) |
| 1392 |
> |
r(del)g(w)n(as)f(dev)n(el-)-150 4947 y(op)r(ed)37 b(b)n(y)h(Ic)n(hiy)n |
| 1393 |
|
(e)e Fm(et)j(al.)67 b Fu(as)37 b(a)g(mo)r(di\014ed)h(form)f(of)h(the)f |
| 1394 |
< |
(hard-)-150 5037 y(sphere)48 b(w)n(ater)g(mo)r(del)h(prop)r(osed)e(b)n |
| 1395 |
< |
(y)i(Bratk)n(o,)j(Blum,)j(and)p -150 5206 300 4 v -59 |
| 1396 |
< |
5384 a Fl(\003)-23 5407 y Fk(Corresp)r(onding)24 b(author.)55 |
| 1397 |
< |
b(Electronic)25 b(mail:)k(gezelter@nd.edu)2042 2150 y |
| 1398 |
< |
Fu(Luzar.)2275 2120 y Fn(6)o(,7)2403 2150 y Fu(SSD)42 |
| 1394 |
> |
(hard-)-150 5043 y(sphere)48 b(w)n(ater)g(mo)r(del)h(prop)r(osed)e(b)n |
| 1395 |
> |
(y)i(Bratk)n(o,)j(Blum,)j(and)p -150 5212 300 4 v -59 |
| 1396 |
> |
5390 a Fl(\003)-23 5413 y Fk(Corresp)r(onding)24 b(author.)55 |
| 1397 |
> |
b(Electronic)25 b(mail:)k(gezelter@nd.edu)2042 2156 y |
| 1398 |
> |
Fu(Luzar.)2275 2126 y Fn(6)o(,7)2403 2156 y Fu(SSD)42 |
| 1399 |
|
b(consists)d(of)i(a)f(single)f(p)r(oin)n(t)i(dip)r(ole)g(with)g(a)2042 |
| 1400 |
< |
2246 y(Lennard-Jones)35 b(core)i(and)h(a)f(stic)n(ky)g(p)r(oten)n(tial) |
| 1401 |
< |
h(that)g(directs)2042 2341 y(the)27 b(particles)f(to)g(assume)g(the)h |
| 1402 |
< |
(prop)r(er)e(h)n(ydrogen)g(b)r(ond)i(orien-)2042 2437 |
| 1400 |
> |
2251 y(Lennard-Jones)35 b(core)i(and)h(a)f(stic)n(ky)g(p)r(oten)n(tial) |
| 1401 |
> |
h(that)g(directs)2042 2347 y(the)27 b(particles)f(to)g(assume)g(the)h |
| 1402 |
> |
(prop)r(er)e(h)n(ydrogen)g(b)r(ond)i(orien-)2042 2442 |
| 1403 |
|
y(tation)32 b(in)h(the)g(\014rst)f(solv)-5 b(ation)31 |
| 1404 |
|
b(shell.)52 b(Th)n(us,)33 b(the)g(in)n(teraction)2042 |
| 1405 |
< |
2532 y(b)r(et)n(w)n(een)24 b(t)n(w)n(o)f(SSD)i(w)n(ater)d(molecules)i |
| 1405 |
> |
2538 y(b)r(et)n(w)n(een)24 b(t)n(w)n(o)f(SSD)i(w)n(ater)d(molecules)i |
| 1406 |
|
Fm(i)33 b Fu(and)24 b Fm(j)36 b Fu(is)24 b(giv)n(en)f(b)n(y)h(the)2042 |
| 1407 |
< |
2628 y(p)r(oten)n(tial)2083 2815 y Fj(u)2131 2827 y Fi(ij)2212 |
| 1408 |
< |
2815 y Fu(=)f Fj(u)2348 2781 y Fi(LJ)2348 2836 y(ij)2439 |
| 1409 |
< |
2815 y Fu(\()p Fj(r)2508 2827 y Fi(ij)2568 2815 y Fu(\))29 |
| 1410 |
< |
b(+)7 b Fj(u)2749 2775 y Fi(dp)2749 2838 y(ij)2822 2815 |
| 1411 |
< |
y Fu(\()p Fh(r)2893 2827 y Fi(ij)2952 2815 y Fj(;)14 |
| 1412 |
< |
b Fh(\012)3058 2827 y Fi(i)3085 2815 y Fj(;)g Fh(\012)3191 |
| 1413 |
< |
2827 y Fi(j)3226 2815 y Fu(\))30 b(+)7 b Fj(u)3408 2775 |
| 1414 |
< |
y Fi(sp)3408 2838 y(ij)3477 2815 y Fu(\()p Fh(r)3548 |
| 1415 |
< |
2827 y Fi(ij)3607 2815 y Fj(;)14 b Fh(\012)3713 2827 |
| 1416 |
< |
y Fi(i)3740 2815 y Fj(;)g Fh(\012)3846 2827 y Fi(j)3881 |
| 1417 |
< |
2815 y Fu(\))p Fj(;)42 b Fu(\(1\))2042 2994 y(where)36 |
| 1418 |
< |
b(the)i Fh(r)2483 3006 y Fi(ij)2578 2994 y Fu(is)f(the)g(p)r(osition)g |
| 1419 |
< |
(v)n(ector)f(b)r(et)n(w)n(een)h(molecules)2042 3089 y |
| 1407 |
> |
2633 y(p)r(oten)n(tial)2083 2821 y Fj(u)2131 2833 y Fi(ij)2212 |
| 1408 |
> |
2821 y Fu(=)f Fj(u)2348 2787 y Fi(LJ)2348 2841 y(ij)2439 |
| 1409 |
> |
2821 y Fu(\()p Fj(r)2508 2833 y Fi(ij)2568 2821 y Fu(\))29 |
| 1410 |
> |
b(+)7 b Fj(u)2749 2781 y Fi(dp)2749 2844 y(ij)2822 2821 |
| 1411 |
> |
y Fu(\()p Fh(r)2893 2833 y Fi(ij)2952 2821 y Fj(;)14 |
| 1412 |
> |
b Fh(\012)3058 2833 y Fi(i)3085 2821 y Fj(;)g Fh(\012)3191 |
| 1413 |
> |
2833 y Fi(j)3226 2821 y Fu(\))30 b(+)7 b Fj(u)3408 2781 |
| 1414 |
> |
y Fi(sp)3408 2844 y(ij)3477 2821 y Fu(\()p Fh(r)3548 |
| 1415 |
> |
2833 y Fi(ij)3607 2821 y Fj(;)14 b Fh(\012)3713 2833 |
| 1416 |
> |
y Fi(i)3740 2821 y Fj(;)g Fh(\012)3846 2833 y Fi(j)3881 |
| 1417 |
> |
2821 y Fu(\))p Fj(;)42 b Fu(\(1\))2042 2999 y(where)36 |
| 1418 |
> |
b(the)i Fh(r)2483 3011 y Fi(ij)2578 2999 y Fu(is)f(the)g(p)r(osition)g |
| 1419 |
> |
(v)n(ector)f(b)r(et)n(w)n(een)h(molecules)2042 3095 y |
| 1420 |
|
Fm(i)44 b Fu(and)35 b Fm(j)48 b Fu(with)36 b(magnitude)f(equal)g(to)g |
| 1421 |
< |
(the)h(distance)f Fj(r)3823 3101 y Fi(i)3851 3089 y Fj(j)5 |
| 1422 |
< |
b Fu(,)37 b(and)2042 3185 y Fh(\012)2111 3197 y Fi(i)2175 |
| 1423 |
< |
3185 y Fu(and)g Fh(\012)2415 3197 y Fi(j)2486 3185 y |
| 1421 |
> |
(the)h(distance)f Fj(r)3823 3107 y Fi(i)3851 3095 y Fj(j)5 |
| 1422 |
> |
b Fu(,)37 b(and)2042 3190 y Fh(\012)2111 3202 y Fi(i)2175 |
| 1423 |
> |
3190 y Fu(and)g Fh(\012)2415 3202 y Fi(j)2486 3190 y |
| 1424 |
|
Fu(represen)n(t)f(the)h(orien)n(tations)e(of)i(the)g(resp)r(ectiv)n(e) |
| 1425 |
< |
2042 3280 y(molecules.)47 b(The)32 b(Lennard-Jones,)e(dip)r(ole,)i(and) |
| 1426 |
< |
f(stic)n(ky)g(parts)2042 3376 y(of)c(the)h(p)r(oten)n(tial)g(are)e |
| 1425 |
> |
2042 3286 y(molecules.)47 b(The)32 b(Lennard-Jones,)e(dip)r(ole,)i(and) |
| 1426 |
> |
f(stic)n(ky)g(parts)2042 3381 y(of)c(the)h(p)r(oten)n(tial)g(are)e |
| 1427 |
|
(giving)h(b)n(y)h(the)g(follo)n(wing)e(equations,)2404 |
| 1428 |
< |
3628 y Fj(u)2452 3594 y Fi(LJ)2452 3649 y(ij)2543 3628 |
| 1429 |
< |
y Fu(\()p Fj(r)2612 3640 y Fi(ij)2671 3628 y Fu(\))e(=)e(4)p |
| 1430 |
< |
Fj(\017)2904 3486 y Fg(")2952 3511 y(\022)3046 3572 y |
| 1431 |
< |
Fj(\033)p 3023 3609 96 4 v 3023 3685 a(r)3060 3697 y |
| 1432 |
< |
Fi(ij)3129 3511 y Fg(\023)3190 3529 y Fn(12)3279 3628 |
| 1433 |
< |
y Ff(\000)3362 3511 y Fg(\022)3455 3572 y Fj(\033)p 3433 |
| 1434 |
< |
3609 V 3433 3685 a(r)3470 3697 y Fi(ij)3539 3511 y Fg(\023)3600 |
| 1435 |
< |
3529 y Fn(6)3637 3486 y Fg(#)3699 3628 y Fj(;)256 b Fu(\(2\))2398 |
| 1436 |
< |
4033 y Fj(u)2446 3993 y Fi(dp)2446 4056 y(ij)2542 4033 |
| 1437 |
< |
y Fu(=)2639 3969 y Fe(\026)2698 3989 y Fi(i)2744 3969 |
| 1438 |
< |
y Ff(\001)19 b Fe(\026)2844 3989 y Fi(j)p 2639 4014 241 |
| 1439 |
< |
4 v 2711 4090 a Fj(r)2750 4061 y Fn(3)2748 4113 y Fi(ij)2908 |
| 1440 |
< |
4033 y Ff(\000)3001 3969 y Fu(3\()p Fe(\026)3133 3989 |
| 1441 |
< |
y Fi(i)3179 3969 y Ff(\001)g Fh(r)3260 3981 y Fi(ij)3319 |
| 1442 |
< |
3969 y Fu(\)\()p Fe(\026)3442 3989 y Fi(j)3495 3969 y |
| 1443 |
< |
Ff(\001)g Fh(r)3576 3981 y Fi(ij)3635 3969 y Fu(\))p |
| 1444 |
< |
3001 4014 667 4 v 3286 4090 a Fj(r)3325 4061 y Fn(5)3323 |
| 1445 |
< |
4113 y Fi(ij)3705 4033 y Fj(;)250 b Fu(\(3\))2271 4390 |
| 1446 |
< |
y Fj(u)2319 4351 y Fi(sp)2319 4414 y(ij)2388 4390 y Fu(\()p |
| 1447 |
< |
Fh(r)2459 4402 y Fi(ij)2518 4390 y Fj(;)14 b Fh(\012)2624 |
| 1448 |
< |
4402 y Fi(i)2652 4390 y Fj(;)g Fh(\012)2757 4402 y Fi(j)2792 |
| 1449 |
< |
4390 y Fu(\))24 b(=)2945 4334 y Fj(\027)2986 4346 y Fn(0)p |
| 1450 |
< |
2945 4371 79 4 v 2964 4447 a Fu(2)3034 4390 y([)p Fj(s)p |
| 1451 |
< |
Fu(\()p Fj(r)3165 4402 y Fi(ij)3224 4390 y Fu(\))p Fj(w)r |
| 1452 |
< |
Fu(\()p Fh(r)3388 4402 y Fi(ij)3448 4390 y Fj(;)14 b |
| 1453 |
< |
Fh(\012)3554 4402 y Fi(i)3581 4390 y Fj(;)g Fh(\012)3687 |
| 1454 |
< |
4402 y Fi(j)3722 4390 y Fu(\))2954 4547 y(+)k Fj(s)3076 |
| 1455 |
< |
4513 y Ft(0)3099 4547 y Fu(\()p Fj(r)3168 4559 y Fi(ij)3227 |
| 1456 |
< |
4547 y Fu(\))p Fj(w)3320 4513 y Ft(0)3345 4547 y Fu(\()p |
| 1457 |
< |
Fh(r)3416 4559 y Fi(ij)3475 4547 y Fj(;)c Fh(\012)3581 |
| 1458 |
< |
4559 y Fi(i)3608 4547 y Fj(;)g Fh(\012)3714 4559 y Fi(j)3749 |
| 1459 |
< |
4547 y Fu(\)])28 b Fj(;)3978 4458 y Fu(\(4\))2042 4725 |
| 1460 |
< |
y(where)h Fe(\026)2343 4745 y Fi(i)2400 4725 y Fu(and)g |
| 1461 |
< |
Fe(\026)2622 4745 y Fi(j)2687 4725 y Fu(are)f(the)i(dip)r(ole)g(unit)g |
| 1462 |
< |
(v)n(ectors)e(of)i(particles)2042 4821 y Fm(i)35 b Fu(and)27 |
| 1428 |
> |
3634 y Fj(u)2452 3600 y Fi(LJ)2452 3654 y(ij)2543 3634 |
| 1429 |
> |
y Fu(\()p Fj(r)2612 3646 y Fi(ij)2671 3634 y Fu(\))e(=)e(4)p |
| 1430 |
> |
Fj(\017)2904 3492 y Fg(")2952 3517 y(\022)3046 3578 y |
| 1431 |
> |
Fj(\033)p 3023 3615 96 4 v 3023 3691 a(r)3060 3703 y |
| 1432 |
> |
Fi(ij)3129 3517 y Fg(\023)3190 3534 y Fn(12)3279 3634 |
| 1433 |
> |
y Ff(\000)3362 3517 y Fg(\022)3455 3578 y Fj(\033)p 3433 |
| 1434 |
> |
3615 V 3433 3691 a(r)3470 3703 y Fi(ij)3539 3517 y Fg(\023)3600 |
| 1435 |
> |
3534 y Fn(6)3637 3492 y Fg(#)3699 3634 y Fj(;)256 b Fu(\(2\))2398 |
| 1436 |
> |
4038 y Fj(u)2446 3998 y Fi(dp)2446 4061 y(ij)2542 4038 |
| 1437 |
> |
y Fu(=)2639 3974 y Fe(\026)2698 3995 y Fi(i)2744 3974 |
| 1438 |
> |
y Ff(\001)19 b Fe(\026)2844 3995 y Fi(j)p 2639 4019 241 |
| 1439 |
> |
4 v 2711 4095 a Fj(r)2750 4067 y Fn(3)2748 4118 y Fi(ij)2908 |
| 1440 |
> |
4038 y Ff(\000)3001 3974 y Fu(3\()p Fe(\026)3133 3995 |
| 1441 |
> |
y Fi(i)3179 3974 y Ff(\001)g Fh(r)3260 3986 y Fi(ij)3319 |
| 1442 |
> |
3974 y Fu(\)\()p Fe(\026)3442 3995 y Fi(j)3495 3974 y |
| 1443 |
> |
Ff(\001)g Fh(r)3576 3986 y Fi(ij)3635 3974 y Fu(\))p |
| 1444 |
> |
3001 4019 667 4 v 3286 4095 a Fj(r)3325 4067 y Fn(5)3323 |
| 1445 |
> |
4118 y Fi(ij)3705 4038 y Fj(;)250 b Fu(\(3\))2271 4396 |
| 1446 |
> |
y Fj(u)2319 4356 y Fi(sp)2319 4419 y(ij)2388 4396 y Fu(\()p |
| 1447 |
> |
Fh(r)2459 4408 y Fi(ij)2518 4396 y Fj(;)14 b Fh(\012)2624 |
| 1448 |
> |
4408 y Fi(i)2652 4396 y Fj(;)g Fh(\012)2757 4408 y Fi(j)2792 |
| 1449 |
> |
4396 y Fu(\))24 b(=)2945 4340 y Fj(\027)2986 4352 y Fn(0)p |
| 1450 |
> |
2945 4377 79 4 v 2964 4453 a Fu(2)3034 4396 y([)p Fj(s)p |
| 1451 |
> |
Fu(\()p Fj(r)3165 4408 y Fi(ij)3224 4396 y Fu(\))p Fj(w)r |
| 1452 |
> |
Fu(\()p Fh(r)3388 4408 y Fi(ij)3448 4396 y Fj(;)14 b |
| 1453 |
> |
Fh(\012)3554 4408 y Fi(i)3581 4396 y Fj(;)g Fh(\012)3687 |
| 1454 |
> |
4408 y Fi(j)3722 4396 y Fu(\))2954 4553 y(+)k Fj(s)3076 |
| 1455 |
> |
4519 y Ft(0)3099 4553 y Fu(\()p Fj(r)3168 4565 y Fi(ij)3227 |
| 1456 |
> |
4553 y Fu(\))p Fj(w)3320 4519 y Ft(0)3345 4553 y Fu(\()p |
| 1457 |
> |
Fh(r)3416 4565 y Fi(ij)3475 4553 y Fj(;)c Fh(\012)3581 |
| 1458 |
> |
4565 y Fi(i)3608 4553 y Fj(;)g Fh(\012)3714 4565 y Fi(j)3749 |
| 1459 |
> |
4553 y Fu(\)])28 b Fj(;)3978 4464 y Fu(\(4\))2042 4731 |
| 1460 |
> |
y(where)h Fe(\026)2343 4751 y Fi(i)2400 4731 y Fu(and)g |
| 1461 |
> |
Fe(\026)2622 4751 y Fi(j)2687 4731 y Fu(are)f(the)i(dip)r(ole)g(unit)g |
| 1462 |
> |
(v)n(ectors)e(of)i(particles)2042 4826 y Fm(i)35 b Fu(and)27 |
| 1463 |
|
b Fm(j)39 b Fu(with)27 b(magnitude)g(2.35)e(D,)i Fj(\027)3253 |
| 1464 |
< |
4833 y Fn(0)3317 4821 y Fu(scales)f(the)h(strength)f(of)2042 |
| 1465 |
< |
4916 y(the)j(o)n(v)n(erall)d(stic)n(ky)i(p)r(oten)n(tial,)h |
| 1466 |
< |
Fj(s)g Fu(and)f Fj(s)3335 4886 y Ft(0)3387 4916 y Fu(are)g(cubic)h |
| 1467 |
< |
(switc)n(hing)2042 5011 y(functions.)71 b(The)39 b Fj(w)j |
| 1468 |
< |
Fu(and)d Fj(w)2983 4981 y Ft(0)3046 5011 y Fu(functions)h(tak)n(e)e |
| 1469 |
< |
(the)h(follo)n(wing)2042 5107 y(forms,)2362 5285 y Fj(w)r |
| 1470 |
< |
Fu(\()p Fh(r)2494 5297 y Fi(ij)2554 5285 y Fj(;)14 b |
| 1471 |
< |
Fh(\012)2659 5297 y Fi(i)2687 5285 y Fj(;)g Fh(\012)2793 |
| 1472 |
< |
5297 y Fi(j)2828 5285 y Fu(\))23 b(=)g(sin)14 b Fj(\022)3126 |
| 1473 |
< |
5297 y Fi(ij)3198 5285 y Fu(sin)g(2)p Fj(\022)3395 5297 |
| 1474 |
< |
y Fi(ij)3467 5285 y Fu(cos)f(2)p Fj(\036)3683 5297 y |
| 1475 |
< |
Fi(ij)3741 5285 y Fj(;)214 b Fu(\(5\))2083 5555 y Fj(w)2144 |
| 1476 |
< |
5521 y Ft(0)2168 5555 y Fu(\()p Fh(r)2239 5567 y Fi(ij)2298 |
| 1477 |
< |
5555 y Fj(;)14 b Fh(\012)2404 5567 y Fi(i)2432 5555 y |
| 1478 |
< |
Fj(;)g Fh(\012)2538 5567 y Fi(j)2573 5555 y Fu(\))23 |
| 1479 |
< |
b(=)g(\(cos)13 b Fj(\022)2912 5567 y Fi(ij)2978 5555 |
| 1480 |
< |
y Ff(\000)7 b Fu(0)p Fj(:)p Fu(6\))3189 5521 y Fn(2)3225 |
| 1481 |
< |
5555 y Fu(\(cos)14 b Fj(\022)3422 5567 y Fi(ij)3488 5555 |
| 1482 |
< |
y Fu(+)7 b(0)p Fj(:)p Fu(8\))3699 5521 y Fn(2)3743 5555 |
| 1483 |
< |
y Ff(\000)g Fj(w)3876 5521 y Fn(0)3913 5555 y Fj(;)42 |
| 1464 |
> |
4838 y Fn(0)3317 4826 y Fu(scales)f(the)h(strength)f(of)2042 |
| 1465 |
> |
4922 y(the)j(o)n(v)n(erall)d(stic)n(ky)i(p)r(oten)n(tial,)h |
| 1466 |
> |
Fj(s)g Fu(and)f Fj(s)3335 4891 y Ft(0)3387 4922 y Fu(are)g(cubic)h |
| 1467 |
> |
(switc)n(hing)2042 5017 y(functions.)71 b(The)39 b Fj(w)j |
| 1468 |
> |
Fu(and)d Fj(w)2983 4987 y Ft(0)3046 5017 y Fu(functions)h(tak)n(e)e |
| 1469 |
> |
(the)h(follo)n(wing)2042 5112 y(forms,)2362 5291 y Fj(w)r |
| 1470 |
> |
Fu(\()p Fh(r)2494 5303 y Fi(ij)2554 5291 y Fj(;)14 b |
| 1471 |
> |
Fh(\012)2659 5303 y Fi(i)2687 5291 y Fj(;)g Fh(\012)2793 |
| 1472 |
> |
5303 y Fi(j)2828 5291 y Fu(\))23 b(=)g(sin)14 b Fj(\022)3126 |
| 1473 |
> |
5303 y Fi(ij)3198 5291 y Fu(sin)g(2)p Fj(\022)3395 5303 |
| 1474 |
> |
y Fi(ij)3467 5291 y Fu(cos)f(2)p Fj(\036)3683 5303 y |
| 1475 |
> |
Fi(ij)3741 5291 y Fj(;)214 b Fu(\(5\))2083 5561 y Fj(w)2144 |
| 1476 |
> |
5527 y Ft(0)2168 5561 y Fu(\()p Fh(r)2239 5573 y Fi(ij)2298 |
| 1477 |
> |
5561 y Fj(;)14 b Fh(\012)2404 5573 y Fi(i)2432 5561 y |
| 1478 |
> |
Fj(;)g Fh(\012)2538 5573 y Fi(j)2573 5561 y Fu(\))23 |
| 1479 |
> |
b(=)g(\(cos)13 b Fj(\022)2912 5573 y Fi(ij)2978 5561 |
| 1480 |
> |
y Ff(\000)7 b Fu(0)p Fj(:)p Fu(6\))3189 5527 y Fn(2)3225 |
| 1481 |
> |
5561 y Fu(\(cos)14 b Fj(\022)3422 5573 y Fi(ij)3488 5561 |
| 1482 |
> |
y Fu(+)7 b(0)p Fj(:)p Fu(8\))3699 5527 y Fn(2)3743 5561 |
| 1483 |
> |
y Ff(\000)g Fj(w)3876 5527 y Fn(0)3913 5561 y Fj(;)42 |
| 1484 |
|
b Fu(\(6\))p eop |
| 1485 |
|
%%Page: 2 2 |
| 1486 |
|
2 1 bop 4043 -299 a Fu(2)-150 -83 y(where)31 b Fj(w)155 |
| 1504 |
|
(del,)h(Ic)n(hiy)n(e)-150 872 y Fm(et)31 b(al.)45 b Fu(rep)r(orted)29 |
| 1505 |
|
b(a)g(calculation)g(sp)r(eed)h(up)g(of)g(up)g(to)f(an)h(order)-150 |
| 1506 |
|
967 y(of)d(magnitude)g(o)n(v)n(er)e(other)h(comparable)g(mo)r(dels)h |
| 1507 |
< |
(while)g(main-)-150 1063 y(taining)f(the)h(structural)f(b)r(eha)n(vior) |
| 1508 |
< |
g(of)g(w)n(ater.)1312 1033 y Fn(5)1375 1063 y Fu(In)h(the)g(original) |
| 1509 |
< |
-150 1158 y(molecular)35 b(dynamics)h(studies)h(of)g(SSD,)g(it)g(w)n |
| 1510 |
< |
(as)e(sho)n(wn)h(that)-150 1254 y(it)f(actually)e(impro)n(v)n(es)g(up)r |
| 1511 |
< |
(on)h(the)h(prediction)f(of)g(w)n(ater's)f(dy-)-150 1349 |
| 1512 |
< |
y(namical)19 b(prop)r(erties)g(3)h(and)f(4-p)r(oin)n(t)h(mo)r(dels.) |
| 1513 |
< |
1303 1319 y Fn(8)1360 1349 y Fu(This)g(attractiv)n(e)-150 |
| 1514 |
< |
1445 y(com)n(bination)33 b(of)i(sp)r(eed)f(and)g(accurate)f(depiction)h |
| 1507 |
> |
(while)g(main-)-150 1063 y(taining)37 b(the)g(structural)f(b)r(eha)n |
| 1508 |
> |
(vior)g(of)h(w)n(ater.)1364 1033 y Fn(5)1437 1063 y Fu(In)h(the)f |
| 1509 |
> |
(origi-)-150 1158 y(nal)31 b(molecular)f(dynamics)g(studies,)i(it)f(w)n |
| 1510 |
> |
(as)f(sho)n(wn)g(that)i(SSD)-150 1254 y(impro)n(v)n(es)g(on)h(the)g |
| 1511 |
> |
(prediction)g(of)h(man)n(y)e(of)i(w)n(ater's)e(dynami-)-150 |
| 1512 |
> |
1349 y(cal)e(prop)r(erties)g(o)n(v)n(er)f(TIP3P)g(and)i(SPC/E.)1282 |
| 1513 |
> |
1319 y Fn(8)1349 1349 y Fu(This)g(attractiv)n(e)-150 |
| 1514 |
> |
1445 y(com)n(bination)i(of)i(sp)r(eed)f(and)g(accurate)f(depiction)h |
| 1515 |
|
(of)h(solv)n(en)n(t)-150 1540 y(prop)r(erties)24 b(mak)n(es)h(SSD)h(a)e |
| 1516 |
|
(mo)r(del)i(of)f(in)n(terest)g(for)g(the)g(sim)n(ula-)-150 |
| 1517 |
|
1636 y(tion)k(of)g(large)e(scale)h(biological)f(systems,)i(suc)n(h)f |
| 1549 |
|
(estigators)-150 3545 y(of)f(the)g(SSD)h(w)n(ater)e(mo)r(del)h(ha)n(v)n |
| 1550 |
|
(e)e(put)j(forth)e(adjustmen)n(ts)i(to)-150 3641 y(the)30 |
| 1551 |
|
b(original)e(SSD)j(w)n(ater)d(mo)r(del)i(to)g(address)e(abnormal)h |
| 1552 |
< |
(den-)-150 3736 y(sit)n(y)i(b)r(eha)n(vior,)h(calling)f(the)h |
| 1553 |
< |
(corrected)e(mo)r(del)i(SSD1.)1628 3706 y Fn(10)1730 |
| 1554 |
< |
3736 y Fu(This)-150 3831 y(study)39 b(will)h(consider)e(this)i(new)f |
| 1555 |
< |
(mo)r(del's)g(b)r(eha)n(vior)f(as)h(w)n(ell,)-150 3927 |
| 1556 |
< |
y(and)26 b(hop)r(efully)g(impro)n(v)n(e)f(up)r(on)h(its)g(depiction)g |
| 1557 |
< |
(of)g(w)n(ater)f(under)-150 4022 y(conditions)i(without)h(the)g(Ew)n |
| 1558 |
< |
(ald)f(Sum.)552 4299 y Fo(I)r(I.)89 b(METHODS)-67 4512 |
| 1559 |
< |
y Fu(As)50 b(stated)h(previously)-7 b(,)55 b(in)50 b(this)h(study)f |
| 1560 |
< |
(the)h(long-range)-150 4608 y(dip)r(ole-dip)r(ole)37 |
| 1561 |
< |
b(in)n(teractions)f(w)n(ere)g(accoun)n(ted)h(for)f(using)h(the)-150 |
| 1562 |
< |
4703 y(reaction)h(\014eld)h(metho)r(d.)70 b(The)39 b(magnitude)g(of)f |
| 1563 |
< |
(the)i(reaction)-150 4799 y(\014eld)28 b(acting)f(on)g(dip)r(ole)h |
| 1564 |
< |
Fm(i)37 b Fu(is)27 b(giv)n(en)g(b)n(y)303 5024 y Ff(E)347 |
| 1565 |
< |
5036 y Fi(i)397 5024 y Fu(=)495 4968 y(2\()p Fj(")608 |
| 1566 |
< |
4980 y Fi(s)661 4968 y Ff(\000)18 b Fu(1\))p 495 5005 |
| 1567 |
< |
324 4 v 527 5081 a(2)p Fj(")608 5093 y Fi(s)661 5081 |
| 1568 |
< |
y Fu(+)g(1)856 4968 y(1)p 838 5005 78 4 v 838 5081 a |
| 1569 |
< |
Fj(r)877 5057 y Fn(3)875 5102 y Fi(c)945 4946 y Fg(X)939 |
| 1570 |
< |
5124 y Fi(j)s Ft(2R)1085 5024 y Fe(\026)1144 5045 y Fi(j)1179 |
| 1571 |
< |
5024 y Fj(f)9 b Fu(\()p Fj(r)1298 5036 y Fi(ij)1357 5024 |
| 1572 |
< |
y Fu(\))28 b Fj(;)346 b Fu(\(7\))-150 5297 y(where)32 |
| 1573 |
< |
b Ff(R)h Fu(is)f(the)h(ca)n(vit)n(y)e(de\014ned)h(b)n(y)h(the)f |
| 1574 |
< |
(cuto\013)h(radius)e(\()p Fj(r)1802 5309 y Fi(c)1837 |
| 1575 |
< |
5297 y Fu(\),)-150 5392 y Fj(")-111 5404 y Fi(s)-43 5392 |
| 1576 |
< |
y Fu(is)i(the)h(dielectric)f(constan)n(t)f(imp)r(osed)h(on)g(the)g |
| 1577 |
< |
(system)g(\(80)2042 -83 y(in)j(this)h(case\),)h Fe(\026)2619 |
| 1578 |
< |
-63 y Fi(j)2690 -83 y Fu(is)f(the)g(dip)r(ole)f(momen)n(t)g(v)n(ector)g |
| 1579 |
< |
(of)g(parti-)2042 24 y(cle)43 b Fm(j)p Fu(,)48 b(and)43 |
| 1580 |
< |
b Fj(f)9 b Fu(\()p Fj(r)2574 36 y Fi(ij)2632 24 y Fu(\))44 |
| 1581 |
< |
b(is)f(a)g(cubic)g(switc)n(hing)g(function.)3827 -6 y |
| 1582 |
< |
Fn(11)3941 24 y Fu(The)2042 120 y(reaction)c(\014eld)h(con)n(tribution) |
| 1583 |
< |
f(to)h(the)h(total)f(energy)f(b)n(y)g(par-)2042 215 y(ticle)f |
| 1584 |
< |
Fm(i)48 b Fu(is)38 b(giv)n(en)g(b)n(y)g Ff(\000)2828 |
| 1585 |
< |
183 y Fn(1)p 2827 197 34 4 v 2827 244 a(2)2870 215 y |
| 1586 |
< |
Fe(\026)2929 236 y Fi(i)2983 215 y Ff(\001)25 b(E)3075 |
| 1552 |
> |
(den-)-150 3736 y(sit)n(y)j(b)r(eha)n(vior)e(\(also)h(observ)n(ed)f |
| 1553 |
> |
(here\),)j(calling)f(the)g(corrected)-150 3831 y(mo)r(del)24 |
| 1554 |
> |
b(SSD1.)313 3801 y Fn(10)408 3831 y Fu(This)g(study)g(will)g(consider)f |
| 1555 |
> |
(this)h(new)g(mo)r(del's)-150 3927 y(b)r(eha)n(vior)30 |
| 1556 |
> |
b(as)g(w)n(ell,)h(and)g(hop)r(efully)h(impro)n(v)n(e)d(up)r(on)i(its)h |
| 1557 |
> |
(depic-)-150 4022 y(tion)c(of)f(w)n(ater)g(under)g(conditions)g |
| 1558 |
> |
(without)h(the)g(Ew)n(ald)f(Sum.)552 4299 y Fo(I)r(I.)89 |
| 1559 |
> |
b(METHODS)-67 4512 y Fu(As)50 b(stated)h(previously)-7 |
| 1560 |
> |
b(,)55 b(in)50 b(this)h(study)f(the)h(long-range)-150 |
| 1561 |
> |
4608 y(dip)r(ole-dip)r(ole)37 b(in)n(teractions)f(w)n(ere)g(accoun)n |
| 1562 |
> |
(ted)h(for)f(using)h(the)-150 4703 y(reaction)h(\014eld)h(metho)r(d.)70 |
| 1563 |
> |
b(The)39 b(magnitude)g(of)f(the)i(reaction)-150 4799 |
| 1564 |
> |
y(\014eld)28 b(acting)f(on)g(dip)r(ole)h Fm(i)37 b Fu(is)27 |
| 1565 |
> |
b(giv)n(en)g(b)n(y)303 5024 y Ff(E)347 5036 y Fi(i)397 |
| 1566 |
> |
5024 y Fu(=)495 4968 y(2\()p Fj(")608 4980 y Fi(s)661 |
| 1567 |
> |
4968 y Ff(\000)18 b Fu(1\))p 495 5005 324 4 v 527 5081 |
| 1568 |
> |
a(2)p Fj(")608 5093 y Fi(s)661 5081 y Fu(+)g(1)856 4968 |
| 1569 |
> |
y(1)p 838 5005 78 4 v 838 5081 a Fj(r)877 5057 y Fn(3)875 |
| 1570 |
> |
5102 y Fi(c)945 4946 y Fg(X)939 5124 y Fi(j)s Ft(2R)1085 |
| 1571 |
> |
5024 y Fe(\026)1144 5045 y Fi(j)1179 5024 y Fj(f)9 b |
| 1572 |
> |
Fu(\()p Fj(r)1298 5036 y Fi(ij)1357 5024 y Fu(\))28 b |
| 1573 |
> |
Fj(;)346 b Fu(\(7\))-150 5297 y(where)32 b Ff(R)h Fu(is)f(the)h(ca)n |
| 1574 |
> |
(vit)n(y)e(de\014ned)h(b)n(y)h(the)f(cuto\013)h(radius)e(\()p |
| 1575 |
> |
Fj(r)1802 5309 y Fi(c)1837 5297 y Fu(\),)-150 5392 y |
| 1576 |
> |
Fj(")-111 5404 y Fi(s)-43 5392 y Fu(is)i(the)h(dielectric)f(constan)n |
| 1577 |
> |
(t)f(imp)r(osed)h(on)g(the)g(system)g(\(80)2042 -83 y(in)j(this)h |
| 1578 |
> |
(case\),)h Fe(\026)2619 -63 y Fi(j)2690 -83 y Fu(is)f(the)g(dip)r(ole)f |
| 1579 |
> |
(momen)n(t)g(v)n(ector)g(of)g(parti-)2042 24 y(cle)43 |
| 1580 |
> |
b Fm(j)p Fu(,)48 b(and)43 b Fj(f)9 b Fu(\()p Fj(r)2574 |
| 1581 |
> |
36 y Fi(ij)2632 24 y Fu(\))44 b(is)f(a)g(cubic)g(switc)n(hing)g |
| 1582 |
> |
(function.)3827 -6 y Fn(11)3941 24 y Fu(The)2042 120 |
| 1583 |
> |
y(reaction)c(\014eld)h(con)n(tribution)f(to)h(the)h(total)f(energy)f(b) |
| 1584 |
> |
n(y)g(par-)2042 215 y(ticle)f Fm(i)48 b Fu(is)38 b(giv)n(en)g(b)n(y)g |
| 1585 |
> |
Ff(\000)2828 183 y Fn(1)p 2827 197 34 4 v 2827 244 a(2)2870 |
| 1586 |
> |
215 y Fe(\026)2929 236 y Fi(i)2983 215 y Ff(\001)25 b(E)3075 |
| 1587 |
|
227 y Fi(i)3141 215 y Fu(and)38 b(the)h(torque)f(on)g(dip)r(ole)2042 |
| 1588 |
|
320 y Fm(i)47 b Fu(b)n(y)38 b Fe(\026)2298 340 y Fi(i)2351 |
| 1589 |
|
320 y Ff(\002)25 b(E)2485 332 y Fi(i)2513 320 y Fu(.)2536 |
| 1609 |
|
y(isothermal)28 b(and)g(micro)r(canonical)f(ensem)n(bles.)40 |
| 1610 |
|
b(The)29 b(constan)n(t)2042 1657 y(pressure)c(sim)n(ulations)g(w)n(ere) |
| 1611 |
|
g(implemen)n(ted)i(using)f(an)f(in)n(tegral)2042 1752 |
| 1612 |
< |
y(thermostat)i(and)h(barostat)f(as)h(outlined)g(b)n(y)g(Ho)r(o)n(v)n |
| 1613 |
< |
(er.)3781 1722 y Fn(13)n(,14)3963 1752 y Fu(F)-7 b(or)2042 |
| 1614 |
< |
1848 y(the)34 b(constan)n(t)e(pressure)g(sim)n(ulations,)i(the)g |
| 1615 |
< |
Fm(Q)41 b Fu(parameter)32 b(for)2042 1943 y(the)e(w)n(as)f(set)h(to)g |
| 1616 |
< |
(5.0)f(am)n(u)g Ff(\001)2928 1928 y Fu(\027)2928 1943 |
| 1617 |
< |
y(A)2990 1913 y Fn(2)3028 1943 y Fu(,)h(and)g(the)g(relaxation)e(time)j |
| 1618 |
< |
(\()p Fj(\034)9 b Fu(\))2042 2038 y(w)n(as)26 b(set)i(at)f(100)g(ps.) |
| 1619 |
< |
2125 2134 y(In)n(tegration)e(of)h(the)g(equations)f(of)h(motion)g(w)n |
| 1620 |
< |
(as)f(carried)g(out)2042 2229 y(using)h(the)g(symplectic)h(splitting)g |
| 1621 |
< |
(metho)r(d)f(prop)r(osed)g(b)n(y)g(Dull-)2042 2325 y(w)n(eb)r(er)37 |
| 1622 |
< |
b Fm(et)i(al.)p Fu(.)2508 2295 y Fn(15)2618 2325 y Fu(The)f(reason)f |
| 1623 |
< |
(for)g(this)i(in)n(tegrator)d(selection)2042 2420 y(deals)g(with)h(p)r |
| 1612 |
> |
y(thermostat)k(and)h(barostat)f(as)g(outlined)h(b)n(y)g(Ho)r(o)n(v)n |
| 1613 |
> |
(er.)3792 1722 y Fn(13)o(,14)3976 1752 y Fu(All)2042 |
| 1614 |
> |
1848 y(particles)42 b(w)n(ere)g(treated)h(as)f(non-linear)g(rigid)h(b)r |
| 1615 |
> |
(o)r(dies.)83 b(Vi-)2042 1943 y(brational)27 b(constrain)n(ts)h(are)g |
| 1616 |
> |
(not)h(necessary)e(in)i(sim)n(ulations)f(of)2042 2038 |
| 1617 |
> |
y(SSD,)h(b)r(ecause)f(there)h(are)e(no)h(explicit)h(h)n(ydrogen)e |
| 1618 |
> |
(atoms,)h(and)2042 2134 y(th)n(us)j(no)f(molecular)g(vibrational)f(mo)r |
| 1619 |
> |
(des)h(need)h(to)g(b)r(e)g(consid-)2042 2229 y(ered.)2125 |
| 1620 |
> |
2325 y(In)n(tegration)25 b(of)h(the)g(equations)f(of)h(motion)g(w)n(as) |
| 1621 |
> |
f(carried)g(out)2042 2420 y(using)h(the)g(symplectic)h(splitting)g |
| 1622 |
> |
(metho)r(d)f(prop)r(osed)g(b)n(y)g(Dull-)2042 2516 y(w)n(eb)r(er)37 |
| 1623 |
> |
b Fm(et)i(al.)p Fu(.)2508 2486 y Fn(15)2618 2516 y Fu(The)f(reason)f |
| 1624 |
> |
(for)g(this)i(in)n(tegrator)d(selection)2042 2611 y(deals)g(with)h(p)r |
| 1625 |
|
(o)r(or)f(energy)f(conserv)-5 b(ation)36 b(of)g(rigid)g(b)r(o)r(dy)h |
| 1626 |
< |
(sys-)2042 2516 y(tems)24 b(using)h(quaternions.)34 b(While)25 |
| 1627 |
< |
b(quaternions)e(w)n(ork)h(w)n(ell)g(for)2042 2611 y(orien)n(tational)33 |
| 1626 |
> |
(sys-)2042 2707 y(tems)24 b(using)h(quaternions.)34 b(While)25 |
| 1627 |
> |
b(quaternions)e(w)n(ork)h(w)n(ell)g(for)2042 2802 y(orien)n(tational)33 |
| 1628 |
|
b(motion)h(in)h(alternate)e(ensem)n(bles,)j(the)f(micro-)2042 |
| 1629 |
< |
2707 y(canonical)j(ensem)n(ble)i(has)f(a)g(constan)n(t)g(energy)g |
| 1630 |
< |
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< |
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< |
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< |
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< |
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< |
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| 1636 |
< |
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| 1637 |
< |
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| 1638 |
< |
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| 1629 |
> |
2898 y(canonical)j(ensem)n(ble)i(has)f(a)g(constan)n(t)g(energy)g |
| 1630 |
> |
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| 1631 |
> |
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| 1632 |
> |
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| 1633 |
> |
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| 1634 |
> |
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| 1635 |
> |
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| 1636 |
> |
3375 y(steady)25 b(drift)h(in)f(the)h(total)f(energy)-7 |
| 1637 |
> |
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| 1638 |
> |
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| 1639 |
|
(di\013erence)g(in)h(the)f(in)n(tegration)f(metho)r(d)i(prop)r(osed) |
| 1640 |
< |
2042 3471 y(b)n(y)37 b(Dullw)n(eb)r(er)h Fm(et)h(al.)68 |
| 1641 |
< |
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< |
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| 1649 |
< |
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| 1655 |
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| 1656 |
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| 1675 |
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(propagation.)48 b(On)32 b(a)n(v)n(erage,)e(a)h(1000)p |
| 1676 |
< |
eop |
| 1640 |
> |
2042 3662 y(b)n(y)k(Dullw)n(eb)r(er)h Fm(et)i(al.)44 |
| 1641 |
> |
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> |
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| 1658 |
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3 2 bop 4043 -299 a Fu(3)-139 -166 y |
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1302 -166 a -150 1418 a Fr(FIG.)26 |
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(e)h(with)-150 5277 y(a)43 b(edge)g(length)h(ratio)e(of)i(appro)n |
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(ximately)d(1.00)p Ff(\002)p Fu(1.06)p Ff(\002)p Fu(1.23.)-150 |
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5372 y(The)e(particles)e(w)n(ere)h(then)h(allo)n(w)n(ed)e(to)i(orien)n |
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(t)e(freely)h(ab)r(out)2055 -166 y |
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gsave currentpoint currentpoint translate -90 neg rotate neg exch |
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neg exch translate |
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2055 -166 a @beginspecial |
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96 @llx 70 @lly 546 @urx 661 @ury 1842 @rwi @setspecial |
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| 19446 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19447 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19448 |
< |
% 00000000000000000000000000000000000000000000ff0000000000000000ff000000ff000000ff |
| 19449 |
< |
% 00001100000055ff0000aa550011bbffcc3300000000ff0000000000cc11000022ff000000000000 |
| 19450 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19451 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19452 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19453 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19454 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19455 |
< |
% 00000000000000000000 |
| 19456 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19457 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19458 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19459 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19460 |
< |
% 00000000000000000000000000000000000000000000ff0000000000000000ff000000ff000000ff |
| 19461 |
< |
% 00000000000000ee0000ee0000bb110099dd00000000ff0000000000ff00000000ff000000000000 |
| 19462 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19463 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19464 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19465 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19466 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19467 |
< |
% 00000000000000000000 |
| 19468 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19469 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19470 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19471 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19472 |
< |
% 00000000000000000000000000000000000000000000ff0000000000000000ff110000ff110000ff |
| 19473 |
< |
% 00005533000033880055990000ee220000ee00000000ff0000000000ee77000000ff000000000000 |
| 19474 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19475 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19476 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19477 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19478 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19479 |
< |
% 00000000000000000000 |
| 19480 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19481 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19482 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19483 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19484 |
< |
% 00000000000000000000000000000000000000000000bb4400000000000000aaffcc66ffffaa77ff |
| 19485 |
< |
% 330088ddffffbb1100995500bbffcceeaa5500000011dd000000000099ee770011dd000000000000 |
| 19486 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19487 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19488 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19489 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19490 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19491 |
< |
% 00000000000000000000 |
| 19492 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19493 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19494 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19495 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19496 |
< |
% 00000000000000000000000000000000000000000000667700000000000000000000000000000055 |
| 19497 |
< |
% 110000000000000000dd0000001166110000000000559900000000001199ffffcc33000000000000 |
| 19498 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19499 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19500 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19501 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19502 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19503 |
< |
% 00000000000000000000 |
| 19504 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19505 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19506 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19507 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19508 |
< |
% 0000000000000000000000000000000000000000000000aa00000000000000000000000000000000 |
| 19509 |
< |
% 00000000000000005599000000000000000000000099220000000000000000000000000000000000 |
| 19510 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19511 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19512 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19513 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19514 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19515 |
< |
% 00000000000000000000 |
| 19516 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19517 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19518 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19519 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19520 |
< |
% 00000000000000000000000000000000000000000000003366003355556600000000000000000000 |
| 19521 |
< |
% 00000000000000009955000000000000000000006666000000000000000000000000000000000000 |
| 19522 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19523 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19524 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19525 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19526 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19527 |
< |
% 00000000000000000000 |
| 19528 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19529 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19530 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19531 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19532 |
< |
% 0000000000000000000000000000000000000000000000003333dd00000000000000000000000000 |
| 19533 |
< |
% 0000000000000000dd00000000000000000000224400000000000000000000000000000000000000 |
| 19534 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19535 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19536 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19537 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19538 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19539 |
< |
% 00000000000000000000 |
| 19540 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19541 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19542 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19543 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19544 |
< |
% 0000000000000000000000000000000000000000000000000000aa88330000000000000000000000 |
| 19545 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19546 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19547 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19548 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19549 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19550 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19551 |
< |
% 00000000000000000000 |
| 19552 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19553 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19554 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19555 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19556 |
< |
% 00000000000000000000000000000000000000000000000000002288000000000000000000000000 |
| 19557 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19558 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19559 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19560 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19561 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19562 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19563 |
< |
% 00000000000000000000 |
| 19564 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19565 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19566 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19567 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19568 |
< |
% 0000000000000000000000000000000000000000000000000000ee33003300000000000000000000 |
| 19569 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19570 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19571 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19572 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19573 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19574 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19575 |
< |
% 00000000000000000000 |
| 19576 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19577 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19578 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19579 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19580 |
< |
% 000000000000000000000000000000000000000000000000000066eecc1100000000000000000000 |
| 19581 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19582 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19583 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19584 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19585 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19586 |
< |
% 00000000000000000000000000000000000000000000000000000000000000000000000000000000 |
| 19587 |
< |
% 00000000000000000000 |
| 19588 |
< |
%%EndImage |
| 19589 |
< |
%%EndPreview |
| 19590 |
< |
save countdictstack mark newpath /showpage {} def /setpagedevice {pop} def |
| 19591 |
< |
%%EndProlog |
| 19592 |
< |
%%Page: 1 1 |
| 19593 |
< |
%%BeginDocument: 1hdense.ps |
| 19594 |
< |
80 dict begin |
| 19595 |
< |
/languagelevel where |
| 19596 |
< |
{pop /gs_languagelevel languagelevel def} |
| 19597 |
< |
{/gs_languagelevel 1 def} ifelse |
| 19598 |
< |
gs_languagelevel 1 gt { |
| 19599 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19600 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19601 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19602 |
< |
{<0000000000000000000000000000000000000000000000000000000000000000>} image end } |
| 19603 |
< |
>> matrix makepattern /Pat0 exch def |
| 19604 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19605 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19606 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19607 |
< |
{<1111000044440000111100004444000011110000444400001111000044440000>} image end } |
| 19608 |
< |
>> matrix makepattern /Pat1 exch def |
| 19609 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19610 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19611 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19612 |
< |
{<1111444411114444111144441111444411114444111144441111444411114444>} image end } |
| 19613 |
< |
>> matrix makepattern /Pat2 exch def |
| 19614 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19615 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19616 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19617 |
< |
{<aaaa5555aaaa5555aaaa5555aaaa5555aaaa5555aaaa5555aaaa5555aaaa5555>} image end } |
| 19618 |
< |
>> matrix makepattern /Pat3 exch def |
| 19619 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19620 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19621 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19622 |
< |
{<eeeebbbbeeeebbbbeeeebbbbeeeebbbbeeeebbbbeeeebbbbeeeebbbbeeeebbbb>} image end } |
| 19623 |
< |
>> matrix makepattern /Pat4 exch def |
| 19624 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19625 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19626 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19627 |
< |
{<eeeeffffbbbbffffeeeeffffbbbbffffeeeeffffbbbbffffeeeeffffbbbbffff>} image end } |
| 19628 |
< |
>> matrix makepattern /Pat5 exch def |
| 19629 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19630 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19631 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19632 |
< |
{<f77dffffbeeffffff77dffffbeeffffff77dffffbeeffffff77dffffbeefffff>} image end } |
| 19633 |
< |
>> matrix makepattern /Pat6 exch def |
| 19634 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19635 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19636 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19637 |
< |
{<ffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffff>} image end } |
| 19638 |
< |
>> matrix makepattern /Pat7 exch def |
| 19639 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19640 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19641 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19642 |
< |
{<e1e1f0f078783c3c1e1e0f0f8787c3c3e1e1f0f078783c3c1e1e0f0f8787c3c3>} image end } |
| 19643 |
< |
>> matrix makepattern /Pat8 exch def |
| 19644 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19645 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19646 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19647 |
< |
{<87870f0f1e1e3c3c7878f0f0e1e1c3c387870f0f1e1e3c3c7878f0f0e1e1c3c3>} image end } |
| 19648 |
< |
>> matrix makepattern /Pat9 exch def |
| 19649 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19650 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19651 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19652 |
< |
{<cccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccccc>} image end } |
| 19653 |
< |
>> matrix makepattern /Pat10 exch def |
| 19654 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19655 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19656 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19657 |
< |
{<00000000ffffffff00000000ffffffff00000000ffffffff00000000ffffffff>} image end } |
| 19658 |
< |
>> matrix makepattern /Pat11 exch def |
| 19659 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19660 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19661 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19662 |
< |
{<7e7ebdbddbdbe7e7e7e7dbdbbdbd7e7e7e7ebdbddbdbe7e7e7e7dbdbbdbd7e7e>} image end } |
| 19663 |
< |
>> matrix makepattern /Pat12 exch def |
| 19664 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19665 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19666 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19667 |
< |
{<fd7e7ebfbfdfdfefeff7f7fbfbfdfd7e7ebfbfdfdfefeff7f7fbfbfdfd7e7ebf>} image end } |
| 19668 |
< |
>> matrix makepattern /Pat13 exch def |
| 19669 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19670 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19671 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19672 |
< |
{<7ebffd7efbfdf7fbeff7dfefbfdf7ebffd7efbfdf7fbeff7dfefbfdf7ebffd7e>} image end } |
| 19673 |
< |
>> matrix makepattern /Pat14 exch def |
| 19674 |
< |
<</PaintType 1 /PatternType 1 /TilingType 1 |
| 19675 |
< |
/BBox [0 0 12 12] /XStep 12 /YStep 12 /PaintProc{ begin |
| 19676 |
< |
12 12 scale 16 16 1 [16 0 0 16 0 0] |
| 19677 |
< |
{<fffffbdff3dfebdfdbdfbbdf7bdffbdefbddfbdbfbd7fbcffbdfffffffffffff>} image end } |
| 19678 |
< |
>> matrix makepattern /Pat15 exch def |
| 19679 |
< |
}{ |
| 19680 |
< |
/Pat0 { 0.000000 setgray } def |
| 19681 |
< |
/Pat1 { 0.062500 setgray } def |
| 19682 |
< |
/Pat2 { 0.125000 setgray } def |
| 19683 |
< |
/Pat3 { 0.187500 setgray } def |
| 19684 |
< |
/Pat4 { 0.250000 setgray } def |
| 19685 |
< |
/Pat5 { 0.312500 setgray } def |
| 19686 |
< |
/Pat6 { 0.375000 setgray } def |
| 19687 |
< |
/Pat7 { 0.437500 setgray } def |
| 19688 |
< |
/Pat8 { 0.500000 setgray } def |
| 19689 |
< |
/Pat9 { 0.562500 setgray } def |
| 19690 |
< |
/Pat10 { 0.625000 setgray } def |
| 19691 |
< |
/Pat11 { 0.687500 setgray } def |
| 19692 |
< |
/Pat12 { 0.750000 setgray } def |
| 19693 |
< |
/Pat13 { 0.812500 setgray } def |
| 19694 |
< |
/Pat14 { 0.875000 setgray } def |
| 19695 |
< |
/Pat15 { 0.937500 setgray } def |
| 19696 |
< |
/setpattern { } def |
| 19697 |
< |
} ifelse |
| 19698 |
< |
/m {moveto} bind def |
| 19699 |
< |
/l {lineto} bind def |
| 19700 |
< |
/s {stroke} bind def |
| 19701 |
< |
% Symbol fill |
| 19702 |
< |
/f { gsave fill grestore stroke } bind def |
| 19703 |
< |
% Opaque symbol |
| 19704 |
< |
/o { gsave 1.000000 1.000000 1.000000 setrgbcolor |
| 19705 |
< |
fill grestore stroke } bind def |
| 19706 |
< |
% Circle symbol |
| 19707 |
< |
/a { 3 -1 roll 0 360 arc } bind def |
| 19708 |
< |
/da { a s } bind def |
| 19709 |
< |
/fa { a f } bind def |
| 19710 |
< |
/oa { a o } bind def |
| 19711 |
< |
% Square symbol |
| 19712 |
< |
/sq { moveto dup dup rmoveto 2 mul |
| 19713 |
< |
dup neg 0 rlineto dup neg 0 exch rlineto |
| 19714 |
< |
0 rlineto closepath } bind def |
| 19715 |
< |
/dsq { sq s } bind def |
| 19716 |
< |
/fsq { sq f } bind def |
| 19717 |
< |
/osq { sq o } bind def |
| 19718 |
< |
% Triangle symbols |
| 19719 |
< |
/t1 { moveto dup 0 exch rmoveto |
| 19720 |
< |
dup neg dup 2 mul rlineto 2 mul 0 rlineto |
| 19721 |
< |
closepath } bind def |
| 19722 |
< |
/dt1 { t1 s } bind def |
| 19723 |
< |
/ft1 { t1 f } bind def |
| 19724 |
< |
/ot1 { t1 o } bind def |
| 19725 |
< |
/t2 { moveto dup neg 0 rmoveto |
| 19726 |
< |
dup dup 2 mul exch neg rlineto |
| 19727 |
< |
2 mul 0 exch rlineto closepath } bind def |
| 19728 |
< |
/dt2 { t2 s } bind def |
| 19729 |
< |
/ft2 { t2 f } bind def |
| 19730 |
< |
/ot2 { t2 o } bind def |
| 19731 |
< |
/t3 { moveto dup neg 0 exch rmoveto |
| 19732 |
< |
dup dup 2 mul rlineto neg 2 mul 0 rlineto |
| 19733 |
< |
closepath } bind def |
| 19734 |
< |
/dt3 { t3 s } bind def |
| 19735 |
< |
/ft3 { t3 f } bind def |
| 19736 |
< |
/ot3 { t3 o } bind def |
| 19737 |
< |
/t4 { moveto dup 0 rmoveto |
| 19738 |
< |
dup dup -2 mul exch rlineto |
| 19739 |
< |
-2 mul 0 exch rlineto closepath } bind def |
| 19740 |
< |
/dt4 { t4 s } bind def |
| 19741 |
< |
/ft4 { t4 f } bind def |
| 19742 |
< |
/ot4 { t4 o } bind def |
| 19743 |
< |
% Diamond symbol |
| 19744 |
< |
/di { moveto dup 0 exch rmoveto |
| 19745 |
< |
dup neg dup rlineto dup dup neg rlineto |
| 19746 |
< |
dup dup rlineto closepath } bind def |
| 19747 |
< |
/ddi { di s } bind def |
| 19748 |
< |
/fdi { di f } bind def |
| 19749 |
< |
/odi { di o } bind def |
| 19750 |
< |
% Plus symbol |
| 19751 |
< |
/pl { dup 0 rmoveto dup -2 mul 0 rlineto |
| 19752 |
< |
dup dup rmoveto -2 mul 0 exch rlineto |
| 19753 |
< |
} bind def |
| 19754 |
< |
/dpl { m pl s } bind def |
| 19755 |
< |
% x symbol |
| 19756 |
< |
/x { dup dup rmoveto dup -2 mul dup rlineto |
| 19757 |
< |
2 mul dup 0 rmoveto dup neg exch rlineto |
| 19758 |
< |
} bind def |
| 19759 |
< |
/dx { m x s } bind def |
| 19760 |
< |
% Splat symbol |
| 19761 |
< |
/dsp { m dup pl dup 0 exch rmoveto 0.707 mul x s |
| 19762 |
< |
} bind def |
| 19763 |
< |
/RJ { |
| 19764 |
< |
stringwidth neg exch neg exch |
| 19765 |
< |
rmoveto |
| 19766 |
< |
} bind def |
| 19767 |
< |
/CS { |
| 19768 |
< |
stringwidth |
| 19769 |
< |
2 div neg exch 2 div neg exch |
| 19770 |
< |
rmoveto |
| 19771 |
< |
} bind def |
| 19772 |
< |
0.24 0.24 scale |
| 19773 |
< |
1 setlinecap |
| 19774 |
< |
|
| 19775 |
< |
mark |
| 19776 |
< |
/ISOLatin1Encoding |
| 19777 |
< |
8#000 1 8#054 {StandardEncoding exch get} for |
| 19778 |
< |
/minus |
| 19779 |
< |
8#056 1 8#217 {StandardEncoding exch get} for |
| 19780 |
< |
/dotlessi |
| 19781 |
< |
8#301 1 8#317 {StandardEncoding exch get} for |
| 19782 |
< |
/space /exclamdown /cent /sterling /currency /yen /brokenbar /section |
| 19783 |
< |
/dieresis /copyright /ordfeminine /guillemotleft /logicalnot /hyphen |
| 19784 |
< |
/registered /macron /degree /plusminus /twosuperior /threesuperior /acute |
| 19785 |
< |
/mu /paragraph /periodcentered /cedilla /onesuperior /ordmasculine |
| 19786 |
< |
/guillemotright /onequarter /onehalf /threequarters /questiondown /Agrave |
| 19787 |
< |
/Aacute /Acircumflex /Atilde /Adieresis /Aring /AE /Ccedilla /Egrave /Eacute |
| 19788 |
< |
/Ecircumflex /Edieresis /Igrave /Iacute /Icircumflex /Idieresis /Eth /Ntilde |
| 19789 |
< |
/Ograve /Oacute /Ocircumflex /Otilde /Odieresis /multiply /Oslash /Ugrave |
| 19790 |
< |
/Uacute /Ucircumflex /Udieresis /Yacute /Thorn /germandbls /agrave /aacute |
| 19791 |
< |
/acircumflex /atilde /adieresis /aring /ae /ccedilla /egrave /eacute |
| 19792 |
< |
/ecircumflex /edieresis /igrave /iacute /icircumflex /idieresis /eth /ntilde |
| 19793 |
< |
/ograve /oacute /ocircumflex /otilde /odieresis /divide /oslash /ugrave |
| 19794 |
< |
/uacute /ucircumflex /udieresis /yacute /thorn /ydieresis |
| 19795 |
< |
/ISOLatin1Encoding where not {256 array astore def} if |
| 19796 |
< |
cleartomark |
| 19797 |
< |
|
| 19798 |
< |
/makeISOEncoded |
| 19799 |
< |
{ findfont /curfont exch def |
| 19800 |
< |
/newfont curfont maxlength dict def |
| 19801 |
< |
/ISOLatin1 (-ISOLatin1) def |
| 19802 |
< |
/curfontname curfont /FontName get dup length string cvs def |
| 19803 |
< |
/newfontname curfontname length ISOLatin1 length add string |
| 19804 |
< |
dup 0 curfontname putinterval |
| 19805 |
< |
dup curfontname length ISOLatin1 putinterval |
| 19806 |
< |
def |
| 19807 |
< |
curfont |
| 19808 |
< |
{ exch dup /FID ne |
| 19809 |
< |
{ dup /Encoding eq |
| 19810 |
< |
{ exch pop ISOLatin1Encoding exch } |
| 19811 |
< |
if |
| 19812 |
< |
dup /FontName eq |
| 19813 |
< |
{ exch pop newfontname exch } |
| 19814 |
< |
if |
| 19815 |
< |
exch newfont 3 1 roll put |
| 19816 |
< |
} |
| 19817 |
< |
{ pop pop } |
| 19818 |
< |
ifelse |
| 19819 |
< |
} |
| 19820 |
< |
forall |
| 19821 |
< |
newfontname newfont definefont |
| 19822 |
< |
} def |
| 19823 |
< |
|
| 19824 |
< |
/Times-Roman makeISOEncoded pop |
| 19825 |
< |
/Times-Bold makeISOEncoded pop |
| 19826 |
< |
/Times-Italic makeISOEncoded pop |
| 19827 |
< |
/Times-BoldItalic makeISOEncoded pop |
| 19828 |
< |
/Helvetica makeISOEncoded pop |
| 19829 |
< |
/Helvetica-Bold makeISOEncoded pop |
| 19830 |
< |
/Helvetica-Oblique makeISOEncoded pop |
| 19831 |
< |
/Helvetica-BoldOblique makeISOEncoded pop |
| 19832 |
< |
2550 0 translate |
| 19833 |
< |
90 rotate |
| 19834 |
< |
0.000000 0.000000 0.000000 setrgbcolor |
| 19835 |
< |
1 setlinewidth |
| 19836 |
< |
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| 19837 |
< |
[] 0 setdash |
| 19838 |
< |
592 438 m |
| 19839 |
< |
592 448 l |
| 19840 |
< |
692 438 m |
| 19841 |
< |
692 448 l |
| 19842 |
< |
793 438 m |
| 19843 |
< |
793 448 l |
| 19844 |
< |
893 438 m |
| 19845 |
< |
893 448 l |
| 19846 |
< |
993 438 m |
| 19847 |
< |
993 448 l |
| 19848 |
< |
1093 438 m |
| 19849 |
< |
1093 448 l |
| 19850 |
< |
1194 438 m |
| 19851 |
< |
1194 448 l |
| 19852 |
< |
1294 438 m |
| 19853 |
< |
1294 448 l |
| 19854 |
< |
1394 438 m |
| 19855 |
< |
1394 448 l |
| 19856 |
< |
1495 438 m |
| 19857 |
< |
1495 448 l |
| 19858 |
< |
1595 438 m |
| 19859 |
< |
1595 448 l |
| 19860 |
< |
1695 438 m |
| 19861 |
< |
1695 448 l |
| 19862 |
< |
1796 438 m |
| 19863 |
< |
1796 448 l |
| 19864 |
< |
1896 438 m |
| 19865 |
< |
1896 448 l |
| 19866 |
< |
1996 438 m |
| 19867 |
< |
1996 448 l |
| 19868 |
< |
2097 438 m |
| 19869 |
< |
2097 448 l |
| 19870 |
< |
2197 438 m |
| 19871 |
< |
2197 448 l |
| 19872 |
< |
2297 438 m |
| 19873 |
< |
2297 448 l |
| 19874 |
< |
2397 438 m |
| 19875 |
< |
2397 448 l |
| 19876 |
< |
2498 438 m |
| 19877 |
< |
2498 448 l |
| 19878 |
< |
2598 438 m |
| 19879 |
< |
2598 448 l |
| 19880 |
< |
2698 438 m |
| 19881 |
< |
2698 448 l |
| 19882 |
< |
592 2127 m |
| 19883 |
< |
592 2117 l |
| 19884 |
< |
692 2127 m |
| 19885 |
< |
692 2117 l |
| 19886 |
< |
793 2127 m |
| 19887 |
< |
793 2117 l |
| 19888 |
< |
893 2127 m |
| 19889 |
< |
893 2117 l |
| 19890 |
< |
993 2127 m |
| 19891 |
< |
993 2117 l |
| 19892 |
< |
1093 2127 m |
| 19893 |
< |
1093 2117 l |
| 19894 |
< |
1194 2127 m |
| 19895 |
< |
1194 2117 l |
| 19896 |
< |
1294 2127 m |
| 19897 |
< |
1294 2117 l |
| 19898 |
< |
1394 2127 m |
| 19899 |
< |
1394 2117 l |
| 19900 |
< |
1495 2127 m |
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< |
1495 2117 l |
| 19902 |
< |
1595 2127 m |
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< |
1595 2117 l |
| 19904 |
< |
1695 2127 m |
| 19905 |
< |
1695 2117 l |
| 19906 |
< |
1796 2127 m |
| 19907 |
< |
1796 2117 l |
| 19908 |
< |
1896 2127 m |
| 19909 |
< |
1896 2117 l |
| 19910 |
< |
1996 2127 m |
| 19911 |
< |
1996 2117 l |
| 19912 |
< |
2097 2127 m |
| 19913 |
< |
2097 2117 l |
| 19914 |
< |
2197 2127 m |
| 19915 |
< |
2197 2117 l |
| 19916 |
< |
2297 2127 m |
| 19917 |
< |
2297 2117 l |
| 19918 |
< |
2397 2127 m |
| 19919 |
< |
2397 2117 l |
| 19920 |
< |
2498 2127 m |
| 19921 |
< |
2498 2117 l |
| 19922 |
< |
2598 2127 m |
| 19923 |
< |
2598 2117 l |
| 19924 |
< |
2698 2127 m |
| 19925 |
< |
2698 2117 l |
| 19926 |
< |
s |
| 19927 |
< |
592 438 m |
| 19928 |
< |
592 458 l |
| 19929 |
< |
893 438 m |
| 19930 |
< |
893 458 l |
| 19931 |
< |
1194 438 m |
| 19932 |
< |
1194 458 l |
| 19933 |
< |
1495 438 m |
| 19934 |
< |
1495 458 l |
| 19935 |
< |
1796 438 m |
| 19936 |
< |
1796 458 l |
| 19937 |
< |
2097 438 m |
| 19938 |
< |
2097 458 l |
| 19939 |
< |
2397 438 m |
| 19940 |
< |
2397 458 l |
| 19941 |
< |
2698 438 m |
| 19942 |
< |
2698 458 l |
| 19943 |
< |
592 2127 m |
| 19944 |
< |
592 2107 l |
| 19945 |
< |
893 2127 m |
| 19946 |
< |
893 2107 l |
| 19947 |
< |
1194 2127 m |
| 19948 |
< |
1194 2107 l |
| 19949 |
< |
1495 2127 m |
| 19950 |
< |
1495 2107 l |
| 19951 |
< |
1796 2127 m |
| 19952 |
< |
1796 2107 l |
| 19953 |
< |
2097 2127 m |
| 19954 |
< |
2097 2107 l |
| 19955 |
< |
2397 2127 m |
| 19956 |
< |
2397 2107 l |
| 19957 |
< |
2698 2127 m |
| 19958 |
< |
2698 2107 l |
| 19959 |
< |
/Times-Italic-ISOLatin1 findfont 60 scalefont setfont |
| 19960 |
< |
/Times-Roman-ISOLatin1 findfont 60 scalefont setfont |
| 19961 |
< |
s |
| 19962 |
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592 388 m |
| 19963 |
< |
gsave |
| 19964 |
< |
592 388 translate |
| 19965 |
< |
0 rotate |
| 19966 |
< |
0 -20 m |
| 19967 |
< |
(150) CS |
| 19968 |
< |
(150) show |
| 19969 |
< |
grestore |
| 19970 |
< |
newpath |
| 19971 |
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893 388 m |
| 19972 |
< |
gsave |
| 19973 |
< |
893 388 translate |
| 19974 |
< |
0 rotate |
| 19975 |
< |
0 -20 m |
| 19976 |
< |
(180) CS |
| 19977 |
< |
(180) show |
| 19978 |
< |
grestore |
| 19979 |
< |
newpath |
| 19980 |
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1194 388 m |
| 19981 |
< |
gsave |
| 19982 |
< |
1194 388 translate |
| 19983 |
< |
0 rotate |
| 19984 |
< |
0 -20 m |
| 19985 |
< |
(210) CS |
| 19986 |
< |
(210) show |
| 19987 |
< |
grestore |
| 19988 |
< |
newpath |
| 19989 |
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1495 388 m |
| 19990 |
< |
gsave |
| 19991 |
< |
1495 388 translate |
| 19992 |
< |
0 rotate |
| 19993 |
< |
0 -20 m |
| 19994 |
< |
(240) CS |
| 19995 |
< |
(240) show |
| 19996 |
< |
grestore |
| 19997 |
< |
newpath |
| 19998 |
< |
1796 388 m |
| 19999 |
< |
gsave |
| 20000 |
< |
1796 388 translate |
| 20001 |
< |
0 rotate |
| 20002 |
< |
0 -20 m |
| 20003 |
< |
(270) CS |
| 20004 |
< |
(270) show |
| 20005 |
< |
grestore |
| 20006 |
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newpath |
| 20007 |
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2097 388 m |
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gsave |
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2097 388 translate |
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| 20011 |
< |
0 -20 m |
| 20012 |
< |
(300) CS |
| 20013 |
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(300) show |
| 20014 |
< |
grestore |
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newpath |
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2397 388 m |
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gsave |
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2397 388 translate |
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| 20020 |
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0 -20 m |
| 20021 |
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(330) CS |
| 20022 |
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(330) show |
| 20023 |
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grestore |
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newpath |
| 20025 |
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2698 388 m |
| 20026 |
< |
gsave |
| 20027 |
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2698 388 translate |
| 20028 |
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| 20029 |
< |
0 -20 m |
| 20030 |
< |
(360) CS |
| 20031 |
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(360) show |
| 20032 |
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grestore |
| 20033 |
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newpath |
| 20034 |
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/Times-Roman-ISOLatin1 findfont 60 scalefont setfont |
| 20035 |
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1645 288 m |
| 20036 |
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gsave |
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1645 288 translate |
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| 20039 |
< |
0 0 m |
| 20040 |
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(T \(K\)) CS |
| 20041 |
< |
(T \(K\)) show |
| 20042 |
< |
grestore |
| 20043 |
< |
newpath |
| 20044 |
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542 438 m |
| 20045 |
< |
552 438 l |
| 20046 |
< |
542 532 m |
| 20047 |
< |
552 532 l |
| 20048 |
< |
542 626 m |
| 20049 |
< |
552 626 l |
| 20050 |
< |
542 720 m |
| 20051 |
< |
552 720 l |
| 20052 |
< |
542 813 m |
| 20053 |
< |
552 813 l |
| 20054 |
< |
542 907 m |
| 20055 |
< |
552 907 l |
| 20056 |
< |
542 1001 m |
| 20057 |
< |
552 1001 l |
| 20058 |
< |
542 1095 m |
| 20059 |
< |
552 1095 l |
| 20060 |
< |
542 1189 m |
| 20061 |
< |
552 1189 l |
| 20062 |
< |
542 1282 m |
| 20063 |
< |
552 1282 l |
| 20064 |
< |
542 1376 m |
| 20065 |
< |
552 1376 l |
| 20066 |
< |
542 1470 m |
| 20067 |
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552 1470 l |
| 20068 |
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542 1564 m |
| 20069 |
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552 1564 l |
| 20070 |
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542 1658 m |
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552 1658 l |
| 20072 |
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542 1751 m |
| 20073 |
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552 1751 l |
| 20074 |
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542 1845 m |
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552 1845 l |
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542 1939 m |
| 20077 |
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552 1939 l |
| 20078 |
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542 2033 m |
| 20079 |
< |
552 2033 l |
| 20080 |
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542 2127 m |
| 20081 |
< |
552 2127 l |
| 20082 |
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2749 438 m |
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2739 438 l |
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2749 532 m |
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2739 532 l |
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2749 626 m |
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2739 1095 l |
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| 20100 |
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2739 1282 l |
| 20102 |
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2749 1376 m |
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2739 1376 l |
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2749 1470 m |
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< |
2739 1470 l |
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2749 1564 m |
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2739 1564 l |
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2749 1658 m |
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2739 1658 l |
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< |
2749 1751 m |
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< |
2739 1751 l |
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2749 1845 m |
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< |
2739 1845 l |
| 20114 |
< |
2749 1939 m |
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< |
2739 1939 l |
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< |
2749 2033 m |
| 20117 |
< |
2739 2033 l |
| 20118 |
< |
2749 2127 m |
| 20119 |
< |
2739 2127 l |
| 20120 |
< |
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| 20121 |
< |
542 438 m |
| 20122 |
< |
562 438 l |
| 20123 |
< |
542 626 m |
| 20124 |
< |
562 626 l |
| 20125 |
< |
542 813 m |
| 20126 |
< |
562 813 l |
| 20127 |
< |
542 1001 m |
| 20128 |
< |
562 1001 l |
| 20129 |
< |
542 1189 m |
| 20130 |
< |
562 1189 l |
| 20131 |
< |
542 1376 m |
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< |
562 1376 l |
| 20133 |
< |
542 1564 m |
| 20134 |
< |
562 1564 l |
| 20135 |
< |
542 1751 m |
| 20136 |
< |
562 1751 l |
| 20137 |
< |
542 1939 m |
| 20138 |
< |
562 1939 l |
| 20139 |
< |
542 2127 m |
| 20140 |
< |
562 2127 l |
| 20141 |
< |
2749 438 m |
| 20142 |
< |
2729 438 l |
| 20143 |
< |
2749 626 m |
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< |
2729 626 l |
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< |
2749 813 m |
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< |
2729 813 l |
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2729 1001 l |
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< |
2749 1189 m |
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2729 1189 l |
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2749 1376 m |
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2729 1376 l |
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2749 1564 m |
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2729 1564 l |
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2749 1751 m |
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2729 1751 l |
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2749 1939 m |
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< |
2729 1939 l |
| 20159 |
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2749 2127 m |
| 20160 |
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2729 2127 l |
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/Times-Roman-ISOLatin1 findfont 60 scalefont setfont |
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gsave |
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0 rotate |
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0 -20 m |
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(0.8) RJ |
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506 626 m |
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gsave |
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0 -20 m |
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grestore |
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506 813 m |
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< |
gsave |
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506 813 translate |
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< |
0 -20 m |
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(0.84) RJ |
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< |
grestore |
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< |
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< |
gsave |
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< |
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< |
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< |
0 -20 m |
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< |
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< |
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< |
grestore |
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< |
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506 1189 m |
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grestore |
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gsave |
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gsave |
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gsave |
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< |
gsave |
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< |
grestore |
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gsave |
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0 rotate |
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0 -20 m |
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grestore |
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352 1282 m |
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gsave |
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90 rotate |
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/Symbol findfont |
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60 scalefont |
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< |
setfont |
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/Times-Roman-ISOLatin1 findfont 60 scalefont setfont |
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< |
@endspecial 3590 -166 a |
| 12411 |
> |
@endspecial 1302 -166 a |
| 12412 |
|
currentpoint grestore moveto |
| 12413 |
< |
3590 -166 a 2042 1513 a Fr(FIG.)28 |
| 12414 |
< |
b(2:)38 b(Av)n(erage)28 b(densit)n(y)e(of)j(SSD)d(w)n(ater)i(at)g |
| 12415 |
< |
(increasing)h(temp)r(er-)2042 1600 y(atures)d(starting)g(from)g(ice)g |
| 12416 |
< |
Fq(I)2890 1609 y Fp(h)2955 1600 y Fr(lattice.)2042 1880 |
| 12417 |
< |
y Fu(\014xed)d(p)r(ositions)f(with)i(angular)d(momen)n(ta)i(randomized) |
| 12418 |
< |
f(at)h(400)2042 1975 y(K)40 b(for)g(v)-5 b(arying)39 |
| 12419 |
< |
b(times.)75 b(The)40 b(rotational)f(temp)r(erature)h(w)n(as)2042 |
| 12420 |
< |
2071 y(then)f(scaled)g(do)n(wn)g(in)g(stages)f(to)h(slo)n(wly)f(co)r |
| 12421 |
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(ol)h(the)h(crystals)2042 2166 y(do)n(wn)27 b(to)g(25)f(K.)h(The)h |
| 12422 |
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(particles)e(w)n(ere)g(then)i(allo)n(w)n(ed)e(translate)2042 |
| 12423 |
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2262 y(with)35 b(\014xed)f(orien)n(tations)f(at)h(a)g(constan)n(t)g |
| 12424 |
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(pressure)f(of)h(1)g(atm)2042 2357 y(for)d(50)f(ps)i(at)f(25)f(K.)i |
| 12425 |
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(Finally)-7 b(,)32 b(all)f(constrain)n(ts)f(w)n(ere)h(remo)n(v)n(ed) |
| 12426 |
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2042 2453 y(and)26 b(the)i(ice)e(crystals)g(w)n(ere)g(allo)n(w)n(ed)f |
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(to)i(equilibrate)f(for)g(50)g(ps)2042 2548 y(at)32 b(25)g(K)h(and)g(a) |
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f(constan)n(t)g(pressure)g(of)g(1)h(atm.)52 b(This)33 |
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< |
b(pro)r(ce-)2042 2644 y(dure)i(resulted)g(in)h(structurally)f(stable)g |
| 12430 |
< |
Fj(I)3409 2656 y Fi(h)3488 2644 y Fu(ice)h(crystals)e(that)2042 |
| 12431 |
< |
2739 y(ob)r(ey)26 b(the)g(Bernal-F)-7 b(o)n(wler)24 b(rules)3084 |
| 12432 |
< |
2709 y Fn(17,18)3239 2739 y Fu(.)36 b(This)26 b(metho)r(d)h(w)n(as)e |
| 12433 |
< |
(also)2042 2835 y(utilized)j(in)h(the)f(making)f(of)h(diamond)g |
| 12434 |
< |
(lattice)g Fj(I)3598 2847 y Fi(c)3661 2835 y Fu(ice)f(crystals,)2042 |
| 12435 |
< |
2930 y(with)22 b(eac)n(h)f(cubic)h(sim)n(ulation)f(b)r(o)n(x)g |
| 12436 |
< |
(consisting)g(of)g(either)h(512)e(or)2042 3026 y(1000)30 |
| 12437 |
< |
b(particles.)51 b(Only)32 b(isotropic)f(v)n(olume)h(\015uctuations)g(w) |
| 12438 |
< |
n(ere)2042 3121 y(p)r(erformed)e(under)h(constan)n(t)f(pressure,)h(so)f |
| 12439 |
< |
(the)i(ratio)e(of)h(edge)2042 3217 y(lengths)c(remained)g(constan)n(t)g |
| 12440 |
< |
(throughout)g(the)h(sim)n(ulations.)2349 3493 y Fo(I)r(I)r(I.)90 |
| 12441 |
< |
b(RESUL)-7 b(TS)29 b(AND)g(DISCUSSION)2125 3706 y Fu(Melting)c(studies) |
| 12442 |
< |
g(w)n(ere)g(p)r(erformed)f(on)h(the)h(randomized)e(ice)2042 |
| 12443 |
< |
3802 y(crystals)18 b(using)i(constan)n(t)f(pressure)f(and)i(temp)r |
| 12444 |
< |
(erature)g(dynam-)2042 3897 y(ics.)84 b(This)44 b(in)n(v)n(olv)n(ed)e |
| 12445 |
< |
(an)h(initial)h(randomization)e(of)h(v)n(elo)r(ci-)2042 |
| 12446 |
< |
3993 y(ties)31 b(ab)r(out)h(the)f(starting)g(temp)r(erature)g(of)g(25)g |
| 12447 |
< |
(K)g(for)f(v)-5 b(arying)2042 4088 y(amoun)n(ts)31 b(of)i(time.)51 |
| 12448 |
< |
b(The)33 b(systems)e(w)n(ere)h(all)g(equilibrated)g(for)2042 |
| 12449 |
< |
4184 y(100)25 b(ps)h(prior)f(to)i(a)f(200)f(ps)h(data)g(collection)g |
| 12450 |
< |
(run)g(at)g(eac)n(h)g(tem-)2042 4279 y(p)r(erature)g(setting,)h |
| 12451 |
< |
(ranging)f(from)h(25)f(to)h(400)f(K,)h(with)g(a)g(max-)2042 |
| 12452 |
< |
4375 y(im)n(um)33 b(degree)f(incremen)n(t)h(of)g(25)f(K.)h(F)-7 |
| 12453 |
< |
b(or)32 b(regions)g(of)h(in)n(terest)2042 4470 y(along)i(this)i(step)n |
| 12454 |
< |
(wise)f(progression,)g(the)h(temp)r(erature)f(incre-)2042 |
| 12455 |
< |
4566 y(men)n(t)28 b(w)n(as)g(decreased)f(from)h(25)f(K)h(to)h(10)e(and) |
| 12456 |
< |
h(then)h(5)f(K.)g(The)2042 4661 y(ab)r(o)n(v)n(e)e(equilibration)i(and) |
| 12413 |
> |
1302 -166 a -150 1418 a Fr(FIG.)26 |
| 12414 |
> |
b(1:)34 b(Energy)26 b(conserv)l(ation)g(using)f(quaternion)h(based)f |
| 12415 |
> |
(in)n(tegra-)-150 1505 y(tion)i(v)n(ersus)g(the)f(symplectic)h(step)f |
| 12416 |
> |
(metho)r(d)g(prop)r(osed)h(b)n(y)f(Dullw)n(e-)-150 1592 |
| 12417 |
> |
y(b)r(er)h Fs(et)j(al.)39 b Fr(with)27 b(increasing)i(time)e(step.)39 |
| 12418 |
> |
b(F)-6 b(or)27 b(eac)n(h)h(time)f(step,)h(the)-150 1680 |
| 12419 |
> |
y(dotted)f(line)h(is)g(total)g(energy)f(using)h(the)f(symplectic)g |
| 12420 |
> |
(step)g(in)n(tegra-)-150 1767 y(tor,)h(and)e(the)h(solid)h(line)f |
| 12421 |
> |
(comes)g(from)g(the)f(quaternion)h(in)n(tegrator.)-150 |
| 12422 |
> |
1854 y(The)22 b(larger)h(time)e(step)g(plots)h(are)h(shifted)f(up)e |
| 12423 |
> |
(from)i(the)f(true)g(energy)-150 1941 y(baseline)27 b(for)f(clarit)n(y) |
| 12424 |
> |
-6 b(.)-150 2221 y Fu(arithmetic)28 b(quaternion)f(propagation.)35 |
| 12425 |
> |
b(With)29 b(the)g(same)e(time)-150 2317 y(step,)22 b(a)d(1000)f(SSD)i |
| 12426 |
> |
(particle)f(sim)n(ulation)h(sho)n(ws)e(an)i(a)n(v)n(erage)d(7\045)-150 |
| 12427 |
> |
2412 y(increase)32 b(in)i(computation)f(time)h(using)f(the)h |
| 12428 |
> |
(symplectic)f(step)-150 2508 y(metho)r(d)e(in)h(place)e(of)h |
| 12429 |
> |
(quaternions.)45 b(This)31 b(cost)f(is)h(more)f(than)-150 |
| 12430 |
> |
2603 y(justi\014ed)f(when)g(comparing)e(the)i(energy)f(conserv)-5 |
| 12431 |
> |
b(ation)27 b(of)h(the)-150 2699 y(t)n(w)n(o)f(metho)r(ds)h(as)f |
| 12432 |
> |
(illustrated)g(in)h(\014gure)f(1.)-67 2794 y(In)33 b(\014gure)f(1,)i |
| 12433 |
> |
(the)f(resulting)f(energy)g(drift)h(at)f(v)-5 b(arious)32 |
| 12434 |
> |
b(time)-150 2890 y(steps)h(for)f(b)r(oth)h(the)g(symplectic)g(step)f |
| 12435 |
> |
(and)h(quaternion)f(in)n(te-)-150 2985 y(gration)25 b(sc)n(hemes)h(is)g |
| 12436 |
> |
(compared.)36 b(All)27 b(of)f(the)h(1000)e(SSD)i(parti-)-150 |
| 12437 |
> |
3081 y(cle)g(sim)n(ulations)g(started)g(with)h(the)g(same)f |
| 12438 |
> |
(con\014guration,)f(and)-150 3176 y(the)40 b(only)f(di\013erence)h(w)n |
| 12439 |
> |
(as)f(the)h(metho)r(d)g(for)f(handling)h(rota-)-150 3272 |
| 12440 |
> |
y(tional)i(motion.)79 b(A)n(t)42 b(time)h(steps)f(of)f(0.1)g(and)h(0.5) |
| 12441 |
> |
f(fs,)46 b(b)r(oth)-150 3367 y(metho)r(ds)37 b(for)g(propagating)e |
| 12442 |
> |
(particle)h(rotation)g(conserv)n(e)g(en-)-150 3463 y(ergy)31 |
| 12443 |
> |
b(fairly)i(w)n(ell,)g(with)g(the)g(quaternion)f(metho)r(d)h(sho)n(wing) |
| 12444 |
> |
f(a)-150 3558 y(sligh)n(t)d(energy)g(drift)h(o)n(v)n(er)d(time)j(in)g |
| 12445 |
> |
(the)g(0.5)f(fs)h(time)g(step)g(sim-)-150 3653 y(ulation.)47 |
| 12446 |
> |
b(A)n(t)31 b(time)h(steps)f(of)g(1)f(and)h(2)g(fs,)h(the)f(energy)f |
| 12447 |
> |
(conser-)-150 3749 y(v)-5 b(ation)25 b(b)r(ene\014ts)h(of)g(the)g |
| 12448 |
> |
(symplectic)f(step)h(metho)r(d)g(are)f(clearly)-150 3844 |
| 12449 |
> |
y(demonstrated.)36 b(Th)n(us,)27 b(while)g(main)n(taining)g(the)g(same) |
| 12450 |
> |
f(degree)-150 3940 y(of)h(energy)f(conserv)-5 b(ation,)26 |
| 12451 |
> |
b(one)h(can)g(tak)n(e)f(considerably)g(longer)-150 4035 |
| 12452 |
> |
y(time)34 b(steps,)g(leading)f(to)g(an)g(o)n(v)n(erall)e(reduction)i |
| 12453 |
> |
(in)g(computa-)-150 4131 y(tion)28 b(time.)-67 4226 y(Energy)23 |
| 12454 |
> |
b(drift)j(in)f(these)g(SSD)g(particle)g(sim)n(ulations)f(w)n(as)f(un-) |
| 12455 |
> |
-150 4322 y(noticeable)36 b(for)h(time)g(steps)g(up)g(to)g(three)g(fem) |
| 12456 |
> |
n(toseconds.)64 b(A)-150 4417 y(sligh)n(t)40 b(energy)f(drift)i(on)f |
| 12457 |
> |
(the)h(order)e(of)h(0.012)f(k)n(cal/mol)f(p)r(er)-150 |
| 12458 |
> |
4513 y(nanosecond)21 b(w)n(as)h(observ)n(ed)g(at)g(a)h(time)g(step)g |
| 12459 |
> |
(of)g(four)f(fem)n(tosec-)-150 4608 y(onds,)34 b(and)f(as)g(exp)r |
| 12460 |
> |
(ected,)i(this)e(drift)h(increases)e(dramatically)-150 |
| 12461 |
> |
4704 y(with)24 b(increasing)e(time)i(step.)35 b(T)-7 |
| 12462 |
> |
b(o)23 b(insure)g(accuracy)f(in)h(the)h(con-)-150 4799 |
| 12463 |
> |
y(stan)n(t)j(energy)f(sim)n(ulations,)h(time)h(steps)f(w)n(ere)f(set)i |
| 12464 |
> |
(at)f(2)g(fs)h(and)-150 4895 y(k)n(ept)38 b(at)g(this)g(v)-5 |
| 12465 |
> |
b(alue)38 b(for)f(constan)n(t)g(pressure)g(sim)n(ulations)g(as)-150 |
| 12466 |
> |
4990 y(w)n(ell.)-67 5086 y(Ice)g(crystals)e(in)i(b)r(oth)g(the)h |
| 12467 |
> |
Fj(I)886 5098 y Fi(h)966 5086 y Fu(and)f Fj(I)1173 5098 |
| 12468 |
> |
y Fi(c)1244 5086 y Fu(lattices)f(w)n(ere)g(gen-)-150 |
| 12469 |
> |
5181 y(erated)k(as)g(starting)g(p)r(oin)n(ts)g(for)g(all)g(the)h(sim)n |
| 12470 |
> |
(ulations.)75 b(The)-150 5277 y Fj(I)-114 5289 y Fi(h)-38 |
| 12471 |
> |
5277 y Fu(crystals)31 b(w)n(ere)h(formed)g(b)n(y)g(\014rst)g(arranging) |
| 12472 |
> |
e(the)j(cen)n(ter)e(of)-150 5372 y(masses)21 b(of)i(the)g(SSD)g |
| 12473 |
> |
(particles)f(in)n(to)g(a)g(\\hexagonal")e(ice)i(lattice)2042 |
| 12474 |
> |
-83 y(of)30 b(1024)f(particles.)45 b(Because)30 b(of)g(the)h(crystal)f |
| 12475 |
> |
(structure)g(of)h Fj(I)4041 -71 y Fi(h)2042 12 y Fu(ice,)23 |
| 12476 |
> |
b(the)f(sim)n(ulation)f(b)r(o)n(x)g(assumed)g(a)g(rectangular)e(shap)r |
| 12477 |
> |
(e)j(with)2042 108 y(a)43 b(edge)g(length)g(ratio)g(of)g(appro)n |
| 12478 |
> |
(ximately)f(1.00)p Ff(\002)p Fu(1.06)p Ff(\002)p Fu(1.23.)2042 |
| 12479 |
> |
203 y(The)c(particles)g(w)n(ere)g(then)h(allo)n(w)n(ed)e(to)h(orien)n |
| 12480 |
> |
(t)g(freely)g(ab)r(out)2042 299 y(\014xed)23 b(p)r(ositions)f(with)i |
| 12481 |
> |
(angular)d(momen)n(ta)i(randomized)f(at)h(400)2042 394 |
| 12482 |
> |
y(K)40 b(for)g(v)-5 b(arying)39 b(times.)75 b(The)40 |
| 12483 |
> |
b(rotational)f(temp)r(erature)h(w)n(as)2042 490 y(then)f(scaled)g(do)n |
| 12484 |
> |
(wn)g(in)g(stages)f(to)h(slo)n(wly)f(co)r(ol)h(the)h(crystals)2042 |
| 12485 |
> |
585 y(do)n(wn)27 b(to)g(25)f(K.)h(The)h(particles)e(w)n(ere)g(then)i |
| 12486 |
> |
(allo)n(w)n(ed)e(translate)2042 681 y(with)35 b(\014xed)f(orien)n |
| 12487 |
> |
(tations)f(at)h(a)g(constan)n(t)g(pressure)f(of)h(1)g(atm)2042 |
| 12488 |
> |
776 y(for)d(50)f(ps)i(at)f(25)f(K.)i(Finally)-7 b(,)32 |
| 12489 |
> |
b(all)f(constrain)n(ts)f(w)n(ere)h(remo)n(v)n(ed)2042 |
| 12490 |
> |
872 y(and)26 b(the)i(ice)e(crystals)g(w)n(ere)g(allo)n(w)n(ed)f(to)i |
| 12491 |
> |
(equilibrate)f(for)g(50)g(ps)2042 967 y(at)32 b(25)g(K)h(and)g(a)f |
| 12492 |
> |
(constan)n(t)g(pressure)g(of)g(1)h(atm.)52 b(This)33 |
| 12493 |
> |
b(pro)r(ce-)2042 1063 y(dure)i(resulted)g(in)h(structurally)f(stable)g |
| 12494 |
> |
Fj(I)3409 1075 y Fi(h)3488 1063 y Fu(ice)h(crystals)e(that)2042 |
| 12495 |
> |
1158 y(ob)r(ey)26 b(the)g(Bernal-F)-7 b(o)n(wler)24 b(rules)3084 |
| 12496 |
> |
1128 y Fn(17,18)3239 1158 y Fu(.)36 b(This)26 b(metho)r(d)h(w)n(as)e |
| 12497 |
> |
(also)2042 1254 y(utilized)j(in)h(the)f(making)f(of)h(diamond)g |
| 12498 |
> |
(lattice)g Fj(I)3598 1266 y Fi(c)3661 1254 y Fu(ice)f(crystals,)2042 |
| 12499 |
> |
1349 y(with)22 b(eac)n(h)f(cubic)h(sim)n(ulation)f(b)r(o)n(x)g |
| 12500 |
> |
(consisting)g(of)g(either)h(512)e(or)2042 1445 y(1000)30 |
| 12501 |
> |
b(particles.)51 b(Only)32 b(isotropic)f(v)n(olume)h(\015uctuations)g(w) |
| 12502 |
> |
n(ere)2042 1540 y(p)r(erformed)e(under)h(constan)n(t)f(pressure,)h(so)f |
| 12503 |
> |
(the)i(ratio)e(of)h(edge)2042 1636 y(lengths)c(remained)g(constan)n(t)g |
| 12504 |
> |
(throughout)g(the)h(sim)n(ulations.)2349 1912 y Fo(I)r(I)r(I.)90 |
| 12505 |
> |
b(RESUL)-7 b(TS)29 b(AND)g(DISCUSSION)2125 2125 y Fu(Melting)c(studies) |
| 12506 |
> |
g(w)n(ere)g(p)r(erformed)f(on)h(the)h(randomized)e(ice)2042 |
| 12507 |
> |
2221 y(crystals)18 b(using)i(constan)n(t)f(pressure)f(and)i(temp)r |
| 12508 |
> |
(erature)g(dynam-)2042 2316 y(ics.)84 b(This)44 b(in)n(v)n(olv)n(ed)e |
| 12509 |
> |
(an)h(initial)h(randomization)e(of)h(v)n(elo)r(ci-)2042 |
| 12510 |
> |
2412 y(ties)31 b(ab)r(out)h(the)f(starting)g(temp)r(erature)g(of)g(25)g |
| 12511 |
> |
(K)g(for)f(v)-5 b(arying)2042 2507 y(amoun)n(ts)31 b(of)i(time.)51 |
| 12512 |
> |
b(The)33 b(systems)e(w)n(ere)h(all)g(equilibrated)g(for)2042 |
| 12513 |
> |
2603 y(100)25 b(ps)h(prior)f(to)i(a)f(200)f(ps)h(data)g(collection)g |
| 12514 |
> |
(run)g(at)g(eac)n(h)g(tem-)2042 2698 y(p)r(erature)g(setting,)h |
| 12515 |
> |
(ranging)f(from)h(25)f(to)h(400)f(K,)h(with)g(a)g(max-)2042 |
| 12516 |
> |
2794 y(im)n(um)33 b(degree)f(incremen)n(t)h(of)g(25)f(K.)h(F)-7 |
| 12517 |
> |
b(or)32 b(regions)g(of)h(in)n(terest)2042 2889 y(along)i(this)i(step)n |
| 12518 |
> |
(wise)f(progression,)g(the)h(temp)r(erature)f(incre-)2042 |
| 12519 |
> |
2985 y(men)n(t)28 b(w)n(as)g(decreased)f(from)h(25)f(K)h(to)h(10)e(and) |
| 12520 |
> |
h(then)h(5)f(K.)g(The)2042 3080 y(ab)r(o)n(v)n(e)e(equilibration)i(and) |
| 12521 |
|
f(pro)r(duction)h(times)g(w)n(ere)f(su\016cien)n(t)2042 |
| 12522 |
< |
4757 y(in)g(that)g(the)g(system)f(v)n(olume)g(\015uctuations)h(damp)r |
| 12523 |
< |
(ened)g(out)g(in)2042 4852 y(all)34 b(but)g(the)h(v)n(ery)e(cold)g(sim) |
| 12524 |
< |
n(ulations)g(\(b)r(elo)n(w)h(225)f(K\).)h(In)g(or-)2042 |
| 12525 |
< |
4948 y(der)23 b(to)h(further)g(impro)n(v)n(e)e(statistics,)j(\014v)n(e) |
| 12526 |
< |
e(separate)g(sim)n(ulation)2042 5043 y(progressions)37 |
| 12527 |
< |
b(w)n(ere)i(p)r(erformed,)k(and)d(the)g(a)n(v)n(eraged)e(results)2042 |
| 12528 |
< |
5138 y(from)27 b(the)h Fj(I)2417 5150 y Fi(h)2488 5138 |
| 12529 |
< |
y Fu(melting)g(sim)n(ulations)f(are)f(sho)n(wn)h(in)h(\014gure)f(2.)p |
| 12530 |
< |
eop |
| 12522 |
> |
3175 y(in)g(that)g(the)g(system)f(v)n(olume)g(\015uctuations)h(damp)r |
| 12523 |
> |
(ened)g(out)g(in)2042 3271 y(all)e(but)h(the)f(v)n(ery)f(cold)h(sim)n |
| 12524 |
> |
(ulations)g(\(b)r(elo)n(w)g(225)f(K\).)h(In)h(order)2042 |
| 12525 |
> |
3366 y(to)38 b(further)g(impro)n(v)n(e)f(statistics,)j(an)e(ensem)n |
| 12526 |
> |
(ble)g(a)n(v)n(erage)d(w)n(as)2042 3462 y(accum)n(ulated)30 |
| 12527 |
> |
b(from)h(\014v)n(e)f(separate)g(sim)n(ulation)g(progressions,)2042 |
| 12528 |
> |
3557 y(eac)n(h)d(starting)f(from)i(a)f(di\013eren)n(t)g(ice)h(crystal.) |
| 12529 |
> |
2638 3834 y Fo(A.)88 b(Densit)n(y)29 b(Beha)n(vior)2125 |
| 12530 |
> |
4047 y Fu(In)e(the)h(initial)g(a)n(v)n(erage)d(densit)n(y)i(v)n(ersus)f |
| 12531 |
> |
(temp)r(erature)h(plot,)2042 4143 y(the)34 b(densit)n(y)g(maxim)n(um)g |
| 12532 |
> |
(clearly)f(app)r(ears)g(b)r(et)n(w)n(een)i(255)d(and)2042 |
| 12533 |
> |
4238 y(265)i(K.)h(The)h(calculated)f(densities)h(within)g(this)g(range) |
| 12534 |
> |
e(w)n(ere)2042 4334 y(nearly)f(indistinguishable,)i(as)e(can)g(b)r(e)h |
| 12535 |
> |
(seen)g(in)g(the)g(zo)r(om)f(of)2042 4429 y(this)g(region)f(of)h(in)n |
| 12536 |
> |
(terest,)h(sho)n(wn)e(in)h(\014gure)g Fh(??)p Fu(.)53 |
| 12537 |
> |
b(The)33 b(greater)2042 4525 y(certain)n(t)n(y)24 b(of)h(the)h(a)n(v)n |
| 12538 |
> |
(erage)c(v)-5 b(alue)26 b(at)f(260)f(K)h(mak)n(es)f(a)h(go)r(o)r(d)f |
| 12539 |
> |
(ar-)2042 4620 y(gumen)n(t)k(for)g(the)h(actual)f(densit)n(y)g(maxim)n |
| 12540 |
> |
(um)g(residing)g(at)g(this)2042 4715 y(midp)r(oin)n(t)j(v)-5 |
| 12541 |
> |
b(alue.)46 b(Figure)30 b Fh(??)i Fu(w)n(as)d(constructed)i(using)f(ice) |
| 12542 |
> |
h Fj(I)4041 4727 y Fi(h)2042 4811 y Fu(crystals)23 b(for)i(the)g |
| 12543 |
> |
(initial)g(con\014guration;)f(and)h(though)g(not)f(pic-)2042 |
| 12544 |
> |
4906 y(tured,)h(the)h(sim)n(ulations)e(starting)g(from)g(ice)h |
| 12545 |
> |
Fj(I)3517 4918 y Fi(c)3576 4906 y Fu(crystal)f(con\014g-)2042 |
| 12546 |
> |
5002 y(urations)h(sho)n(w)n(ed)h(similar)g(results,)g(with)h(a)f |
| 12547 |
> |
(liquid-phase)g(den-)2042 5097 y(sit)n(y)g(maxim)n(um)g(in)h(this)g |
| 12548 |
> |
(same)f(region)f(\(b)r(et)n(w)n(een)i(255)e(and)i(260)2042 |
| 12549 |
> |
5193 y(K\).)f(In)h(addition,)g(the)f Fj(I)2818 5205 y |
| 12550 |
> |
Fi(c)2879 5193 y Fu(crystals)g(are)f(more)h(fragile)f(than)i(the)2042 |
| 12551 |
> |
5288 y Fj(I)2078 5300 y Fi(h)2154 5288 y Fu(crystals,)34 |
| 12552 |
> |
b(leading)e(them)i(to)f(deform)f(in)n(to)h(a)g(dense)g(glassy)2042 |
| 12553 |
> |
5384 y(state)d(at)g(lo)n(w)n(er)f(temp)r(eratures.)45 |
| 12554 |
> |
b(This)30 b(resulted)h(in)f(an)g(o)n(v)n(erall)p eop |
| 12555 |
|
%%Page: 4 4 |
| 12556 |
|
4 3 bop 4043 -299 a Fu(4)-150 -166 y |
| 12557 |
|
gsave currentpoint currentpoint translate -90 neg rotate neg exch |
| 21676 |
|
@endspecial 1385 -166 a |
| 21677 |
|
currentpoint grestore moveto |
| 21678 |
|
1385 -166 a -150 1525 a Fr(FIG.)81 |
| 21679 |
< |
b(3:)144 b(Densit)n(y)80 b(v)n(ersus)g(temp)r(erature)g(for)h(TIP4P) |
| 21679 |
> |
b(2:)144 b(Densit)n(y)80 b(v)n(ersus)g(temp)r(erature)g(for)h(TIP4P) |
| 21680 |
|
1805 1493 y Fc(19)1871 1525 y Fr(,)-150 1612 y(TIP3P)75 |
| 21681 |
|
1580 y Fc(19)141 1612 y Fr(,)33 b(SPC/E)435 1580 y Fc(20)501 |
| 21682 |
|
1612 y Fr(,)g(SSD)d(without)i(Reaction)f(Field,)j(SSD,)d(and)-150 |
| 21683 |
< |
1699 y(Exp)r(erimen)n(t)243 1667 y Fc(21)307 1699 y Fr(.)446 |
| 21684 |
< |
1979 y Fo(A.)88 b(Densit)n(y)29 b(Beha)n(vior)-67 2193 |
| 21685 |
< |
y Fu(In)f(the)g(initial)f(a)n(v)n(erage)e(densit)n(y)i(v)n(ersus)f |
| 21686 |
< |
(temp)r(erature)h(plot,)-150 2288 y(the)35 b(densit)n(y)f(maxim)n(um)g |
| 21687 |
< |
(clearly)f(app)r(ears)g(b)r(et)n(w)n(een)h(255)f(and)-150 |
| 21688 |
< |
2384 y(265)h(K.)i(The)f(calculated)g(densities)h(within)g(this)g(range) |
| 21689 |
< |
e(w)n(ere)-150 2479 y(nearly)f(indistinguishable,)i(as)e(can)g(b)r(e)i |
| 21690 |
< |
(seen)e(in)h(the)g(zo)r(om)f(of)-150 2575 y(this)38 b(region)e(of)h(in) |
| 21691 |
< |
n(terest,)i(sho)n(wn)e(in)h(\014gure)e(2.)66 b(The)37 |
| 21692 |
< |
b(greater)-150 2670 y(certain)n(t)n(y)24 b(of)h(the)h(a)n(v)n(erage)d |
| 21693 |
< |
(v)-5 b(alue)25 b(at)g(260)f(K)h(mak)n(es)f(a)h(go)r(o)r(d)g(ar-)-150 |
| 21694 |
< |
2766 y(gumen)n(t)j(for)g(the)h(actual)f(densit)n(y)g(maxim)n(um)g |
| 30069 |
< |
(residing)g(at)g(this)-150 2861 y(midp)r(oin)n(t)36 b(v)-5 |
| 30070 |
< |
b(alue.)61 b(Figure)35 b(2)g(w)n(as)g(constructed)g(using)g(ice)h |
| 30071 |
< |
Fj(I)1849 2873 y Fi(h)-150 2956 y Fu(crystals)24 b(for)g(the)h(initial) |
| 30072 |
< |
g(con\014guration;)f(and)h(though)g(not)g(pic-)-150 3052 |
| 30073 |
< |
y(tured,)h(the)f(sim)n(ulations)f(starting)g(from)h(ice)f |
| 30074 |
< |
Fj(I)1325 3064 y Fi(c)1385 3052 y Fu(crystal)f(con\014g-)-150 |
| 30075 |
< |
3147 y(urations)j(sho)n(w)n(ed)f(similar)h(results,)g(with)h(a)g |
| 30076 |
< |
(liquid-phase)f(den-)-150 3243 y(sit)n(y)g(maxim)n(um)h(in)f(this)h |
| 30077 |
< |
(same)f(region)f(\(b)r(et)n(w)n(een)i(255)e(and)i(260)-150 |
| 30078 |
< |
3338 y(K\).)f(In)h(addition,)g(the)g Fj(I)627 3350 y |
| 30079 |
< |
Fi(c)688 3338 y Fu(crystals)e(are)g(more)h(fragile)f(than)i(the)-150 |
| 30080 |
< |
3434 y Fj(I)-114 3446 y Fi(h)-37 3434 y Fu(crystals,)33 |
| 30081 |
< |
b(leading)f(them)i(to)f(deform)g(in)n(to)f(a)h(dense)g(glassy)-150 |
| 30082 |
< |
3529 y(state)d(at)h(lo)n(w)n(er)d(temp)r(eratures.)45 |
| 30083 |
< |
b(This)31 b(resulted)f(in)g(an)h(o)n(v)n(erall)-150 3625 |
| 30084 |
< |
y(lo)n(w)k(temp)r(erature)g(densit)n(y)h(maxim)n(um)g(at)f(200)f(K,)i |
| 30085 |
< |
(but)g(they)-150 3720 y(still)i(retained)g(a)g(common)f(liquid)i(state) |
| 30086 |
< |
f(densit)n(y)g(maxim)n(um)-150 3816 y(with)28 b(the)g |
| 30087 |
< |
Fj(I)218 3828 y Fi(h)289 3816 y Fu(sim)n(ulations.)-67 |
| 30088 |
< |
3911 y(The)19 b(densit)n(y)g(maxim)n(um)g(for)g(SSD)h(actually)e |
| 30089 |
< |
(compares)g(quite)-150 4007 y(fa)n(v)n(orably)h(to)j(other)f(simple)h |
| 30090 |
< |
(w)n(ater)f(mo)r(dels.)35 b(Figure)21 b(3)g(sho)n(ws)g(a)-150 |
| 30091 |
< |
4102 y(plot)j(of)g(these)f(\014ndings)h(with)g(the)h(densit)n(y)e |
| 30092 |
< |
(progression)e(of)j(sev-)-150 4198 y(eral)36 b(other)g(mo)r(dels)h(and) |
| 30093 |
< |
f(exp)r(erimen)n(t)h(obtained)g(from)f(other)-150 4293 |
| 30094 |
< |
y(sources.)134 4263 y Fn(19)o({21)328 4293 y Fu(Of)26 |
| 21683 |
> |
1699 y(Exp)r(erimen)n(t)243 1667 y Fc(21)307 1699 y Fr(.)-150 |
| 21684 |
> |
1979 y Fu(lo)n(w)k(temp)r(erature)g(densit)n(y)h(maxim)n(um)g(at)f(200) |
| 21685 |
> |
f(K,)i(but)g(they)-150 2075 y(still)i(retained)g(a)g(common)f(liquid)i |
| 21686 |
> |
(state)f(densit)n(y)g(maxim)n(um)-150 2170 y(with)28 |
| 21687 |
> |
b(the)g Fj(I)218 2182 y Fi(h)289 2170 y Fu(sim)n(ulations.)-67 |
| 21688 |
> |
2266 y(The)19 b(densit)n(y)g(maxim)n(um)g(for)g(SSD)h(actually)e |
| 21689 |
> |
(compares)g(quite)-150 2361 y(fa)n(v)n(orably)h(to)j(other)f(simple)h |
| 21690 |
> |
(w)n(ater)f(mo)r(dels.)35 b(Figure)21 b(2)g(sho)n(ws)g(a)-150 |
| 21691 |
> |
2456 y(plot)j(of)g(these)f(\014ndings)h(with)g(the)h(densit)n(y)e |
| 21692 |
> |
(progression)e(of)j(sev-)-150 2552 y(eral)36 b(other)g(mo)r(dels)h(and) |
| 21693 |
> |
f(exp)r(erimen)n(t)h(obtained)g(from)f(other)-150 2647 |
| 21694 |
> |
y(sources.)134 2617 y Fn(19)o({21)328 2647 y Fu(Of)26 |
| 21695 |
|
b(the)g(listed)g(simple)g(w)n(ater)f(mo)r(dels,)h(SSD)h(has)-150 |
| 21696 |
< |
4389 y(results)d(closest)g(to)h(the)g(exp)r(erimen)n(tally)f(observ)n |
| 21697 |
< |
(ed)f(w)n(ater)h(den-)-150 4484 y(sit)n(y)i(maxim)n(um.)36 |
| 21696 |
> |
2743 y(results)d(closest)g(to)h(the)g(exp)r(erimen)n(tally)f(observ)n |
| 21697 |
> |
(ed)f(w)n(ater)h(den-)-150 2838 y(sit)n(y)i(maxim)n(um.)36 |
| 21698 |
|
b(Of)27 b(the)g(listed)f(w)n(ater)f(mo)r(dels,)i(TIP4P)e(has)h(a)-150 |
| 21699 |
< |
4580 y(densit)n(y)32 b(maxim)n(um)g(b)r(eha)n(vior)f(most)h(lik)n(e)g |
| 21700 |
< |
(that)h(seen)f(in)h(SSD.)-150 4675 y(Though)25 b(not)h(sho)n(wn,)f(it)h |
| 21699 |
> |
2934 y(densit)n(y)32 b(maxim)n(um)g(b)r(eha)n(vior)f(most)h(lik)n(e)g |
| 21700 |
> |
(that)h(seen)f(in)h(SSD.)-150 3029 y(Though)25 b(not)h(sho)n(wn,)f(it)h |
| 21701 |
|
(is)g(useful)g(to)f(note)h(that)g(TIP5P)e(has)h(a)-150 |
| 21702 |
< |
4771 y(w)n(ater)i(densit)n(y)g(maxim)n(um)g(nearly)g(iden)n(tical)g(to) |
| 21703 |
< |
h(exp)r(erimen)n(t.)-67 4866 y(P)n(ossibly)j(of)i(more)g(imp)r(ortance) |
| 21704 |
< |
f(is)h(the)h(densit)n(y)e(scaling)g(of)-150 4961 y(SSD)27 |
| 21702 |
> |
3125 y(w)n(ater)i(densit)n(y)g(maxim)n(um)g(nearly)g(iden)n(tical)g(to) |
| 21703 |
> |
h(exp)r(erimen)n(t.)-67 3220 y(P)n(ossibly)j(of)i(more)g(imp)r(ortance) |
| 21704 |
> |
f(is)h(the)h(densit)n(y)e(scaling)g(of)-150 3316 y(SSD)27 |
| 21705 |
|
b(relativ)n(e)f(to)h(other)f(common)g(mo)r(dels)h(at)f(an)n(y)g(giv)n |
| 21706 |
< |
(en)g(tem-)-150 5057 y(p)r(erature)31 b(\(Fig.)48 b(3\).)f(Note)32 |
| 21707 |
< |
b(that)f(the)h(SSD)g(mo)r(del)g(assumes)e(a)-150 5152 |
| 21706 |
> |
(en)g(tem-)-150 3411 y(p)r(erature)31 b(\(Fig.)48 b(2\).)f(Note)32 |
| 21707 |
> |
b(that)f(the)h(SSD)g(mo)r(del)g(assumes)e(a)-150 3507 |
| 21708 |
|
y(lo)n(w)n(er)e(densit)n(y)h(than)g(an)n(y)f(of)h(the)h(other)e(listed) |
| 21709 |
< |
i(mo)r(dels)f(at)g(the)-150 5248 y(same)i(pressure,)h(b)r(eha)n(vior)e |
| 21709 |
> |
i(mo)r(dels)f(at)g(the)-150 3602 y(same)i(pressure,)h(b)r(eha)n(vior)e |
| 21710 |
|
(whic)n(h)i(is)g(esp)r(ecially)f(apparen)n(t)g(at)-150 |
| 21711 |
< |
5343 y(temp)r(eratures)h(greater)f(than)i(300)e(K.)h(Lo)n(w)n(er)f |
| 21712 |
< |
(than)i(exp)r(ected)2042 -83 y(densities)d(ha)n(v)n(e)e(b)r(een)j |
| 21713 |
< |
(observ)n(ed)d(for)i(other)f(systems)g(with)i(the)2042 |
| 21714 |
< |
12 y(use)h(of)h(a)f(reaction)g(\014eld)h(for)f(long-range)e |
| 21715 |
< |
(electrostatic)i(in)n(ter-)2042 108 y(actions,)g(so)g(the)g(most)g(lik) |
| 21716 |
< |
n(ely)g(reason)e(for)i(these)g(signi\014can)n(tly)2042 |
| 21717 |
< |
203 y(lo)n(w)n(er)23 b(densities)h(in)h(these)g(sim)n(ulations)e(is)i |
| 21718 |
< |
(the)g(presence)e(of)i(the)2042 299 y(reaction)f(\014eld.)2533 |
| 21719 |
< |
269 y Fn(12)2629 299 y Fu(In)h(order)f(to)h(test)g(the)h(e\013ect)g(of) |
| 21720 |
< |
f(the)g(reaction)2042 394 y(\014eld)j(on)g(the)h(densit)n(y)f(of)g(the) |
| 21721 |
< |
g(systems,)g(the)h(sim)n(ulations)e(w)n(ere)2042 490 |
| 21722 |
< |
y(rep)r(eated)32 b(for)g(the)i(temp)r(erature)e(region)g(of)g(in)n |
| 21723 |
< |
(terest)h(without)2042 585 y(a)27 b(reaction)g(\014eld)h(presen)n(t.)37 |
| 21724 |
< |
b(The)28 b(results)f(of)h(these)g(sim)n(ulations)2042 |
| 21725 |
< |
681 y(are)38 b(also)g(displa)n(y)n(ed)h(in)g(\014gure)g(3.)71 |
| 21726 |
< |
b(Without)41 b(reaction)d(\014eld,)2042 776 y(these)26 |
| 21727 |
< |
b(densities)f(increase)g(considerably)f(to)i(more)f(exp)r(erimen-)2042 |
| 21728 |
< |
872 y(tally)43 b(reasonable)e(v)-5 b(alues,)46 b(esp)r(ecially)d |
| 21729 |
< |
(around)e(the)j(freezing)2042 967 y(p)r(oin)n(t)37 b(of)g(liquid)h(w)n |
| 21730 |
< |
(ater.)64 b(The)38 b(shap)r(e)e(of)i(the)f(curv)n(e)f(is)h(simi-)2042 |
| 21731 |
< |
1063 y(lar)g(to)h(the)g(curv)n(e)f(pro)r(duced)h(from)g(SSD)g(sim)n |
| 21732 |
< |
(ulations)g(using)2042 1158 y(reaction)e(\014eld,)k(sp)r(eci\014cally)c |
| 21733 |
< |
(the)i(rapidly)e(decreasing)f(densi-)2042 1254 y(ties)24 |
| 21711 |
> |
3698 y(temp)r(eratures)h(greater)f(than)i(300)e(K.)h(Lo)n(w)n(er)f |
| 21712 |
> |
(than)i(exp)r(ected)-150 3793 y(densities)d(ha)n(v)n(e)f(b)r(een)h |
| 21713 |
> |
(observ)n(ed)e(for)i(other)f(systems)h(with)g(the)-150 |
| 21714 |
> |
3889 y(use)j(of)f(a)g(reaction)g(\014eld)h(for)f(long-range)e |
| 21715 |
> |
(electrostatic)i(in)n(ter-)-150 3984 y(actions,)h(so)e(the)i(most)e |
| 21716 |
> |
(lik)n(ely)h(reason)f(for)g(these)h(signi\014can)n(tly)-150 |
| 21717 |
> |
4080 y(lo)n(w)n(er)23 b(densities)h(in)h(these)g(sim)n(ulations)f(is)g |
| 21718 |
> |
(the)h(presence)f(of)g(the)-150 4175 y(reaction)g(\014eld.)341 |
| 21719 |
> |
4145 y Fn(12)437 4175 y Fu(In)h(order)f(to)h(test)h(the)f(e\013ect)h |
| 21720 |
> |
(of)f(the)h(reaction)-150 4271 y(\014eld)i(on)g(the)h(densit)n(y)f(of)g |
| 21721 |
> |
(the)h(systems,)e(the)i(sim)n(ulations)e(w)n(ere)-150 |
| 21722 |
> |
4366 y(rep)r(eated)32 b(for)h(the)g(temp)r(erature)f(region)g(of)h(in)n |
| 21723 |
> |
(terest)f(without)-150 4461 y(a)27 b(reaction)g(\014eld)h(presen)n(t.) |
| 21724 |
> |
37 b(The)28 b(results)g(of)f(these)h(sim)n(ulations)-150 |
| 21725 |
> |
4557 y(are)38 b(also)h(displa)n(y)n(ed)f(in)h(\014gure)g(2.)72 |
| 21726 |
> |
b(Without)40 b(reaction)e(\014eld,)-150 4652 y(these)26 |
| 21727 |
> |
b(densities)g(increase)e(considerably)g(to)i(more)f(exp)r(erimen-)-150 |
| 21728 |
> |
4748 y(tally)43 b(reasonable)e(v)-5 b(alues,)46 b(esp)r(ecially)d |
| 21729 |
> |
(around)f(the)h(freezing)-150 4843 y(p)r(oin)n(t)37 b(of)g(liquid)h(w)n |
| 21730 |
> |
(ater.)65 b(The)37 b(shap)r(e)g(of)g(the)g(curv)n(e)g(is)g(simi-)-150 |
| 21731 |
> |
4939 y(lar)g(to)h(the)g(curv)n(e)f(pro)r(duced)h(from)g(SSD)h(sim)n |
| 21732 |
> |
(ulations)e(using)-150 5034 y(reaction)f(\014eld,)k(sp)r(eci\014cally)c |
| 21733 |
> |
(the)i(rapidly)e(decreasing)g(densi-)-150 5130 y(ties)24 |
| 21734 |
|
b(at)g(higher)g(temp)r(eratures;)g(ho)n(w)n(ev)n(er,)f(a)h(sligh)n(t)g |
| 21735 |
< |
(shift)g(in)h(the)2042 1349 y(densit)n(y)30 b(maxim)n(um)g(lo)r |
| 21736 |
< |
(cation,)g(do)n(wn)f(to)h(245)f(K,)h(is)g(observ)n(ed.)2042 |
| 21737 |
< |
1445 y(This)21 b(is)f(probably)g(a)g(more)g(accurate)g(comparison)f(to) |
| 21738 |
< |
i(the)g(other)2042 1540 y(listed)f(w)n(ater)f(mo)r(dels)g(in)h(that)g |
| 30139 |
< |
(no)g(long)f(range)f(corrections)g(w)n(ere)2042 1636 |
| 30140 |
< |
y(applied)27 b(in)h(those)f(sim)n(ulations.)3079 1605 |
| 30141 |
< |
y Fn(19,20)2125 1731 y Fu(It)33 b(has)e(b)r(een)i(observ)n(ed)e(that)i |
| 30142 |
< |
(densities)f(are)f(dep)r(enden)n(t)i(on)2042 1826 y(the)j(cuto\013)h |
| 30143 |
< |
(radius)e(used)h(for)f(a)h(v)-5 b(ariet)n(y)35 b(of)h(w)n(ater)f(mo)r |
| 30144 |
< |
(dels)h(in)2042 1922 y(sim)n(ulations)g(b)r(oth)i(with)g(and)f(without) |
| 30145 |
< |
h(the)g(use)f(of)g(reaction)2042 2017 y(\014eld.)2217 |
| 30146 |
< |
1987 y Fn(12)2323 2017 y Fu(In)f(order)e(to)h(address)g(the)h(p)r |
| 30147 |
< |
(ossible)f(a\013ect)g(of)h(cuto\013)2042 2113 y(radius,)26 |
| 30148 |
< |
b(sim)n(ulations)g(w)n(ere)h(p)r(erformed)f(with)i(a)e(dip)r(olar)h |
| 30149 |
< |
(cuto\013)2042 2208 y(radius)j(of)g(12.0)2571 2193 y(\027)2571 |
| 30150 |
< |
2208 y(A)h(to)g(complimen)n(t)f(the)i(previous)d(SSD)j(sim)n(u-)2042 |
| 30151 |
< |
2304 y(lations,)e(all)g(p)r(erformed)g(with)h(a)f(cuto\013)g(of)g(9.0) |
| 30152 |
< |
3587 2289 y(\027)3587 2304 y(A.)h(All)f(the)h(re-)2042 |
| 30153 |
< |
2399 y(sulting)e(densities)h(o)n(v)n(erlapp)r(ed)e(within)j(error)c |
| 30154 |
< |
(and)j(sho)n(w)n(ed)e(no)2042 2495 y(signi\014can)n(t)21 |
| 30155 |
< |
b(trend)h(in)g(lo)n(w)n(er)f(or)g(higher)g(densities)i(as)e(a)h |
| 30156 |
< |
(function)2042 2590 y(of)33 b(cuto\013)h(radius,)h(b)r(oth)f(for)f(sim) |
| 30157 |
< |
n(ulations)g(with)h(and)g(without)2042 2686 y(reaction)39 |
| 30158 |
< |
b(\014eld.)77 b(These)40 b(results)g(indicate)h(that)g(there)f(is)g(no) |
| 30159 |
< |
2042 2781 y(ma)5 b(jor)26 b(b)r(ene\014t)i(in)f(c)n(ho)r(osing)f(a)h |
| 30160 |
< |
(longer)f(cuto\013)i(radius)e(in)i(sim)n(u-)2042 2877 |
| 30161 |
< |
y(lations)23 b(using)h(SSD.)h(This)f(is)g(comforting)f(in)h(that)g(the) |
| 30162 |
< |
h(use)f(of)g(a)2042 2972 y(longer)e(cuto\013)h(radius)f(results)h(in)g |
| 30163 |
< |
(a)g(near)f(doubling)h(of)g(the)h(time)2042 3068 y(required)i(to)i |
| 30164 |
< |
(compute)g(a)f(single)g(tra)5 b(jectory)-7 b(.)2596 3344 |
| 30165 |
< |
y Fo(B.)88 b(T)-7 b(ransp)r(ort)30 b(Beha)n(vior)2125 |
| 30166 |
< |
3557 y Fu(Of)f(imp)r(ortance)f(in)h(these)f(t)n(yp)r(es)h(of)g(studies) |
| 30167 |
< |
f(are)g(the)h(trans-)2042 3653 y(p)r(ort)44 b(prop)r(erties)f(of)h(the) |
| 30168 |
< |
g(particles)f(and)h(ho)n(w)f(they)h(c)n(hange)2042 3748 |
| 30169 |
< |
y(when)29 b(altering)f(the)h(en)n(vironmen)n(tal)e(conditions.)41 |
| 30170 |
< |
b(In)29 b(order)e(to)2042 3844 y(prob)r(e)34 b(transp)r(ort,)i(constan) |
| 30171 |
< |
n(t)d(energy)h(sim)n(ulations)g(w)n(ere)g(p)r(er-)2042 |
| 30172 |
< |
3939 y(formed)27 b(ab)r(out)g(the)h(a)n(v)n(erage)c(densit)n(y)j(unco)n |
| 30173 |
< |
(v)n(ered)f(b)n(y)h(the)h(con-)2042 4035 y(stan)n(t)21 |
| 30174 |
< |
b(pressure)g(sim)n(ulations.)34 b(Sim)n(ulations)22 b(started)f(with)h |
| 30175 |
< |
(ran-)2042 4130 y(domized)32 b(v)n(elo)r(cities)f(and)h(underw)n(en)n |
| 30176 |
< |
(t)g(50)f(ps)h(of)h(temp)r(erature)2042 4226 y(scaling)25 |
| 30177 |
< |
b(and)h(50)f(ps)h(of)g(constan)n(t)f(energy)g(equilibration)g(b)r |
| 30178 |
< |
(efore)2042 4321 y(obtaining)32 b(a)h(200)e(ps)i(tra)5 |
| 30179 |
< |
b(jectory)-7 b(.)52 b(Di\013usion)33 b(constan)n(ts)f(w)n(ere)2042 |
| 30180 |
< |
4417 y(calculated)27 b(via)h(ro)r(ot-mean)f(square)f(deviation)i |
| 30181 |
< |
(analysis.)37 b(The)2042 4512 y(a)n(v)n(eraged)e(results)i(from)h(5)f |
| 30182 |
< |
(sets)h(of)f(these)h(NVE)g(sim)n(ulations)2042 4608 y(is)29 |
| 30183 |
< |
b(displa)n(y)n(ed)f(in)i(\014gure)f(4,)g(alongside)f(exp)r(erimen)n |
| 30184 |
< |
(tal,)h(SPC/E,)2042 4703 y(and)e(TIP5P)f(results.)2735 |
| 30185 |
< |
4673 y Fn(4,20,22,23)2125 4799 y Fu(The)38 b(observ)n(ed)e(v)-5 |
| 30186 |
< |
b(alues)37 b(for)g(the)h(di\013usion)g(constan)n(t)f(p)r(oin)n(t)2042 |
| 30187 |
< |
4894 y(out)45 b(one)g(of)g(the)h(strengths)e(of)h(the)h(SSD)g(mo)r |
| 30188 |
< |
(del.)90 b(Of)45 b(the)2042 4990 y(three)39 b(exp)r(erimen)n(tal)g(mo)r |
| 30189 |
< |
(dels)g(sho)n(wn,)j(the)e(SSD)g(mo)r(del)g(has)2042 5085 |
| 30190 |
< |
y(the)23 b(most)g(accurate)f(depiction)i(of)f(the)g(di\013usion)h |
| 30191 |
< |
(trend)f(seen)g(in)2042 5180 y(exp)r(erimen)n(t)i(in)g(b)r(oth)h(the)g |
| 30192 |
< |
(sup)r(erco)r(oled)e(and)h(normal)f(regimes.)2042 5276 |
| 30193 |
< |
y(SPC/E)19 b(do)r(es)h(a)g(resp)r(ectable)f(job)h(b)n(y)g(getting)g |
| 30194 |
< |
(similar)g(v)-5 b(alues)20 b(as)2042 5371 y(SSD)28 b(and)f(exp)r |
| 30195 |
< |
(erimen)n(t)h(around)e(290)g(K;)h(ho)n(w)n(ev)n(er,)f(it)i(deviates)p |
| 30196 |
< |
eop |
| 30197 |
< |
%%Page: 5 5 |
| 30198 |
< |
5 4 bop 4043 -299 a Fu(5)-129 -166 y |
| 21735 |
> |
(shift)h(in)f(the)-150 5225 y(densit)n(y)30 b(maxim)n(um)g(lo)r |
| 21736 |
> |
(cation,)g(do)n(wn)g(to)f(245)g(K,)h(is)g(observ)n(ed.)-150 |
| 21737 |
> |
5321 y(This)21 b(is)f(probably)g(a)h(more)f(accurate)f(comparison)g(to) |
| 21738 |
> |
i(the)g(other)2063 -166 y |
| 21739 |
|
gsave currentpoint currentpoint translate -90 neg rotate neg exch |
| 21740 |
|
neg exch translate |
| 21741 |
< |
-129 -166 a @beginspecial |
| 21742 |
< |
104 @llx 85 @lly 556 @urx 674 @ury 1842 @rwi @setspecial |
| 21741 |
> |
2063 -166 a @beginspecial 104 |
| 21742 |
> |
@llx 85 @lly 556 @urx 674 @ury 1842 @rwi @setspecial |
| 21743 |
|
%%BeginDocument: betterDiffuse.epsi |
| 21744 |
|
%!PS-Adobe-2.0 EPSF-1.2 |
| 21745 |
|
%%Title: betterDiffuse.ps |
| 29716 |
|
%%EOF |
| 29717 |
|
|
| 29718 |
|
%%EndDocument |
| 29719 |
< |
@endspecial 1406 -166 a |
| 29719 |
> |
@endspecial 3598 -166 a |
| 29720 |
|
currentpoint grestore moveto |
| 29721 |
< |
1406 -166 a -150 1513 a Fr(FIG.)22 |
| 29722 |
< |
b(4:)33 b(Av)n(erage)22 b(di\013usion)f(co)r(e\016cien)n(t)i(o)n(v)n |
| 29723 |
< |
(er)e(increasing)i(temp)r(era-)-150 1600 y(ture)c(for)i(SSD,)e(SPC/E) |
| 29724 |
< |
543 1568 y Fc(20)609 1600 y Fr(,)i(TIP5P)876 1568 y Fc(4)911 |
| 29725 |
< |
1600 y Fr(,)g(and)f(Exp)r(erimen)n(tal)f(data)g(from)-150 |
| 29726 |
< |
1687 y(Gillen)27 b Fs(et)h(al.)248 1655 y Fc(22)312 1687 |
| 29727 |
< |
y Fr(,)e(and)g(from)f(Mills)853 1655 y Fc(23)920 1687 |
| 29728 |
< |
y Fr(.)-150 1967 y Fu(at)f(b)r(oth)i(higher)d(and)i(lo)n(w)n(er)e(temp) |
| 29729 |
< |
r(eratures,)i(failing)f(to)g(predict)-150 2063 y(the)33 |
| 29730 |
< |
b(exp)r(erimen)n(tal)f(trend.)51 b(TIP5P)31 b(and)h(SSD)h(b)r(oth)g |
| 29731 |
< |
(start)e(o\013)-150 2158 y(lo)n(w)j(at)h(the)h(colder)e(temp)r |
| 29732 |
< |
(eratures)g(and)h(tend)g(to)g(di\013use)h(to)r(o)-150 |
| 29733 |
< |
2254 y(rapidly)d(at)g(the)g(higher)g(temp)r(eratures.)53 |
| 29734 |
< |
b(This)34 b(t)n(yp)r(e)f(of)g(trend)-150 2349 y(at)e(the)g(higher)g |
| 29735 |
< |
(temp)r(eratures)f(is)h(not)g(surprising)e(in)j(that)f(the)-150 |
| 29736 |
< |
2445 y(densities)c(of)h(b)r(oth)g(TIP5P)e(and)h(SSD)h(are)f(lo)n(w)n |
| 29737 |
< |
(er)e(than)j(exp)r(eri-)-150 2540 y(men)n(tal)d(w)n(ater)g(at)g(temp)r |
| 29738 |
< |
(eratures)g(higher)g(than)h(ro)r(om)e(temp)r(er-)-150 |
| 29739 |
< |
2635 y(ature.)34 b(When)20 b(calculating)f(the)h(di\013usion)g(co)r |
| 29740 |
< |
(e\016cien)n(ts)f(for)h(SSD)-150 2731 y(at)32 b(exp)r(erimen)n(tal)f |
| 29741 |
< |
(densities,)i(the)f(resulting)g(v)-5 b(alues)31 b(fall)h(more)-150 |
| 29742 |
< |
2826 y(in)24 b(line)h(with)f(exp)r(erimen)n(t)g(at)g(these)g(temp)r |
| 29743 |
< |
(eratures,)g(alb)r(eit)g(not)-150 2922 y(at)g(standard)e(pressure.)35 |
| 29744 |
< |
b(Results)23 b(under)h(these)g(conditions)f(can)-150 |
| 29745 |
< |
3017 y(b)r(e)28 b(found)g(later)f(in)h(this)g(pap)r(er.)-15 |
| 29746 |
< |
3294 y Fo(C.)88 b(Structural)32 b(Changes)d(and)h(Characterization)-67 |
| 29747 |
< |
3507 y Fu(By)e(starting)f(the)h(sim)n(ulations)f(from)g(the)i |
| 29748 |
< |
(crystalline)e(state,)-150 3603 y(the)f(melting)h(transition)e(and)h |
| 29749 |
< |
(the)g(ice)g(structure)f(can)h(b)r(e)g(stud-)-150 3698 |
| 29750 |
< |
y(ied)20 b(along)f(with)h(the)h(liquid)f(phase)g(b)r(eha)n(vior)e(b)r |
| 29751 |
< |
(ey)n(ond)i(the)g(melt-)-150 3794 y(ing)27 b(p)r(oin)n(t.)37 |
| 29752 |
< |
b(T)-7 b(o)26 b(lo)r(cate)h(the)g(melting)g(transition,)g(the)g |
| 29753 |
< |
(constan)n(t)-150 3889 y(pressure)22 b(heat)i(capacit)n(y)e(\(C)766 |
| 29754 |
< |
3901 y Fn(p)807 3889 y Fu(\))i(w)n(as)e(monitored)h(in)h(eac)n(h)f(of)g |
| 29755 |
< |
(the)-150 3984 y(sim)n(ulations.)34 b(In)22 b(the)g(melting)f(sim)n |
| 29756 |
< |
(ulations)g(of)h(the)g(1024)d(parti-)-150 4080 y(cle)i(ice)g |
| 29757 |
< |
Fj(I)122 4092 y Fi(h)187 4080 y Fu(sim)n(ulations,)g(a)g(large)e(spik)n |
| 29758 |
< |
(e)i(in)g(C)1252 4092 y Fn(p)1314 4080 y Fu(o)r(ccurs)f(at)h(245)f(K,) |
| 29759 |
< |
-150 4175 y(indicating)33 b(a)g(\014rst)g(order)f(phase)g(transition)h |
| 29760 |
< |
(for)g(the)g(melting)-150 4271 y(of)h(these)g(ice)f(crystals.)54 |
| 29761 |
< |
b(When)35 b(the)f(reaction)f(\014eld)h(is)f(turned)-150 |
| 29762 |
< |
4366 y(o\013,)22 b(the)g(melting)f(transition)f(o)r(ccurs)g(at)h(235)f |
| 29763 |
< |
(K.)h(These)f(melting)-150 4462 y(transitions)25 b(are)h(considerably)e |
| 29764 |
< |
(lo)n(w)n(er)h(than)h(the)h(exp)r(erimen)n(tal)-150 4557 |
| 29765 |
< |
y(v)-5 b(alue,)31 b(but)g(this)g(is)f(not)g(surprising)f(in)i(that)g |
| 29766 |
< |
(SSD)g(is)f(a)g(simple)-150 4653 y(rigid)d(b)r(o)r(dy)h(mo)r(del)g |
| 29767 |
< |
(with)g(a)f(\014xed)g(dip)r(ole.)-67 4748 y(Additional)71 |
| 29768 |
< |
b(analyses)e(for)i(understanding)f(the)h(melt-)-150 4844 |
| 29721 |
> |
3598 -166 a 2042 1513 a Fr(FIG.)h(3:)33 |
| 29722 |
> |
b(Av)n(erage)21 b(di\013usion)h(co)r(e\016cien)n(t)h(o)n(v)n(er)e |
| 29723 |
> |
(increasing)i(temp)r(era-)2042 1600 y(ture)c(for)h(SSD,)f(SPC/E)2734 |
| 29724 |
> |
1568 y Fc(20)2800 1600 y Fr(,)i(TIP5P)3067 1568 y Fc(4)3103 |
| 29725 |
> |
1600 y Fr(,)g(and)e(Exp)r(erimen)n(tal)g(data)h(from)2042 |
| 29726 |
> |
1687 y(Gillen)26 b Fs(et)j(al.)2440 1655 y Fc(22)2504 |
| 29727 |
> |
1687 y Fr(,)d(and)f(from)h(Mills)3045 1655 y Fc(23)3111 |
| 29728 |
> |
1687 y Fr(.)2042 1967 y Fu(listed)20 b(w)n(ater)f(mo)r(dels)g(in)h |
| 29729 |
> |
(that)g(no)g(long)f(range)f(corrections)g(w)n(ere)2042 |
| 29730 |
> |
2063 y(applied)27 b(in)h(those)f(sim)n(ulations.)3079 |
| 29731 |
> |
2032 y Fn(19,20)2125 2158 y Fu(It)33 b(has)e(b)r(een)i(observ)n(ed)e |
| 29732 |
> |
(that)i(densities)f(are)f(dep)r(enden)n(t)i(on)2042 2254 |
| 29733 |
> |
y(the)j(cuto\013)h(radius)e(used)h(for)f(a)h(v)-5 b(ariet)n(y)35 |
| 29734 |
> |
b(of)h(w)n(ater)f(mo)r(dels)h(in)2042 2349 y(sim)n(ulations)g(b)r(oth)i |
| 29735 |
> |
(with)g(and)f(without)h(the)g(use)f(of)g(reaction)2042 |
| 29736 |
> |
2445 y(\014eld.)2217 2414 y Fn(12)2323 2445 y Fu(In)f(order)e(to)h |
| 29737 |
> |
(address)g(the)h(p)r(ossible)f(a\013ect)g(of)h(cuto\013)2042 |
| 29738 |
> |
2540 y(radius,)26 b(sim)n(ulations)g(w)n(ere)h(p)r(erformed)f(with)i(a) |
| 29739 |
> |
e(dip)r(olar)h(cuto\013)2042 2635 y(radius)j(of)g(12.0)2571 |
| 29740 |
> |
2620 y(\027)2571 2635 y(A)h(to)g(complimen)n(t)f(the)i(previous)d(SSD)j |
| 29741 |
> |
(sim)n(u-)2042 2731 y(lations,)e(all)g(p)r(erformed)g(with)h(a)f |
| 29742 |
> |
(cuto\013)g(of)g(9.0)3587 2716 y(\027)3587 2731 y(A.)h(All)f(the)h(re-) |
| 29743 |
> |
2042 2826 y(sulting)e(densities)h(o)n(v)n(erlapp)r(ed)e(within)j(error) |
| 29744 |
> |
c(and)j(sho)n(w)n(ed)e(no)2042 2922 y(signi\014can)n(t)21 |
| 29745 |
> |
b(trend)h(in)g(lo)n(w)n(er)f(or)g(higher)g(densities)i(as)e(a)h |
| 29746 |
> |
(function)2042 3017 y(of)33 b(cuto\013)h(radius,)h(b)r(oth)f(for)f(sim) |
| 29747 |
> |
n(ulations)g(with)h(and)g(without)2042 3113 y(reaction)39 |
| 29748 |
> |
b(\014eld.)77 b(These)40 b(results)g(indicate)h(that)g(there)f(is)g(no) |
| 29749 |
> |
2042 3208 y(ma)5 b(jor)26 b(b)r(ene\014t)i(in)f(c)n(ho)r(osing)f(a)h |
| 29750 |
> |
(longer)f(cuto\013)i(radius)e(in)i(sim)n(u-)2042 3304 |
| 29751 |
> |
y(lations)23 b(using)h(SSD.)h(This)f(is)g(comforting)f(in)h(that)g(the) |
| 29752 |
> |
h(use)f(of)g(a)2042 3399 y(longer)e(cuto\013)h(radius)f(results)h(in)g |
| 29753 |
> |
(a)g(near)f(doubling)h(of)g(the)h(time)2042 3495 y(required)i(to)i |
| 29754 |
> |
(compute)g(a)f(single)g(tra)5 b(jectory)-7 b(.)2596 3771 |
| 29755 |
> |
y Fo(B.)88 b(T)-7 b(ransp)r(ort)30 b(Beha)n(vior)2125 |
| 29756 |
> |
3984 y Fu(Of)f(imp)r(ortance)f(in)h(these)f(t)n(yp)r(es)h(of)g(studies) |
| 29757 |
> |
f(are)g(the)h(trans-)2042 4080 y(p)r(ort)44 b(prop)r(erties)f(of)h(the) |
| 29758 |
> |
g(particles)f(and)h(ho)n(w)f(they)h(c)n(hange)2042 4175 |
| 29759 |
> |
y(when)29 b(altering)f(the)h(en)n(vironmen)n(tal)e(conditions.)41 |
| 29760 |
> |
b(In)29 b(order)e(to)2042 4271 y(prob)r(e)34 b(transp)r(ort,)i(constan) |
| 29761 |
> |
n(t)d(energy)h(sim)n(ulations)g(w)n(ere)g(p)r(er-)2042 |
| 29762 |
> |
4366 y(formed)27 b(ab)r(out)g(the)h(a)n(v)n(erage)c(densit)n(y)j(unco)n |
| 29763 |
> |
(v)n(ered)f(b)n(y)h(the)h(con-)2042 4462 y(stan)n(t)21 |
| 29764 |
> |
b(pressure)g(sim)n(ulations.)34 b(Sim)n(ulations)22 b(started)f(with)h |
| 29765 |
> |
(ran-)2042 4557 y(domized)32 b(v)n(elo)r(cities)f(and)h(underw)n(en)n |
| 29766 |
> |
(t)g(50)f(ps)h(of)h(temp)r(erature)2042 4653 y(scaling)25 |
| 29767 |
> |
b(and)h(50)f(ps)h(of)g(constan)n(t)f(energy)g(equilibration)g(b)r |
| 29768 |
> |
(efore)2042 4748 y(obtaining)32 b(a)h(200)e(ps)i(tra)5 |
| 29769 |
> |
b(jectory)-7 b(.)52 b(Di\013usion)33 b(constan)n(ts)f(w)n(ere)2042 |
| 29770 |
> |
4844 y(calculated)27 b(via)h(ro)r(ot-mean)f(square)f(deviation)i |
| 29771 |
> |
(analysis.)37 b(The)2042 4939 y(a)n(v)n(eraged)e(results)i(from)h(5)f |
| 29772 |
> |
(sets)h(of)f(these)h(NVE)g(sim)n(ulations)2042 5035 y(is)29 |
| 29773 |
> |
b(displa)n(y)n(ed)f(in)i(\014gure)f(3,)g(alongside)f(exp)r(erimen)n |
| 29774 |
> |
(tal,)h(SPC/E,)2042 5130 y(and)e(TIP5P)f(results.)2735 |
| 29775 |
> |
5100 y Fn(4,20,22,23)2125 5226 y Fu(The)38 b(observ)n(ed)e(v)-5 |
| 29776 |
> |
b(alues)37 b(for)g(the)h(di\013usion)g(constan)n(t)f(p)r(oin)n(t)2042 |
| 29777 |
> |
5321 y(out)45 b(one)g(of)g(the)h(strengths)e(of)h(the)h(SSD)g(mo)r |
| 29778 |
> |
(del.)90 b(Of)45 b(the)2042 5417 y(three)39 b(exp)r(erimen)n(tal)g(mo)r |
| 29779 |
> |
(dels)g(sho)n(wn,)j(the)e(SSD)g(mo)r(del)g(has)p eop |
| 29780 |
> |
%%Page: 5 5 |
| 29781 |
> |
5 4 bop 4043 -299 a Fu(5)-150 -83 y(the)24 b(most)f(accurate)e |
| 29782 |
> |
(depiction)j(of)f(the)h(di\013usion)f(trend)g(seen)g(in)-150 |
| 29783 |
> |
12 y(exp)r(erimen)n(t)i(in)h(b)r(oth)f(the)h(sup)r(erco)r(oled)e(and)h |
| 29784 |
> |
(normal)f(regimes.)-150 108 y(SPC/E)19 b(do)r(es)h(a)g(resp)r(ectable)f |
| 29785 |
> |
(job)i(b)n(y)f(getting)g(similar)f(v)-5 b(alues)20 b(as)-150 |
| 29786 |
> |
203 y(SSD)28 b(and)g(exp)r(erimen)n(t)f(around)f(290)g(K;)i(ho)n(w)n |
| 29787 |
> |
(ev)n(er,)d(it)j(deviates)-150 299 y(at)c(b)r(oth)i(higher)d(and)i(lo)n |
| 29788 |
> |
(w)n(er)e(temp)r(eratures,)i(failing)f(to)g(predict)-150 |
| 29789 |
> |
394 y(the)33 b(exp)r(erimen)n(tal)f(trend.)51 b(TIP5P)31 |
| 29790 |
> |
b(and)h(SSD)h(b)r(oth)g(start)e(o\013)-150 490 y(lo)n(w)j(at)h(the)h |
| 29791 |
> |
(colder)e(temp)r(eratures)g(and)h(tend)g(to)g(di\013use)h(to)r(o)-150 |
| 29792 |
> |
585 y(rapidly)d(at)g(the)g(higher)g(temp)r(eratures.)53 |
| 29793 |
> |
b(This)34 b(t)n(yp)r(e)f(of)g(trend)-150 681 y(at)e(the)g(higher)g |
| 29794 |
> |
(temp)r(eratures)f(is)h(not)g(surprising)e(in)j(that)f(the)-150 |
| 29795 |
> |
776 y(densities)c(of)h(b)r(oth)g(TIP5P)e(and)h(SSD)h(are)f(lo)n(w)n(er) |
| 29796 |
> |
e(than)j(exp)r(eri-)-150 872 y(men)n(tal)d(w)n(ater)g(at)g(temp)r |
| 29797 |
> |
(eratures)g(higher)g(than)h(ro)r(om)e(temp)r(er-)-150 |
| 29798 |
> |
967 y(ature.)34 b(When)20 b(calculating)f(the)h(di\013usion)g(co)r |
| 29799 |
> |
(e\016cien)n(ts)f(for)h(SSD)-150 1063 y(at)32 b(exp)r(erimen)n(tal)f |
| 29800 |
> |
(densities,)i(the)f(resulting)g(v)-5 b(alues)31 b(fall)h(more)-150 |
| 29801 |
> |
1158 y(in)24 b(line)h(with)f(exp)r(erimen)n(t)g(at)g(these)g(temp)r |
| 29802 |
> |
(eratures,)g(alb)r(eit)g(not)-150 1254 y(at)g(standard)e(pressure.)35 |
| 29803 |
> |
b(Results)23 b(under)h(these)g(conditions)f(can)-150 |
| 29804 |
> |
1349 y(b)r(e)28 b(found)g(later)f(in)h(this)g(pap)r(er.)-15 |
| 29805 |
> |
1625 y Fo(C.)88 b(Structural)32 b(Changes)d(and)h(Characterization)-67 |
| 29806 |
> |
1839 y Fu(By)e(starting)f(the)h(sim)n(ulations)f(from)g(the)i |
| 29807 |
> |
(crystalline)e(state,)-150 1934 y(the)f(melting)h(transition)e(and)h |
| 29808 |
> |
(the)g(ice)g(structure)f(can)h(b)r(e)g(stud-)-150 2030 |
| 29809 |
> |
y(ied)20 b(along)f(with)h(the)h(liquid)f(phase)g(b)r(eha)n(vior)e(b)r |
| 29810 |
> |
(ey)n(ond)i(the)g(melt-)-150 2125 y(ing)27 b(p)r(oin)n(t.)37 |
| 29811 |
> |
b(T)-7 b(o)26 b(lo)r(cate)h(the)g(melting)g(transition,)g(the)g |
| 29812 |
> |
(constan)n(t)-150 2221 y(pressure)22 b(heat)i(capacit)n(y)e(\(C)766 |
| 29813 |
> |
2233 y Fn(p)807 2221 y Fu(\))i(w)n(as)e(monitored)h(in)h(eac)n(h)f(of)g |
| 29814 |
> |
(the)-150 2316 y(sim)n(ulations.)34 b(In)22 b(the)g(melting)f(sim)n |
| 29815 |
> |
(ulations)g(of)h(the)g(1024)d(parti-)-150 2412 y(cle)i(ice)g |
| 29816 |
> |
Fj(I)122 2424 y Fi(h)187 2412 y Fu(sim)n(ulations,)g(a)g(large)e(spik)n |
| 29817 |
> |
(e)i(in)g(C)1252 2424 y Fn(p)1314 2412 y Fu(o)r(ccurs)f(at)h(245)f(K,) |
| 29818 |
> |
-150 2507 y(indicating)33 b(a)g(\014rst)g(order)f(phase)g(transition)h |
| 29819 |
> |
(for)g(the)g(melting)-150 2603 y(of)h(these)g(ice)f(crystals.)54 |
| 29820 |
> |
b(When)35 b(the)f(reaction)f(\014eld)h(is)f(turned)-150 |
| 29821 |
> |
2698 y(o\013,)22 b(the)g(melting)f(transition)f(o)r(ccurs)g(at)h(235)f |
| 29822 |
> |
(K.)h(These)f(melting)-150 2794 y(transitions)25 b(are)h(considerably)e |
| 29823 |
> |
(lo)n(w)n(er)h(than)h(the)h(exp)r(erimen)n(tal)-150 2889 |
| 29824 |
> |
y(v)-5 b(alue,)31 b(but)g(this)g(is)f(not)g(surprising)f(in)i(that)g |
| 29825 |
> |
(SSD)g(is)f(a)g(simple)-150 2985 y(rigid)d(b)r(o)r(dy)h(mo)r(del)g |
| 29826 |
> |
(with)g(a)f(\014xed)g(dip)r(ole.)-67 3080 y(Additional)71 |
| 29827 |
> |
b(analyses)e(for)i(understanding)f(the)h(melt-)-150 3175 |
| 29828 |
|
y(ing)48 b(phase-transition)e(pro)r(cess)h(w)n(ere)g(p)r(erformed)h |
| 29829 |
< |
(via)g(t)n(w)n(o-)-150 4939 y(dimensional)26 b(structure)h(and)f(dip)r |
| 29830 |
< |
(ole)h(angle)f(correlations.)34 b(Ex-)-150 5035 y(pressions)26 |
| 29831 |
< |
b(for)h(the)h(correlations)e(are)g(as)h(follo)n(ws:)2059 |
| 29832 |
< |
1788 y @beginspecial 0 @llx 0 @lly 965 @urx 939 @ury |
| 29833 |
< |
2409 @rwi @setspecial |
| 29829 |
> |
(via)g(t)n(w)n(o-)-150 3271 y(dimensional)26 b(structure)h(and)f(dip)r |
| 29830 |
> |
(ole)h(angle)f(correlations.)34 b(Ex-)-150 3366 y(pressions)26 |
| 29831 |
> |
b(for)h(the)h(correlations)e(are)g(as)h(follo)n(ws:)-67 |
| 29832 |
> |
3665 y Fj(g)-27 3677 y Fn(AB)72 3665 y Fu(\()p Fj(r)n(;)14 |
| 29833 |
> |
b Fu(cos)g Fj(\022)r Fu(\))23 b(=)172 3784 y Fj(V)p 87 |
| 29834 |
> |
3821 238 4 v 87 3897 a(N)154 3909 y Fn(A)207 3897 y Fj(N)274 |
| 29835 |
> |
3909 y Fn(B)334 3840 y Ff(h)366 3761 y Fg(X)367 3939 |
| 29836 |
> |
y Fi(i)p Ft(2)p Fn(A)501 3761 y Fg(X)500 3939 y Fi(j)s |
| 29837 |
> |
Ft(2)p Fn(B)636 3840 y Fj(\016)s Fu(\(cos)13 b Fj(\022)21 |
| 29838 |
> |
b Ff(\000)d Fu(cos)13 b Fj(\022)1140 3852 y Fi(ij)1198 |
| 29839 |
> |
3840 y Fu(\))p Fj(\016)s Fu(\()p Fj(r)22 b Ff(\000)c(j)p |
| 29840 |
> |
Fh(r)1506 3852 y Fi(ij)1565 3840 y Ff(j)p Fu(\))p Ff(i)28 |
| 29841 |
> |
b Fj(;)83 b Fu(\(8\))-67 4225 y Fj(g)-27 4237 y Fn(AB)72 |
| 29842 |
> |
4225 y Fu(\()p Fj(r)n(;)14 b Fu(cos)g Fj(!)s Fu(\))23 |
| 29843 |
> |
b(=)146 4344 y Fj(V)p 61 4381 V 61 4457 a(N)128 4469 |
| 29844 |
> |
y Fn(A)180 4457 y Fj(N)247 4469 y Fn(B)308 4400 y Ff(h)340 |
| 29845 |
> |
4321 y Fg(X)341 4499 y Fi(i)p Ft(2)p Fn(A)475 4321 y |
| 29846 |
> |
Fg(X)474 4499 y Fi(j)s Ft(2)p Fn(B)610 4400 y Fj(\016)s |
| 29847 |
> |
Fu(\(cos)13 b Fj(!)21 b Ff(\000)d Fu(cos)13 b Fj(!)1140 |
| 29848 |
> |
4412 y Fi(ij)1198 4400 y Fu(\))p Fj(\016)s Fu(\()p Fj(r)22 |
| 29849 |
> |
b Ff(\000)c(j)p Fh(r)1506 4412 y Fi(ij)1565 4400 y Ff(j)p |
| 29850 |
> |
Fu(\))p Ff(i)28 b Fj(;)83 b Fu(\(9\))-150 4668 y(where)19 |
| 29851 |
> |
b Fj(\022)j Fu(and)d Fj(!)j Fu(refer)c(to)i(the)f(angles)g(sho)n(wn)f |
| 29852 |
> |
(in)i(the)g(ab)r(o)n(v)n(e)e(illus-)-150 4763 y(tration.)36 |
| 29853 |
> |
b(By)26 b(binning)g(o)n(v)n(er)f(b)r(oth)i(distance)f(and)g(the)h |
| 29854 |
> |
(cosine)e(of)-150 4858 y(the)31 b(desired)g(angle)f(b)r(et)n(w)n(een)h |
| 29855 |
> |
(the)h(t)n(w)n(o)e(dip)r(oles,)i(the)g(g\()p Fm(r)9 b |
| 29856 |
> |
Fu(\))31 b(can)-150 4954 y(b)r(e)38 b(dissected)f(to)f(determine)i(the) |
| 29857 |
> |
f(common)g(dip)r(ole)g(arrange-)-150 5049 y(men)n(ts)29 |
| 29858 |
> |
b(that)g(constitute)g(the)h(p)r(eaks)e(and)h(troughs.)40 |
| 29859 |
> |
b(F)-7 b(rames)28 b(A)-150 5145 y(and)d(B)h(of)f(\014gure)g(4)g(sho)n |
| 29860 |
> |
(w)g(a)g(relativ)n(ely)f(crystalline)h(state)g(of)h(an)-150 |
| 29861 |
> |
5240 y(ice)36 b Fj(I)19 5252 y Fi(c)89 5240 y Fu(sim)n(ulation.)62 |
| 29862 |
> |
b(The)36 b(\014rst)g(p)r(eak)g(of)g(the)g(g\()p Fm(r)9 |
| 29863 |
> |
b Fu(\))36 b(primarily)-150 5336 y(consists)23 b(of)h(the)g(preferred)f |
| 29864 |
> |
(h)n(ydrogen)f(b)r(onding)i(arrangemen)n(ts)-150 5431 |
| 29865 |
> |
y(as)i(dictated)i(b)n(y)e(the)i(tetrahedral)e(stic)n(ky)g(p)r(oten)n |
| 29866 |
> |
(tial,)h(one)g(p)r(eak)2059 1788 y @beginspecial 0 @llx |
| 29867 |
> |
0 @lly 965 @urx 939 @ury 2409 @rwi @setspecial |
| 29868 |
|
%%BeginDocument: fullContours.eps |
| 29869 |
|
%!PS-Adobe-3.1 EPSF-3.0 |
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%%Title: fullContours.eps |
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%AI9_PrivateDataEnd |
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%%EndDocument |
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@endspecial 2042 1958 a Fr(FIG.)g(5:)39 b(Con)n(tour)27 |
| 64955 |
> |
@endspecial 2042 1958 a Fr(FIG.)g(4:)39 b(Con)n(tour)27 |
| 64956 |
|
b(plots)h(of)g(2D)g(angular)g(g\()p Fq(r)r Fr(\)'s)g(for)g(512)g(SSD)e |
| 64957 |
|
(sys-)2042 2045 y(tems)h(at)h(100)h(K)e(\(A)g(&)h(B\))g(and)f(300)i(K)e |
| 64958 |
|
(\(C)h(&)g(D\).)f(Con)n(tour)i(colors)2042 2132 y(are)i(in)n(v)n(erted) |
| 71090 |
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@endspecial 2042 3428 a(FIG.)31 b(6:)46 b(Tw)n(o)32 |
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> |
@endspecial 2042 3428 a(FIG.)31 b(5:)46 b(Tw)n(o)32 |
| 71094 |
|
b(dimensional)f(illustration)i(of)f(the)f(angles)h(in)n(v)n(olv)n(ed) |
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< |
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< |
Fj(r)n(;)14 b Fu(cos)f Fj(\022)r Fu(\))24 b(=)2364 4118 |
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< |
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< |
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< |
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| 71101 |
< |
y Fg(X)2692 4273 y Fi(j)s Ft(2)p Fn(B)2827 4174 y Fj(\016)s |
| 71102 |
< |
Fu(\(cos)14 b Fj(\022)20 b Ff(\000)f Fu(cos)13 b Fj(\022)3332 |
| 71103 |
< |
4186 y Fi(ij)3390 4174 y Fu(\))p Fj(\016)s Fu(\()p Fj(r)22 |
| 71104 |
< |
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| 71105 |
< |
Fu(\))p Ff(i)28 b Fj(;)83 b Fu(\(8\))2125 4559 y Fj(g)2165 |
| 71106 |
< |
4571 y Fn(AB)2264 4559 y Fu(\()p Fj(r)n(;)14 b Fu(cos)f |
| 71107 |
< |
Fj(!)s Fu(\))23 b(=)2338 4677 y Fj(V)p 2252 4714 V 2252 |
| 71108 |
< |
4790 a(N)2319 4802 y Fn(A)2372 4790 y Fj(N)2439 4802 |
| 71109 |
< |
y Fn(B)2499 4733 y Ff(h)2531 4655 y Fg(X)2532 4833 y |
| 71110 |
< |
Fi(i)p Ft(2)p Fn(A)2667 4655 y Fg(X)2666 4833 y Fi(j)s |
| 71111 |
< |
Ft(2)p Fn(B)2801 4733 y Fj(\016)s Fu(\(cos)14 b Fj(!)21 |
| 71112 |
< |
b Ff(\000)d Fu(cos)13 b Fj(!)3332 4745 y Fi(ij)3390 4733 |
| 71113 |
< |
y Fu(\))p Fj(\016)s Fu(\()p Fj(r)22 b Ff(\000)c(j)p Fh(r)3698 |
| 71114 |
< |
4745 y Fi(ij)3757 4733 y Ff(j)p Fu(\))p Ff(i)28 b Fj(;)83 |
| 71115 |
< |
b Fu(\(9\))2042 5001 y(where)19 b Fj(\022)i Fu(and)f |
| 71116 |
< |
Fj(!)i Fu(refer)c(to)h(the)h(angles)e(sho)n(wn)h(in)h(the)f(ab)r(o)n(v) |
| 71117 |
< |
n(e)f(illus-)2042 5097 y(tration.)36 b(By)26 b(binning)g(o)n(v)n(er)f |
| 71118 |
< |
(b)r(oth)i(distance)f(and)g(the)h(cosine)e(of)2042 5192 |
| 71119 |
< |
y(the)31 b(desired)g(angle)f(b)r(et)n(w)n(een)h(the)h(t)n(w)n(o)e(dip)r |
| 71120 |
< |
(oles,)i(the)f(g\()p Fm(r)9 b Fu(\))32 b(can)2042 5288 |
| 71121 |
< |
y(b)r(e)37 b(dissected)g(to)g(determine)g(the)h(common)f(dip)r(ole)g |
| 79489 |
< |
(arrange-)2042 5383 y(men)n(ts)29 b(that)g(constitute)g(the)h(p)r(eaks) |
| 79490 |
< |
e(and)h(troughs.)40 b(F)-7 b(rames)28 b(A)2042 5479 y(and)d(B)h(of)f |
| 79491 |
< |
(\014gure)g(5)g(sho)n(w)g(a)g(relativ)n(ely)f(crystalline)h(state)g(of) |
| 79492 |
< |
g(an)p eop |
| 71096 |
> |
(4.)2042 3796 y Fu(for)k(the)i(donating)e(and)h(the)g(other)f(for)h |
| 71097 |
> |
(the)g(accepting)g(h)n(ydro-)2042 3891 y(gen)39 b(b)r(onds.)73 |
| 71098 |
> |
b(Due)40 b(to)g(the)g(high)f(degree)g(of)h(crystallinit)n(y)e(of)2042 |
| 71099 |
> |
3987 y(the)e(sample,)i(the)f(second)e(and)h(third)g(solv)-5 |
| 71100 |
> |
b(ation)35 b(shells)h(sho)n(w)2042 4082 y(a)30 b(rep)r(eated)h(p)r(eak) |
| 71101 |
> |
f(arrangemen)n(t)f(whic)n(h)h(deca)n(ys)g(at)h(distances)2042 |
| 71102 |
> |
4178 y(around)19 b(the)j(fourth)e(solv)-5 b(ation)20 |
| 71103 |
> |
b(shell,)i(near)e(the)h(imp)r(osed)g(cuto\013)2042 4273 |
| 71104 |
> |
y(for)27 b(the)h(Lennard-Jones)e(and)i(dip)r(ole-dip)r(ole)g(in)n |
| 71105 |
> |
(teractions.)36 b(In)2042 4368 y(the)19 b(higher)g(temp)r(erature)f |
| 71106 |
> |
(sim)n(ulation)h(sho)n(wn)f(in)i(frames)e(C)h(and)2042 |
| 71107 |
> |
4464 y(D,)35 b(the)g(rep)r(eated)f(p)r(eak)g(features)g(are)g |
| 71108 |
> |
(signi\014can)n(tly)g(blurred.)2042 4559 y(The)21 b(\014rst)g(solv)-5 |
| 71109 |
> |
b(ation)20 b(shell)h(still)h(sho)n(ws)e(the)h(strong)f(e\013ect)i(of)f |
| 71110 |
> |
(the)2042 4655 y(stic)n(ky-p)r(oten)n(tial,)j(although)f(it)h(co)n(v)n |
| 71111 |
> |
(ers)e(a)i(larger)e(area,)h(extend-)2042 4750 y(ing)33 |
| 71112 |
> |
b(to)g(include)h(a)f(fraction)f(of)i(aligned)e(dip)r(ole)i(p)r(eaks)f |
| 71113 |
> |
(within)2042 4846 y(the)d(\014rst)g(solv)-5 b(ation)30 |
| 71114 |
> |
b(shell.)44 b(The)31 b(latter)f(p)r(eaks)f(lose)h(de\014nition)2042 |
| 71115 |
> |
4941 y(as)f(thermal)g(motion)g(and)h(the)g(comp)r(eting)g(dip)r(ole)f |
| 71116 |
> |
(force)g(o)n(v)n(er-)2042 5037 y(comes)23 b(the)h(stic)n(ky)g(p)r(oten) |
| 71117 |
> |
n(tial's)f(tigh)n(t)h(tetrahedral)f(structuring)2042 |
| 71118 |
> |
5132 y(of)k(the)h(\015uid.)2125 5228 y(This)k(complex)g(in)n(terpla)n |
| 71119 |
> |
(y)f(b)r(et)n(w)n(een)h(dip)r(ole)h(and)f(stic)n(ky)f(in-)2042 |
| 71120 |
> |
5323 y(teractions)37 b(w)n(as)g(remark)n(ed)f(up)r(on)i(as)f(a)h(p)r |
| 71121 |
> |
(ossible)f(reason)g(for)p eop |
| 71122 |
|
%%Page: 6 6 |
| 71123 |
< |
6 5 bop 4043 -299 a Fu(6)-150 -83 y(ice)36 b Fj(I)19 |
| 79495 |
< |
-71 y Fi(c)89 -83 y Fu(sim)n(ulation.)62 b(The)36 b(\014rst)g(p)r(eak)g |
| 79496 |
< |
(of)g(the)g(g\()p Fm(r)9 b Fu(\))36 b(primarily)-150 |
| 79497 |
< |
12 y(consists)23 b(of)h(the)g(preferred)f(h)n(ydrogen)f(b)r(onding)i |
| 79498 |
< |
(arrangemen)n(ts)-150 108 y(as)i(dictated)i(b)n(y)e(the)i(tetrahedral)e |
| 79499 |
< |
(stic)n(ky)g(p)r(oten)n(tial,)h(one)g(p)r(eak)-150 203 |
| 79500 |
< |
y(for)j(the)i(donating)e(and)h(the)g(other)g(for)f(the)i(accepting)e(h) |
| 79501 |
< |
n(ydro-)-150 299 y(gen)39 b(b)r(onds.)73 b(Due)40 b(to)g(the)g(high)g |
| 79502 |
< |
(degree)e(of)i(crystallinit)n(y)e(of)-150 394 y(the)e(sample,)i(the)f |
| 79503 |
< |
(second)e(and)h(third)g(solv)-5 b(ation)36 b(shells)f(sho)n(w)-150 |
| 79504 |
< |
490 y(a)30 b(rep)r(eated)h(p)r(eak)f(arrangemen)n(t)f(whic)n(h)i(deca)n |
| 79505 |
< |
(ys)e(at)i(distances)-150 585 y(around)20 b(the)h(fourth)g(solv)-5 |
| 79506 |
< |
b(ation)19 b(shell,)j(near)e(the)h(imp)r(osed)g(cuto\013)-150 |
| 79507 |
< |
681 y(for)27 b(the)i(Lennard-Jones)c(and)j(dip)r(ole-dip)r(ole)g(in)n |
| 79508 |
< |
(teractions.)36 b(In)-150 776 y(the)20 b(higher)e(temp)r(erature)h(sim) |
| 79509 |
< |
n(ulation)f(sho)n(wn)h(in)g(frames)f(C)i(and)-150 872 |
| 79510 |
< |
y(D,)35 b(the)g(rep)r(eated)f(p)r(eak)h(features)f(are)f(signi\014can)n |
| 79511 |
< |
(tly)h(blurred.)-150 967 y(The)21 b(\014rst)g(solv)-5 |
| 79512 |
< |
b(ation)20 b(shell)h(still)h(sho)n(ws)e(the)h(strong)f(e\013ect)i(of)f |
| 79513 |
< |
(the)-150 1063 y(stic)n(ky-p)r(oten)n(tial,)j(although)f(it)i(co)n(v)n |
| 79514 |
< |
(ers)c(a)j(larger)e(area,)i(extend-)-150 1158 y(ing)33 |
| 79515 |
< |
b(to)g(include)h(a)f(fraction)g(of)g(aligned)f(dip)r(ole)i(p)r(eaks)f |
| 79516 |
< |
(within)-150 1254 y(the)e(\014rst)f(solv)-5 b(ation)29 |
| 79517 |
< |
b(shell.)45 b(The)30 b(latter)g(p)r(eaks)g(lose)f(de\014nition)-150 |
| 79518 |
< |
1349 y(as)g(thermal)g(motion)h(and)f(the)h(comp)r(eting)g(dip)r(ole)g |
| 79519 |
< |
(force)f(o)n(v)n(er-)-150 1445 y(comes)23 b(the)i(stic)n(ky)e(p)r(oten) |
| 79520 |
< |
n(tial's)g(tigh)n(t)h(tetrahedral)f(structuring)-150 |
| 79521 |
< |
1540 y(of)28 b(the)g(\015uid.)-67 1636 y(This)k(complex)g(in)n(terpla)n |
| 79522 |
< |
(y)f(b)r(et)n(w)n(een)h(dip)r(ole)h(and)f(stic)n(ky)f(in-)-150 |
| 79523 |
< |
1731 y(teractions)37 b(w)n(as)g(remark)n(ed)f(up)r(on)i(as)f(a)h(p)r |
| 79524 |
< |
(ossible)g(reason)e(for)-150 1826 y(the)25 b(split)f(second)g(p)r(eak)g |
| 71123 |
> |
6 5 bop 4043 -299 a Fu(6)-150 -83 y(the)25 b(split)f(second)g(p)r(eak)g |
| 71124 |
|
(in)g(the)h(o)n(xygen-o)n(xygen)c(g\()p Fm(r)9 b Fu(\).)1592 |
| 71125 |
< |
1796 y Fn(5)1654 1826 y Fu(A)n(t)24 b(lo)n(w)-150 1922 |
| 71126 |
< |
y(temp)r(eratures,)h(the)h(second)f(solv)-5 b(ation)24 |
| 71127 |
< |
b(shell)h(p)r(eak)g(app)r(ears)g(to)-150 2017 y(ha)n(v)n(e)k(t)n(w)n(o) |
| 71128 |
< |
h(distinct)h(parts)f(that)g(blend)h(together)e(to)i(form)f(one)-150 |
| 71129 |
< |
2113 y(observ)-5 b(able)22 b(p)r(eak.)36 b(A)n(t)23 b(higher)g(temp)r |
| 71130 |
< |
(eratures,)h(this)g(split)g(c)n(har-)-150 2208 y(acter)k(alters)h(to)g |
| 71131 |
< |
(sho)n(w)f(the)i(leading)e(4)1101 2193 y(\027)1101 2208 |
| 71132 |
< |
y(A)i(p)r(eak)f(dominated)g(b)n(y)-150 2304 y(equatorial)i(an)n |
| 71133 |
< |
(ti-parallel)h(dip)r(ole)h(orien)n(tations,)g(and)g(there)g(is)-150 |
| 71134 |
< |
2399 y(tigh)n(tly)k(bunc)n(hed)h(group)f(of)g(axially)f(arranged)g(dip) |
| 71135 |
< |
r(oles)h(that)-150 2495 y(most)29 b(lik)n(ely)f(consist)h(of)f(the)i |
| 71136 |
< |
(smaller)e(fraction)g(aligned)g(dip)r(ole)-150 2590 y(pairs.)36 |
| 71137 |
< |
b(The)27 b(trailing)f(part)g(of)h(the)g(split)h(p)r(eak)e(at)h(5)1513 |
| 71138 |
< |
2575 y(\027)1513 2590 y(A)g(is)g(domi-)-150 2686 y(nated)f(b)n(y)g |
| 71139 |
< |
(aligned)g(dip)r(oles)g(that)g(range)f(primarily)g(within)i(the)-150 |
| 71140 |
< |
2781 y(axial)c(to)h(the)h(c)n(hief)f(h)n(ydrogen)e(b)r(ond)j |
| 71141 |
< |
(arrangemen)n(ts)c(similar)j(to)-150 2877 y(those)g(seen)g(in)h(the)f |
| 71142 |
< |
(\014rst)h(solv)-5 b(ation)23 b(shell.)36 b(This)24 b(evidence)g(indi-) |
| 71143 |
< |
-150 2972 y(cates)h(that)g(the)h(dip)r(ole)f(pair)g(in)n(teraction)f(b) |
| 71144 |
< |
r(egins)h(to)h(dominate)-150 3068 y(outside)31 b(of)g(the)g(range)f(of) |
| 71145 |
< |
h(the)g(dip)r(olar)g(repulsion)f(term,)i(with)-150 3163 |
| 71146 |
< |
y(the)e(primary)f(energetically)f(fa)n(v)n(orable)g(dip)r(ole)i |
| 71147 |
< |
(arrangemen)n(ts)-150 3259 y(p)r(opulating)j(the)h(region)e |
| 71148 |
< |
(immediately)i(outside)g(of)f(it's)h(range)-150 3354 |
| 71149 |
< |
y(\(around)24 b(4)228 3339 y(\027)228 3354 y(A\),)i(and)f(arrangemen)n |
| 71150 |
< |
(ts)e(that)j(seek)e(to)h(ideally)g(sat-)-150 3450 y(isfy)33 |
| 71151 |
< |
b(b)r(oth)g(the)g(stic)n(ky)f(and)g(dip)r(ole)h(forces)f(lo)r(cate)g |
| 71152 |
< |
(themselv)n(es)-150 3545 y(just)c(b)r(ey)n(ond)f(this)h(region)f |
| 71153 |
< |
(\(around)g(5)1097 3530 y(\027)1097 3545 y(A\).)-67 3641 |
| 71154 |
< |
y(F)-7 b(rom)25 b(these)h(\014ndings,)f(the)h(split)g(second)f(p)r(eak) |
| 71155 |
< |
g(is)g(primarily)-150 3736 y(the)35 b(pro)r(duct)g(of)f(the)i(dip)r |
| 71156 |
< |
(olar)e(repulsion)g(term)g(of)h(the)g(stic)n(ky)-150 |
| 71157 |
< |
3831 y(p)r(oten)n(tial.)56 b(In)34 b(fact,)h(the)g(leading)e(of)h(the)g |
| 71158 |
< |
(t)n(w)n(o)f(p)r(eaks)h(can)f(b)r(e)-150 3927 y(pushed)25 |
| 71159 |
< |
b(out)h(and)f(merged)f(with)i(the)g(outer)e(split)i(p)r(eak)f(just)h(b) |
| 71160 |
< |
n(y)-150 4022 y(extending)h(the)g(switc)n(hing)f(function)i(cuto\013)f |
| 71161 |
< |
(\()p Fj(s)1366 3992 y Ft(0)1389 4022 y Fu(\()p Fj(r)1458 |
| 71162 |
< |
4034 y Fi(ij)1517 4022 y Fu(\)\))h(from)e(its)-150 4127 |
| 71163 |
< |
y(normal)k(4.0)272 4112 y(\027)272 4127 y(A)h(to)g(v)-5 |
| 71164 |
< |
b(alues)31 b(of)g(4.5)f(or)g(ev)n(en)g(5)1326 4112 y(\027)1326 |
| 79566 |
< |
4127 y(A.)h(This)g(t)n(yp)r(e)g(of)-150 4222 y(correction)f(is)i(not)g |
| 71125 |
> |
-113 y Fn(5)1654 -83 y Fu(A)n(t)24 b(lo)n(w)-150 12 y(temp)r(eratures,) |
| 71126 |
> |
h(the)h(second)f(solv)-5 b(ation)24 b(shell)h(p)r(eak)g(app)r(ears)g |
| 71127 |
> |
(to)-150 108 y(ha)n(v)n(e)k(t)n(w)n(o)h(distinct)h(parts)f(that)g |
| 71128 |
> |
(blend)h(together)e(to)i(form)f(one)-150 203 y(observ)-5 |
| 71129 |
> |
b(able)22 b(p)r(eak.)36 b(A)n(t)23 b(higher)g(temp)r(eratures,)h(this)g |
| 71130 |
> |
(split)g(c)n(har-)-150 299 y(acter)k(alters)h(to)g(sho)n(w)f(the)i |
| 71131 |
> |
(leading)e(4)1101 284 y(\027)1101 299 y(A)i(p)r(eak)f(dominated)g(b)n |
| 71132 |
> |
(y)-150 394 y(equatorial)i(an)n(ti-parallel)h(dip)r(ole)h(orien)n |
| 71133 |
> |
(tations,)g(and)g(there)g(is)-150 490 y(tigh)n(tly)k(bunc)n(hed)h |
| 71134 |
> |
(group)f(of)g(axially)f(arranged)g(dip)r(oles)h(that)-150 |
| 71135 |
> |
585 y(most)29 b(lik)n(ely)f(consist)h(of)f(the)i(smaller)e(fraction)g |
| 71136 |
> |
(aligned)g(dip)r(ole)-150 681 y(pairs.)36 b(The)27 b(trailing)f(part)g |
| 71137 |
> |
(of)h(the)g(split)h(p)r(eak)e(at)h(5)1513 666 y(\027)1513 |
| 71138 |
> |
681 y(A)g(is)g(domi-)-150 776 y(nated)f(b)n(y)g(aligned)g(dip)r(oles)g |
| 71139 |
> |
(that)g(range)f(primarily)g(within)i(the)-150 872 y(axial)c(to)h(the)h |
| 71140 |
> |
(c)n(hief)f(h)n(ydrogen)e(b)r(ond)j(arrangemen)n(ts)c(similar)j(to)-150 |
| 71141 |
> |
967 y(those)g(seen)g(in)h(the)f(\014rst)h(solv)-5 b(ation)23 |
| 71142 |
> |
b(shell.)36 b(This)24 b(evidence)g(indi-)-150 1063 y(cates)h(that)g |
| 71143 |
> |
(the)h(dip)r(ole)f(pair)g(in)n(teraction)f(b)r(egins)h(to)h(dominate) |
| 71144 |
> |
-150 1158 y(outside)31 b(of)g(the)g(range)f(of)h(the)g(dip)r(olar)g |
| 71145 |
> |
(repulsion)f(term,)i(with)-150 1254 y(the)e(primary)f(energetically)f |
| 71146 |
> |
(fa)n(v)n(orable)g(dip)r(ole)i(arrangemen)n(ts)-150 1349 |
| 71147 |
> |
y(p)r(opulating)j(the)h(region)e(immediately)i(outside)g(of)f(it's)h |
| 71148 |
> |
(range)-150 1445 y(\(around)24 b(4)228 1430 y(\027)228 |
| 71149 |
> |
1445 y(A\),)i(and)f(arrangemen)n(ts)e(that)j(seek)e(to)h(ideally)g |
| 71150 |
> |
(sat-)-150 1540 y(isfy)33 b(b)r(oth)g(the)g(stic)n(ky)f(and)g(dip)r |
| 71151 |
> |
(ole)h(forces)f(lo)r(cate)g(themselv)n(es)-150 1636 y(just)c(b)r(ey)n |
| 71152 |
> |
(ond)f(this)h(region)f(\(around)g(5)1097 1621 y(\027)1097 |
| 71153 |
> |
1636 y(A\).)-67 1731 y(F)-7 b(rom)25 b(these)h(\014ndings,)f(the)h |
| 71154 |
> |
(split)g(second)f(p)r(eak)g(is)g(primarily)-150 1826 |
| 71155 |
> |
y(the)35 b(pro)r(duct)g(of)f(the)i(dip)r(olar)e(repulsion)g(term)g(of)h |
| 71156 |
> |
(the)g(stic)n(ky)-150 1922 y(p)r(oten)n(tial.)56 b(In)34 |
| 71157 |
> |
b(fact,)h(the)g(leading)e(of)h(the)g(t)n(w)n(o)f(p)r(eaks)h(can)f(b)r |
| 71158 |
> |
(e)-150 2017 y(pushed)25 b(out)h(and)f(merged)f(with)i(the)g(outer)e |
| 71159 |
> |
(split)i(p)r(eak)f(just)h(b)n(y)-150 2113 y(extending)h(the)g(switc)n |
| 71160 |
> |
(hing)f(function)i(cuto\013)f(\()p Fj(s)1366 2083 y Ft(0)1389 |
| 71161 |
> |
2113 y Fu(\()p Fj(r)1458 2125 y Fi(ij)1517 2113 y Fu(\)\))h(from)e(its) |
| 71162 |
> |
-150 2217 y(normal)k(4.0)272 2202 y(\027)272 2217 y(A)h(to)g(v)-5 |
| 71163 |
> |
b(alues)31 b(of)g(4.5)f(or)g(ev)n(en)g(5)1326 2202 y(\027)1326 |
| 71164 |
> |
2217 y(A.)h(This)g(t)n(yp)r(e)g(of)-150 2313 y(correction)f(is)i(not)g |
| 71165 |
|
(recommended)f(for)g(impro)n(ving)g(the)h(liquid)-150 |
| 71166 |
< |
4318 y(structure,)c(b)r(ecause)f(the)h(second)g(solv)-5 |
| 71167 |
< |
b(ation)27 b(shell)h(will)g(still)g(b)r(e)-150 4413 y(shifted)g(to)r(o) |
| 71166 |
> |
2408 y(structure,)c(b)r(ecause)f(the)h(second)g(solv)-5 |
| 71167 |
> |
b(ation)27 b(shell)h(will)g(still)g(b)r(e)-150 2504 y(shifted)g(to)r(o) |
| 71168 |
|
e(far)g(out.)37 b(In)27 b(addition,)g(this)g(w)n(ould)g(ha)n(v)n(e)e |
| 71169 |
< |
(an)i(ev)n(en)-150 4509 y(more)i(detrimen)n(tal)h(e\013ect)g(on)g(the)h |
| 71170 |
< |
(system)e(densities,)i(leading)-150 4604 y(to)40 b(a)g(liquid)h(with)f |
| 71169 |
> |
(an)i(ev)n(en)-150 2599 y(more)i(detrimen)n(tal)h(e\013ect)g(on)g(the)h |
| 71170 |
> |
(system)e(densities,)i(leading)-150 2695 y(to)40 b(a)g(liquid)h(with)f |
| 71171 |
|
(a)g(more)g(op)r(en)g(structure)g(and)g(a)g(densit)n(y)-150 |
| 71172 |
< |
4700 y(considerably)24 b(lo)n(w)n(er)f(than)i(the)h(normal)e(SSD)h(b)r |
| 71173 |
< |
(eha)n(vior)f(sho)n(wn)-150 4795 y(previously)-7 b(.)47 |
| 71172 |
> |
2790 y(considerably)24 b(lo)n(w)n(er)f(than)i(the)h(normal)e(SSD)h(b)r |
| 71173 |
> |
(eha)n(vior)f(sho)n(wn)-150 2886 y(previously)-7 b(.)47 |
| 71174 |
|
b(A)31 b(b)r(etter)h(correction)e(w)n(ould)h(b)r(e)g(to)g(include)h |
| 71175 |
< |
(the)-150 4891 y(quadrup)r(ole-quadrup)r(ole)e(in)n(teractions)h(for)h |
| 71176 |
< |
(the)g(w)n(ater)f(parti-)-150 4986 y(cles)h(outside)h(of)f(the)h |
| 71175 |
> |
(the)-150 2981 y(quadrup)r(ole-quadrup)r(ole)e(in)n(teractions)h(for)h |
| 71176 |
> |
(the)g(w)n(ater)f(parti-)-150 3077 y(cles)h(outside)h(of)f(the)h |
| 71177 |
|
(\014rst)g(solv)-5 b(ation)31 b(shell,)j(but)f(this)g(reduces)-150 |
| 71178 |
< |
5082 y(the)g(simplicit)n(y)f(and)h(sp)r(eed)g(adv)-5 |
| 71178 |
> |
3172 y(the)g(simplicit)n(y)f(and)h(sp)r(eed)g(adv)-5 |
| 71179 |
|
b(an)n(tage)30 b(of)j(SSD,)g(so)f(it)h(is)f(not)-150 |
| 71180 |
< |
5177 y(the)c(most)f(desirable)g(path)h(to)f(tak)n(e.)2070 |
| 71181 |
< |
-31 y Fr(T)-6 b(ABLE)26 b(I:)g(P)n(arameters)g(for)g(the)f(original)j |
| 71182 |
< |
(and)d(adjusted)h(mo)r(dels)p 2228 12 1644 4 v 2270 94 |
| 71183 |
< |
a(P)n(arameters)260 b(SSD)3054 63 y Fl(y)3222 94 y Fr(SSD/E)84 |
| 71184 |
< |
b(SSD/RF)p 2228 124 V 2322 205 a Fq(\033)28 b Fr(\()2424 |
| 71185 |
< |
192 y(\027)2424 205 y(A\))398 b(3.051)169 b(3.035)k(3.019)2322 |
| 71186 |
< |
292 y Fq(\017)25 b Fr(\(k)n(cal/mol\))178 b(0.152)169 |
| 71187 |
< |
b(0.152)k(0.152)2322 379 y Fq(\026)26 b Fr(\(D\))417 |
| 71188 |
< |
b(2.35)187 b(2.418)173 b(2.480)2322 467 y Fq(\027)2360 |
| 71189 |
< |
475 y Fc(0)2420 467 y Fr(\(k)n(cal/mol\))117 b(3.7284)169 |
| 71190 |
< |
b(3.90)211 b(3.90)2322 558 y Fq(r)2357 567 y Fp(l)2406 |
| 71191 |
< |
558 y Fr(\()2436 545 y(\027)2436 558 y(A\))406 b(2.75)206 |
| 71192 |
< |
b(2.40)211 b(2.40)2322 649 y Fq(r)2357 657 y Fp(u)2423 |
| 71193 |
< |
649 y Fr(\()2453 636 y(\027)2453 649 y(A\))389 b(3.35)206 |
| 71194 |
< |
b(3.80)211 b(3.80)2322 736 y Fq(\027)2365 705 y Fl(0)2360 |
| 71195 |
< |
749 y Fc(0)2420 736 y Fr(\(k)n(cal/mol\))117 b(3.7284)169 |
| 71196 |
< |
b(3.90)211 b(3.90)2322 828 y Fq(r)2359 796 y Fl(0)2357 |
| 71197 |
< |
843 y Fp(l)2406 828 y Fr(\()2436 815 y(\027)2436 828 |
| 71198 |
< |
y(A\))406 b(2.75)206 b(2.75)211 b(2.75)2322 919 y Fq(r)2359 |
| 71199 |
< |
887 y Fl(0)2357 932 y Fp(u)2423 919 y Fr(\()2453 906 |
| 71200 |
< |
y(\027)2453 919 y(A\))389 b(4.00)206 b(3.35)211 b(3.35)2245 |
| 71201 |
< |
1020 y Fl(y)2303 1051 y Fr(ref.)35 b(5)2158 1326 y Fo(D.)87 |
| 71202 |
< |
b(Adjusted)30 b(P)n(oten)n(tials:)40 b(SSD/E)29 b(and)h(SSD/RF)2125 |
| 71203 |
< |
1540 y Fu(The)i(prop)r(ensit)n(y)f(of)h(SSD)h(to)f(adopt)g(lo)n(w)n(er) |
| 71204 |
< |
f(than)h(exp)r(ected)2042 1636 y(densities)21 b(under)g(v)-5 |
| 71205 |
< |
b(arying)21 b(conditions)f(is)i(troubling,)g(esp)r(ecially)2042 |
| 71206 |
< |
1731 y(at)32 b(higher)f(temp)r(eratures.)50 b(In)32 b(order)f(to)h |
| 71207 |
< |
(correct)f(this)h(b)r(eha)n(v-)2042 1826 y(ior,)25 b(it's)h(necessary)d |
| 71208 |
< |
(to)j(adjust)g(the)f(force)g(\014eld)h(parameters)e(for)2042 |
| 71209 |
< |
1922 y(the)g(primary)e(in)n(termolecular)g(in)n(teractions.)35 |
| 71210 |
< |
b(In)23 b(undergoing)g(a)2042 2017 y(reparameterization,)30 |
| 71211 |
< |
b(it)j(is)f(imp)r(ortan)n(t)f(not)h(to)g(fo)r(cus)g(on)g(just)2042 |
| 71212 |
< |
2113 y(one)23 b(prop)r(ert)n(y)f(and)h(neglect)g(the)g(other)g(imp)r |
| 71213 |
< |
(ortan)n(t)g(prop)r(erties.)2042 2208 y(In)38 b(this)h(case,)h(it)f(w)n |
| 71214 |
< |
(ould)f(b)r(e)g(ideal)g(to)h(correct)d(the)j(densities)2042 |
| 71215 |
< |
2304 y(while)28 b(main)n(taining)e(the)i(accurate)f(transp)r(ort)f |
| 71216 |
< |
(prop)r(erties.)2125 2399 y(The)c(p)r(ossible)h(parameters)d(for)i |
| 71217 |
< |
(tuning)h(include)g(the)g Fj(\033)j Fu(and)c Fj(\017)2042 |
| 71218 |
< |
2495 y Fu(Lennard-Jones)28 b(parameters,)h(the)h(dip)r(ole)g(strength)g |
| 71219 |
< |
(\()p Fj(\026)p Fu(\),)h(and)2042 2590 y(the)20 b(stic)n(ky)f |
| 71220 |
< |
(attractiv)n(e)g(and)g(dip)r(ole)h(repulsiv)n(e)f(terms)g(with)h(their) |
| 71221 |
< |
2042 2686 y(resp)r(ectiv)n(e)31 b(cuto\013s.)51 b(T)-7 |
| 71222 |
< |
b(o)31 b(alter)h(the)g(attractiv)n(e)f(and)h(repulsiv)n(e)2042 |
| 71223 |
< |
2781 y(terms)h(of)g(the)h(stic)n(ky)f(p)r(oten)n(tial)g(indep)r(enden)n |
| 71224 |
< |
(tly)-7 b(,)36 b(it)e(is)f(neces-)2042 2877 y(sary)26 |
| 71225 |
< |
b(to)i(separate)e(the)i(terms)f(as)g(follo)n(ws:)2150 |
| 71226 |
< |
3076 y Fj(u)2198 3036 y Fi(sp)2198 3099 y(ij)2267 3076 |
| 71227 |
< |
y Fu(\()p Fh(r)2338 3088 y Fi(ij)2398 3076 y Fj(;)14 |
| 71228 |
< |
b Fh(\012)2503 3088 y Fi(i)2531 3076 y Fj(;)g Fh(\012)2637 |
| 71229 |
< |
3088 y Fi(j)2672 3076 y Fu(\))23 b(=)2825 3020 y Fj(\027)2866 |
| 71230 |
< |
3032 y Fn(0)p 2825 3057 79 4 v 2843 3133 a Fu(2)2913 |
| 71231 |
< |
3076 y([)p Fj(s)p Fu(\()p Fj(r)3044 3088 y Fi(ij)3103 |
| 71232 |
< |
3076 y Fu(\))p Fj(w)r Fu(\()p Fh(r)3267 3088 y Fi(ij)3327 |
| 71233 |
< |
3076 y Fj(;)14 b Fh(\012)3433 3088 y Fi(i)3461 3076 y |
| 71234 |
< |
Fj(;)g Fh(\012)3567 3088 y Fi(j)3602 3076 y Fu(\)])2833 |
| 71235 |
< |
3285 y(+)2926 3229 y Fj(\027)2972 3199 y Ft(0)2967 3249 |
| 71236 |
< |
y Fn(0)p 2926 3266 V 2945 3342 a Fu(2)3015 3285 y([)p |
| 71237 |
< |
Fj(s)3077 3251 y Ft(0)3100 3285 y Fu(\()p Fj(r)3169 3297 |
| 71238 |
< |
y Fi(ij)3228 3285 y Fu(\))p Fj(w)3321 3251 y Ft(0)3345 |
| 71239 |
< |
3285 y Fu(\()p Fh(r)3416 3297 y Fi(ij)3475 3285 y Fj(;)g |
| 71240 |
< |
Fh(\012)3581 3297 y Fi(i)3609 3285 y Fj(;)g Fh(\012)3715 |
| 71241 |
< |
3297 y Fi(j)3750 3285 y Fu(\)])p Fj(;)3937 3184 y Fu(\(10\))2125 |
| 71242 |
< |
3491 y(where)27 b Fj(\027)2406 3503 y Fn(0)2471 3491 |
| 71180 |
> |
3268 y(the)c(most)f(desirable)g(path)h(to)f(tak)n(e.)-34 |
| 71181 |
> |
3544 y Fo(D.)88 b(Adjusted)29 b(P)n(oten)n(tials:)40 |
| 71182 |
> |
b(SSD/E)30 b(and)f(SSD/RF)-67 3757 y Fu(The)j(prop)r(ensit)n(y)g(of)g |
| 71183 |
> |
(SSD)h(to)f(adopt)f(lo)n(w)n(er)g(than)h(exp)r(ected)-150 |
| 71184 |
> |
3853 y(densities)21 b(under)h(v)-5 b(arying)20 b(conditions)h(is)g |
| 71185 |
> |
(troubling,)h(esp)r(ecially)-150 3948 y(at)32 b(higher)f(temp)r |
| 71186 |
> |
(eratures.)50 b(In)32 b(order)f(to)h(correct)f(this)h(b)r(eha)n(v-)-150 |
| 71187 |
> |
4044 y(ior,)25 b(it's)h(necessary)e(to)h(adjust)h(the)g(force)e |
| 71188 |
> |
(\014eld)i(parameters)e(for)-150 4139 y(the)g(primary)e(in)n |
| 71189 |
> |
(termolecular)g(in)n(teractions.)35 b(In)24 b(undergoing)e(a)-150 |
| 71190 |
> |
4235 y(reparameterization,)31 b(it)h(is)g(imp)r(ortan)n(t)f(not)h(to)g |
| 71191 |
> |
(fo)r(cus)g(on)g(just)-150 4330 y(one)23 b(prop)r(ert)n(y)f(and)h |
| 71192 |
> |
(neglect)g(the)h(other)e(imp)r(ortan)n(t)h(prop)r(erties.)-150 |
| 71193 |
> |
4426 y(In)38 b(this)h(case,)h(it)f(w)n(ould)f(b)r(e)h(ideal)f(to)g |
| 71194 |
> |
(correct)f(the)h(densities)-150 4521 y(while)28 b(main)n(taining)f(the) |
| 71195 |
> |
h(accurate)e(transp)r(ort)h(prop)r(erties.)-67 4617 y(The)c(p)r |
| 71196 |
> |
(ossible)f(parameters)f(for)h(tuning)g(include)h(the)g |
| 71197 |
> |
Fj(\033)j Fu(and)d Fj(\017)-150 4712 y Fu(Lennard-Jones)28 |
| 71198 |
> |
b(parameters,)h(the)h(dip)r(ole)h(strength)e(\()p Fj(\026)p |
| 71199 |
> |
Fu(\),)j(and)-150 4807 y(the)20 b(stic)n(ky)f(attractiv)n(e)g(and)g |
| 71200 |
> |
(dip)r(ole)h(repulsiv)n(e)f(terms)g(with)h(their)-150 |
| 71201 |
> |
4903 y(resp)r(ectiv)n(e)31 b(cuto\013s.)51 b(T)-7 b(o)32 |
| 71202 |
> |
b(alter)f(the)i(attractiv)n(e)d(and)i(repulsiv)n(e)-150 |
| 71203 |
> |
4998 y(terms)h(of)g(the)h(stic)n(ky)f(p)r(oten)n(tial)g(indep)r(enden)n |
| 71204 |
> |
(tly)-7 b(,)36 b(it)e(is)f(neces-)2070 -31 y Fr(T)-6 |
| 71205 |
> |
b(ABLE)26 b(I:)g(P)n(arameters)g(for)g(the)f(original)j(and)d(adjusted) |
| 71206 |
> |
h(mo)r(dels)p 2228 12 1644 4 v 2270 94 a(P)n(arameters)260 |
| 71207 |
> |
b(SSD)3054 63 y Fl(y)3222 94 y Fr(SSD/E)84 b(SSD/RF)p |
| 71208 |
> |
2228 124 V 2322 205 a Fq(\033)28 b Fr(\()2424 192 y(\027)2424 |
| 71209 |
> |
205 y(A\))398 b(3.051)169 b(3.035)k(3.019)2322 292 y |
| 71210 |
> |
Fq(\017)25 b Fr(\(k)n(cal/mol\))178 b(0.152)169 b(0.152)k(0.152)2322 |
| 71211 |
> |
379 y Fq(\026)26 b Fr(\(D\))417 b(2.35)187 b(2.418)173 |
| 71212 |
> |
b(2.480)2322 467 y Fq(\027)2360 475 y Fc(0)2420 467 y |
| 71213 |
> |
Fr(\(k)n(cal/mol\))117 b(3.7284)169 b(3.90)211 b(3.90)2322 |
| 71214 |
> |
558 y Fq(r)2357 567 y Fp(l)2406 558 y Fr(\()2436 545 |
| 71215 |
> |
y(\027)2436 558 y(A\))406 b(2.75)206 b(2.40)211 b(2.40)2322 |
| 71216 |
> |
649 y Fq(r)2357 657 y Fp(u)2423 649 y Fr(\()2453 636 |
| 71217 |
> |
y(\027)2453 649 y(A\))389 b(3.35)206 b(3.80)211 b(3.80)2322 |
| 71218 |
> |
736 y Fq(\027)2365 705 y Fl(0)2360 749 y Fc(0)2420 736 |
| 71219 |
> |
y Fr(\(k)n(cal/mol\))117 b(3.7284)169 b(3.90)211 b(3.90)2322 |
| 71220 |
> |
828 y Fq(r)2359 796 y Fl(0)2357 843 y Fp(l)2406 828 y |
| 71221 |
> |
Fr(\()2436 815 y(\027)2436 828 y(A\))406 b(2.75)206 b(2.75)211 |
| 71222 |
> |
b(2.75)2322 919 y Fq(r)2359 887 y Fl(0)2357 932 y Fp(u)2423 |
| 71223 |
> |
919 y Fr(\()2453 906 y(\027)2453 919 y(A\))389 b(4.00)206 |
| 71224 |
> |
b(3.35)211 b(3.35)2245 1020 y Fl(y)2303 1051 y Fr(ref.)35 |
| 71225 |
> |
b(5)2042 1326 y Fu(sary)26 b(to)i(separate)e(the)i(terms)f(as)g(follo)n |
| 71226 |
> |
(ws:)2150 1526 y Fj(u)2198 1486 y Fi(sp)2198 1549 y(ij)2267 |
| 71227 |
> |
1526 y Fu(\()p Fh(r)2338 1538 y Fi(ij)2398 1526 y Fj(;)14 |
| 71228 |
> |
b Fh(\012)2503 1538 y Fi(i)2531 1526 y Fj(;)g Fh(\012)2637 |
| 71229 |
> |
1538 y Fi(j)2672 1526 y Fu(\))23 b(=)2825 1470 y Fj(\027)2866 |
| 71230 |
> |
1482 y Fn(0)p 2825 1507 79 4 v 2843 1583 a Fu(2)2913 |
| 71231 |
> |
1526 y([)p Fj(s)p Fu(\()p Fj(r)3044 1538 y Fi(ij)3103 |
| 71232 |
> |
1526 y Fu(\))p Fj(w)r Fu(\()p Fh(r)3267 1538 y Fi(ij)3327 |
| 71233 |
> |
1526 y Fj(;)14 b Fh(\012)3433 1538 y Fi(i)3461 1526 y |
| 71234 |
> |
Fj(;)g Fh(\012)3567 1538 y Fi(j)3602 1526 y Fu(\)])2833 |
| 71235 |
> |
1735 y(+)2926 1678 y Fj(\027)2972 1648 y Ft(0)2967 1699 |
| 71236 |
> |
y Fn(0)p 2926 1715 V 2945 1792 a Fu(2)3015 1735 y([)p |
| 71237 |
> |
Fj(s)3077 1700 y Ft(0)3100 1735 y Fu(\()p Fj(r)3169 1747 |
| 71238 |
> |
y Fi(ij)3228 1735 y Fu(\))p Fj(w)3321 1700 y Ft(0)3345 |
| 71239 |
> |
1735 y Fu(\()p Fh(r)3416 1747 y Fi(ij)3475 1735 y Fj(;)g |
| 71240 |
> |
Fh(\012)3581 1747 y Fi(i)3609 1735 y Fj(;)g Fh(\012)3715 |
| 71241 |
> |
1747 y Fi(j)3750 1735 y Fu(\)])p Fj(;)3937 1634 y Fu(\(10\))2125 |
| 71242 |
> |
1941 y(where)27 b Fj(\027)2406 1953 y Fn(0)2471 1941 |
| 71243 |
|
y Fu(scales)f(the)i(strength)f(of)g(the)h(tetrahedral)e(attrac-)2042 |
| 71244 |
< |
3586 y(tion)40 b(and)g Fj(\027)2445 3556 y Ft(0)2440 |
| 71245 |
< |
3607 y Fn(0)2517 3586 y Fu(acts)g(in)g(an)g(iden)n(tical)g(fashion)g |
| 71246 |
< |
(on)g(the)g(dip)r(ole)2042 3682 y(repulsion)29 b(term.)43 |
| 71244 |
> |
2036 y(tion)40 b(and)g Fj(\027)2445 2006 y Ft(0)2440 |
| 71245 |
> |
2057 y Fn(0)2517 2036 y Fu(acts)g(in)g(an)g(iden)n(tical)g(fashion)g |
| 71246 |
> |
(on)g(the)g(dip)r(ole)2042 2131 y(repulsion)29 b(term.)43 |
| 71247 |
|
b(F)-7 b(or)30 b(purp)r(oses)f(of)h(the)g(reparameterization,)2042 |
| 71248 |
< |
3777 y(the)j(separation)e(w)n(as)g(p)r(erformed,)i(but)h(the)f(\014nal) |
| 71249 |
< |
f(parameters)2042 3873 y(w)n(ere)h(adjusted)i(so)f(that)h(it)g(is)f |
| 71250 |
< |
(unnecessary)f(to)i(separate)e(the)2042 3968 y(terms)25 |
| 71248 |
> |
2227 y(the)j(separation)e(w)n(as)g(p)r(erformed,)i(but)h(the)f(\014nal) |
| 71249 |
> |
f(parameters)2042 2322 y(w)n(ere)h(adjusted)i(so)f(that)h(it)g(is)f |
| 71250 |
> |
(unnecessary)f(to)i(separate)e(the)2042 2418 y(terms)25 |
| 71251 |
|
b(when)i(implemen)n(ting)f(the)g(adjusted)h(w)n(ater)d(p)r(oten)n |
| 71252 |
< |
(tials.)2042 4064 y(The)e(results)g(of)h(the)g(reparameterizations)c |
| 71253 |
< |
(are)j(sho)n(wn)f(in)i(table)2042 4159 y(I.)60 b(Note)35 |
| 71254 |
< |
b(that)h(b)r(oth)f(the)h(tetrahedral)e(attractiv)n(e)g(and)h(dip)r(o-) |
| 71255 |
< |
2042 4255 y(lar)k(repulsiv)n(e)g(don't)h(share)f(the)h(same)g(lo)n(w)n |
| 71256 |
< |
(er)e(cuto\013)i(\()p Fj(r)3916 4267 y Fi(l)3943 4255 |
| 71257 |
< |
y Fu(\))g(in)2042 4350 y(the)d(newly)g(parameterized)f(p)r(oten)n |
| 71258 |
< |
(tials)h(-)f(soft)i(stic)n(ky)e(dip)r(ole)2042 4446 y(enhanced)f |
| 71252 |
> |
(tials.)2042 2513 y(The)e(results)g(of)h(the)g(reparameterizations)c |
| 71253 |
> |
(are)j(sho)n(wn)f(in)i(table)2042 2609 y(I.)60 b(Note)35 |
| 71254 |
> |
b(that)h(b)r(oth)f(the)h(tetrahedral)e(attractiv)n(e)g(and)h(dip)r(o-) |
| 71255 |
> |
2042 2704 y(lar)k(repulsiv)n(e)g(don't)h(share)f(the)h(same)g(lo)n(w)n |
| 71256 |
> |
(er)e(cuto\013)i(\()p Fj(r)3916 2716 y Fi(l)3943 2704 |
| 71257 |
> |
y Fu(\))g(in)2042 2800 y(the)d(newly)g(parameterized)f(p)r(oten)n |
| 71258 |
> |
(tials)h(-)f(soft)i(stic)n(ky)e(dip)r(ole)2042 2895 y(enhanced)f |
| 71259 |
|
(\(SSD/E\))h(and)f(soft)h(stic)n(ky)f(dip)r(ole)g(reaction)g(\014eld) |
| 71260 |
< |
2042 4541 y(\(SSD/RF\).)2125 4636 y(In)20 b(the)g(pap)r(er)f(detailing) |
| 71260 |
> |
2042 2991 y(\(SSD/RF\).)2125 3086 y(In)20 b(the)g(pap)r(er)f(detailing) |
| 71261 |
|
h(the)g(dev)n(elopmen)n(t)f(of)h(SSD,)g(Liu)g(and)2042 |
| 71262 |
< |
4732 y(Ic)n(hiy)n(e)h(placed)g(particular)g(emphasis)g(on)h(an)f |
| 71263 |
< |
(accurate)g(descrip-)2042 4827 y(tion)29 b(of)f(the)i(\014rst)e(solv)-5 |
| 71262 |
> |
3182 y(Ic)n(hiy)n(e)h(placed)g(particular)g(emphasis)g(on)h(an)f |
| 71263 |
> |
(accurate)g(descrip-)2042 3277 y(tion)29 b(of)f(the)i(\014rst)e(solv)-5 |
| 71264 |
|
b(ation)28 b(shell.)40 b(This)29 b(resulted)g(in)g(a)f(some-)2042 |
| 71265 |
< |
4923 y(what)40 b(tall)f(and)h(sharp)f(\014rst)h(p)r(eak)f(that)i(in)n |
| 71266 |
< |
(tegrated)d(to)i(giv)n(e)2042 5018 y(similar)35 b(co)r(ordination)g(n)n |
| 71265 |
> |
3373 y(what)40 b(tall)f(and)h(sharp)f(\014rst)h(p)r(eak)f(that)i(in)n |
| 71266 |
> |
(tegrated)d(to)i(giv)n(e)2042 3468 y(similar)35 b(co)r(ordination)g(n)n |
| 71267 |
|
(um)n(b)r(ers)g(to)h(the)g(exp)r(erimen)n(tal)g(data)2042 |
| 71268 |
< |
5114 y(obtained)26 b(b)n(y)g(Sop)r(er)f(and)h(Phillips.)3184 |
| 71269 |
< |
5084 y Fn(5,25)3333 5114 y Fu(New)g(exp)r(erimen)n(tal)g(x-)2042 |
| 71270 |
< |
5209 y(ra)n(y)i(scattering)h(data)g(from)h(the)g(Head-Gordon)e(lab)h |
| 71271 |
< |
(indicates)2042 5305 y(a)j(sligh)n(tly)f(lo)n(w)n(er)g(and)h(shifted)h |
| 71272 |
< |
(\014rst)f(p)r(eak)f(in)i(the)f(g)3743 5317 y Fn(OO)3849 |
| 71273 |
< |
5305 y Fu(\()p Fj(r)r Fu(\),)j(so)2042 5400 y(adjustmen)n(ts)25 |
| 71268 |
> |
3564 y(obtained)26 b(b)n(y)g(Sop)r(er)f(and)h(Phillips.)3184 |
| 71269 |
> |
3533 y Fn(5,25)3333 3564 y Fu(New)g(exp)r(erimen)n(tal)g(x-)2042 |
| 71270 |
> |
3659 y(ra)n(y)i(scattering)h(data)g(from)h(the)g(Head-Gordon)e(lab)h |
| 71271 |
> |
(indicates)2042 3755 y(a)j(sligh)n(tly)f(lo)n(w)n(er)g(and)h(shifted)h |
| 71272 |
> |
(\014rst)f(p)r(eak)f(in)i(the)f(g)3743 3767 y Fn(OO)3849 |
| 71273 |
> |
3755 y Fu(\()p Fj(r)r Fu(\),)j(so)2042 3850 y(adjustmen)n(ts)25 |
| 71274 |
|
b(to)h(SSD)g(w)n(ere)e(made)h(while)h(taking)f(in)n(to)g(consid-)2042 |
| 71275 |
< |
5496 y(eration)i(the)i(new)g(exp)r(erimen)n(tal)f(\014ndings.)3442 |
| 71276 |
< |
5466 y Fn(24)3540 5496 y Fu(Figure)g(7)g(sho)n(ws)p eop |
| 71275 |
> |
3945 y(eration)i(the)i(new)g(exp)r(erimen)n(tal)f(\014ndings.)3442 |
| 71276 |
> |
3915 y Fn(24)3540 3945 y Fu(Figure)g(6)g(sho)n(ws)2042 |
| 71277 |
> |
4041 y(the)23 b(relo)r(cation)f(of)i(the)f(\014rst)g(p)r(eak)g(of)h |
| 71278 |
> |
(the)f(o)n(xygen-o)n(xygen)d(g\()p Fm(r)9 b Fu(\))2042 |
| 71279 |
> |
4136 y(b)n(y)30 b(comparing)g(the)h(original)f(SSD)i(\(with)f(and)g |
| 71280 |
> |
(without)h(reac-)2042 4232 y(tion)24 b(\014eld\),)i(SSD-E,)e(and)g |
| 71281 |
> |
(SSD-RF)h(to)g(the)f(new)h(exp)r(erimen)n(tal)2042 4327 |
| 71282 |
> |
y(results.)71 b(Both)39 b(the)g(mo)r(di\014ed)h(w)n(ater)e(mo)r(dels)h |
| 71283 |
> |
(ha)n(v)n(e)f(shorter)2042 4423 y(p)r(eaks)23 b(that)h(are)f(brough)n |
| 71284 |
> |
(t)f(in)i(more)f(closely)g(to)h(the)g(exp)r(erimen-)2042 |
| 71285 |
> |
4518 y(tal)33 b(p)r(eak)g(\(as)h(seen)f(in)h(the)f(insets)h(of)f |
| 71286 |
> |
(\014gure)g(6\).)54 b(This)34 b(struc-)2042 4614 y(tural)c(alteration)g |
| 71287 |
> |
(w)n(as)g(accomplished)h(b)n(y)f(a)h(reduction)g(in)g(the)2042 |
| 71288 |
> |
4709 y(Lennard-Jones)k Fj(\033)41 b Fu(v)-5 b(ariable)37 |
| 71289 |
> |
b(as)g(w)n(ell)g(as)g(adjustmen)n(t)h(of)g(the)2042 4805 |
| 71290 |
> |
y(stic)n(ky)25 b(p)r(oten)n(tial)h(strength)f(and)h(cuto\013s.)37 |
| 71291 |
> |
b(The)25 b(cuto\013s)h(for)g(the)2042 4900 y(tetrahedral)34 |
| 71292 |
> |
b(attractiv)n(e)g(and)i(dip)r(olar)e(repulsiv)n(e)h(terms)g(w)n(ere) |
| 71293 |
> |
2042 4996 y(nearly)24 b(sw)n(app)r(ed)h(with)h(eac)n(h)f(other.)36 |
| 71294 |
> |
b(Isosurfaces)23 b(of)j(the)g(origi-)2042 5091 y(nal)h(and)g(mo)r |
| 71295 |
> |
(di\014ed)h(stic)n(ky)f(p)r(oten)n(tials)h(are)e(sho)n(wn)h(in)h |
| 71296 |
> |
(\014gure)3993 5061 y Fb(?)4061 5091 y Fu(.)2042 5187 |
| 71297 |
> |
y(In)22 b(these)h(isosurfaces,)f(it)h(is)f(easy)f(to)i(see)f(ho)n(w)g |
| 71298 |
> |
(altering)f(the)i(cut-)2042 5282 y(o\013s)i(c)n(hanges)f(the)i |
| 71299 |
> |
(repulsiv)n(e)e(and)i(attractiv)n(e)e(c)n(haracter)f(of)j(the)2042 |
| 71300 |
> |
5378 y(particles.)53 b(With)34 b(a)f(reduced)g(repulsiv)n(e)g(surface)f |
| 71301 |
> |
(\(the)i(dark)n(er)p eop |
| 71302 |
|
%%Page: 7 7 |
| 71303 |
|
7 6 bop 4043 -299 a Fu(7)-133 2930 y @beginspecial 71 |
| 71304 |
|
@llx 60 @lly 514 @urx 743 @ury 2409 @rwi @setspecial |
| 86245 |
|
%%EOF |
| 86246 |
|
|
| 86247 |
|
%%EndDocument |
| 86248 |
< |
@endspecial -150 3100 a Fr(FIG.)26 b(7:)34 b(Plots)27 |
| 86248 |
> |
@endspecial -150 3100 a Fr(FIG.)26 b(6:)34 b(Plots)27 |
| 86249 |
|
b(comparing)e(exp)r(erimen)n(t)1076 3068 y Fc(24)1165 |
| 86250 |
|
3100 y Fr(with)g(SSD/E)g(and)g(SSD)-150 3187 y(without)c(reaction)g |
| 86251 |
|
(\014eld)g(\(top\),)g(as)h(w)n(ell)f(as)h(SSD/RF)d(and)h(SSD)g(with) |
| 480289 |
|
%%EOF |
| 480290 |
|
|
| 480291 |
|
%%EndDocument |
| 480292 |
< |
@endspecial -150 4970 a(FIG.)h(8:)36 b(Isosurfaces)29 |
| 480292 |
> |
@endspecial -150 4970 a(FIG.)h(7:)36 b(Isosurfaces)29 |
| 480293 |
|
b(of)e(the)f(stic)n(ky)g(p)r(oten)n(tial)h(for)g(SSD)f(\(left\))h(and) |
| 480294 |
|
-150 5057 y(SSD/E)37 b(&)f(SSD/RF)h(\(righ)n(t\).)68 |
| 480295 |
|
b(Ligh)n(t)37 b(areas)i(corresp)r(ond)e(to)h(the)-150 |
| 480296 |
|
5144 y(tetrahedral)29 b(attractiv)n(e)h(part,)g(and)e(the)h(dark)n(er)g |
| 480297 |
|
(areas)h(corresp)r(ond)-150 5231 y(to)c(the)f(dip)r(olar)i(repulsiv)n |
| 480298 |
< |
(e)e(part.)2042 -83 y Fu(the)e(relo)r(cation)f(of)i(the)f(\014rst)g(p)r |
| 480299 |
< |
(eak)g(of)h(the)f(o)n(xygen-o)n(xygen)d(g\()p Fm(r)9 |
| 480300 |
< |
b Fu(\))2042 12 y(b)n(y)30 b(comparing)g(the)h(original)f(SSD)i(\(with) |
| 480301 |
< |
f(and)g(without)h(reac-)2042 108 y(tion)24 b(\014eld\),)i(SSD-E,)e(and) |
| 480302 |
< |
g(SSD-RF)h(to)g(the)f(new)h(exp)r(erimen)n(tal)2042 203 |
| 480303 |
< |
y(results.)71 b(Both)39 b(the)g(mo)r(di\014ed)h(w)n(ater)e(mo)r(dels)h |
| 480304 |
< |
(ha)n(v)n(e)f(shorter)2042 299 y(p)r(eaks)23 b(that)h(are)f(brough)n(t) |
| 480305 |
< |
f(in)i(more)f(closely)g(to)h(the)g(exp)r(erimen-)2042 |
| 488683 |
< |
394 y(tal)33 b(p)r(eak)g(\(as)h(seen)f(in)h(the)f(insets)h(of)f |
| 488684 |
< |
(\014gure)g(7\).)54 b(This)34 b(struc-)2042 490 y(tural)c(alteration)g |
| 488685 |
< |
(w)n(as)g(accomplished)h(b)n(y)f(a)h(reduction)g(in)g(the)2042 |
| 488686 |
< |
585 y(Lennard-Jones)k Fj(\033)41 b Fu(v)-5 b(ariable)37 |
| 488687 |
< |
b(as)g(w)n(ell)g(as)g(adjustmen)n(t)h(of)g(the)2042 681 |
| 488688 |
< |
y(stic)n(ky)25 b(p)r(oten)n(tial)h(strength)f(and)h(cuto\013s.)37 |
| 488689 |
< |
b(The)25 b(cuto\013s)h(for)g(the)2042 776 y(tetrahedral)34 |
| 488690 |
< |
b(attractiv)n(e)g(and)i(dip)r(olar)e(repulsiv)n(e)h(terms)g(w)n(ere) |
| 488691 |
< |
2042 872 y(nearly)24 b(sw)n(app)r(ed)h(with)h(eac)n(h)f(other.)36 |
| 488692 |
< |
b(Isosurfaces)23 b(of)j(the)g(origi-)2042 967 y(nal)h(and)g(mo)r |
| 488693 |
< |
(di\014ed)h(stic)n(ky)f(p)r(oten)n(tials)h(are)e(sho)n(wn)h(in)h |
| 488694 |
< |
(\014gure)3993 937 y Fb(?)4061 967 y Fu(.)2042 1063 y(In)22 |
| 488695 |
< |
b(these)h(isosurfaces,)f(it)h(is)f(easy)f(to)i(see)f(ho)n(w)g(altering) |
| 488696 |
< |
f(the)i(cut-)2042 1158 y(o\013s)i(c)n(hanges)f(the)i(repulsiv)n(e)e |
| 488697 |
< |
(and)i(attractiv)n(e)e(c)n(haracter)f(of)j(the)2042 1254 |
| 488698 |
< |
y(particles.)53 b(With)34 b(a)f(reduced)g(repulsiv)n(e)g(surface)f |
| 488699 |
< |
(\(the)i(dark)n(er)2042 1349 y(region\),)25 b(the)h(particles)g(can)f |
| 488700 |
< |
(mo)n(v)n(e)g(closer)g(to)g(one)h(another,)f(in-)2042 |
| 488701 |
< |
1445 y(creasing)i(the)j(densit)n(y)e(for)h(the)g(o)n(v)n(erall)e |
| 488702 |
< |
(system.)41 b(This)29 b(c)n(hange)2042 1540 y(in)d(in)n(teraction)e |
| 488703 |
< |
(cuto\013)i(also)f(results)g(in)h(a)f(more)g(gradual)f(orien-)2042 |
| 488704 |
< |
1636 y(tational)c(motion)g(b)n(y)g(allo)n(wing)f(the)i(particles)f(to)g |
| 488705 |
< |
(main)n(tain)g(pre-)2042 1731 y(ferred)k(dip)r(olar)g(arrangemen)n(ts)f |
| 488706 |
< |
(b)r(efore)i(they)g(b)r(egin)g(to)g(feel)g(the)2042 1826 |
| 480298 |
> |
(e)e(part.)2042 -83 y Fu(region\),)g(the)h(particles)g(can)f(mo)n(v)n |
| 480299 |
> |
(e)g(closer)g(to)g(one)h(another,)f(in-)2042 12 y(creasing)i(the)j |
| 480300 |
> |
(densit)n(y)e(for)h(the)g(o)n(v)n(erall)e(system.)41 |
| 480301 |
> |
b(This)29 b(c)n(hange)2042 108 y(in)d(in)n(teraction)e(cuto\013)i(also) |
| 480302 |
> |
f(results)g(in)h(a)f(more)g(gradual)f(orien-)2042 203 |
| 480303 |
> |
y(tational)c(motion)g(b)n(y)g(allo)n(wing)f(the)i(particles)f(to)g |
| 480304 |
> |
(main)n(tain)g(pre-)2042 299 y(ferred)k(dip)r(olar)g(arrangemen)n(ts)f |
| 480305 |
> |
(b)r(efore)i(they)g(b)r(egin)g(to)g(feel)g(the)2042 394 |
| 480306 |
|
y(pull)c(of)g(the)g(tetrahedral)f(restructuring.)33 b(Up)r(on)22 |
| 480307 |
< |
b(mo)n(ving)d(closer)2042 1922 y(together,)28 b(the)h(dip)r(olar)e |
| 480307 |
> |
b(mo)n(ving)d(closer)2042 490 y(together,)28 b(the)h(dip)r(olar)e |
| 480308 |
|
(repulsion)h(term)g(b)r(ecomes)h(activ)n(e)e(and)2042 |
| 480309 |
< |
2017 y(excludes)39 b(the)h(unph)n(ysical)f(arrangemen)n(ts.)70 |
| 480310 |
< |
b(This)40 b(compares)2042 2113 y(with)25 b(the)g(original)e(SSD's)i |
| 480309 |
> |
585 y(excludes)39 b(the)h(unph)n(ysical)f(arrangemen)n(ts.)70 |
| 480310 |
> |
b(This)40 b(compares)2042 681 y(with)25 b(the)g(original)e(SSD's)i |
| 480311 |
|
(excluding)f(dip)r(olar)g(b)r(efore)g(the)h(par-)2042 |
| 480312 |
< |
2208 y(ticles)k(feel)h(the)f(pull)h(of)f(the)h(\\h)n(ydrogen)d(b)r |
| 480313 |
< |
(onds".)41 b(Aside)30 b(from)2042 2304 y(impro)n(ving)35 |
| 480312 |
> |
776 y(ticles)k(feel)h(the)f(pull)h(of)f(the)h(\\h)n(ydrogen)d(b)r |
| 480313 |
> |
(onds".)41 b(Aside)30 b(from)2042 872 y(impro)n(ving)35 |
| 480314 |
|
b(the)i(shap)r(e)f(of)h(the)g(\014rst)f(p)r(eak)g(in)h(the)g(g\()p |
| 480315 |
< |
Fm(r)9 b Fu(\),)39 b(this)2042 2399 y(impro)n(v)n(es)27 |
| 480315 |
> |
Fm(r)9 b Fu(\),)39 b(this)2042 967 y(impro)n(v)n(es)27 |
| 480316 |
|
b(the)h(densities)h(considerably)e(b)n(y)h(allo)n(wing)f(the)i(p)r(er-) |
| 480317 |
< |
2042 2495 y(sistence)j(of)g(full)g(dip)r(olar)g(c)n(haracter)e(b)r(elo) |
| 480318 |
< |
n(w)i(the)g(previous)f(4.0)2042 2575 y(\027)2042 2590 |
| 480319 |
< |
y(A)d(cuto\013.)2125 2686 y(While)43 b(adjusting)f(the)h(lo)r(cation)f |
| 480320 |
< |
(and)h(shap)r(e)f(of)h(the)f(\014rst)2042 2781 y(p)r(eak)23 |
| 480317 |
> |
2042 1063 y(sistence)j(of)g(full)g(dip)r(olar)g(c)n(haracter)e(b)r(elo) |
| 480318 |
> |
n(w)i(the)g(previous)f(4.0)2042 1143 y(\027)2042 1158 |
| 480319 |
> |
y(A)d(cuto\013.)2125 1254 y(While)43 b(adjusting)f(the)h(lo)r(cation)f |
| 480320 |
> |
(and)h(shap)r(e)f(of)h(the)f(\014rst)2042 1349 y(p)r(eak)23 |
| 480321 |
|
b(of)h(g\()p Fm(r)9 b Fu(\))24 b(impro)n(v)n(es)e(the)i(densities)g(to) |
| 480322 |
< |
f(some)h(degree,)f(these)2042 2877 y(c)n(hanges)34 b(alone)i(are)f |
| 480322 |
> |
f(some)h(degree,)f(these)2042 1445 y(c)n(hanges)34 b(alone)i(are)f |
| 480323 |
|
(insu\016cien)n(t)h(to)g(bring)g(the)g(system)g(den-)2042 |
| 480324 |
< |
2972 y(sities)c(up)h(to)g(the)g(v)-5 b(alues)32 b(observ)n(ed)f(exp)r |
| 480324 |
> |
1540 y(sities)c(up)h(to)g(the)g(v)-5 b(alues)32 b(observ)n(ed)f(exp)r |
| 480325 |
|
(erimen)n(tally)-7 b(.)51 b(T)-7 b(o)32 b(\014n-)2042 |
| 480326 |
< |
3068 y(ish)i(bringing)f(up)i(the)f(densities,)i(the)f(dip)r(ole)f |
| 480327 |
< |
(momen)n(ts)g(w)n(ere)2042 3163 y(increased)g(in)h(b)r(oth)h(the)g |
| 480326 |
> |
1636 y(ish)i(bringing)f(up)i(the)f(densities,)i(the)f(dip)r(ole)f |
| 480327 |
> |
(momen)n(ts)g(w)n(ere)2042 1731 y(increased)g(in)h(b)r(oth)h(the)g |
| 480328 |
|
(adjusted)f(mo)r(dels.)60 b(Being)35 b(a)g(dip)r(ole)2042 |
| 480329 |
< |
3259 y(based)e(mo)r(del,)i(the)f(structure)f(and)g(transp)r(ort)g(are)f |
| 480330 |
< |
(v)n(ery)h(sen-)2042 3354 y(sitiv)n(e)40 b(to)h(c)n(hanges)f(in)h(the)h |
| 480331 |
< |
(dip)r(ole)f(momen)n(t.)77 b(The)41 b(original)2042 3450 |
| 480332 |
< |
y(SSD)27 b(simply)f(used)h(the)f(dip)r(ole)h(momen)n(t)f(calculated)g |
| 480333 |
< |
(from)g(the)2042 3545 y(TIP3P)44 b(w)n(ater)h(mo)r(del,)50 |
| 480329 |
> |
1826 y(based)e(mo)r(del,)i(the)f(structure)f(and)g(transp)r(ort)g(are)f |
| 480330 |
> |
(v)n(ery)h(sen-)2042 1922 y(sitiv)n(e)40 b(to)h(c)n(hanges)f(in)h(the)h |
| 480331 |
> |
(dip)r(ole)f(momen)n(t.)77 b(The)41 b(original)2042 2017 |
| 480332 |
> |
y(SSD)27 b(simply)f(used)h(the)f(dip)r(ole)h(momen)n(t)f(calculated)g |
| 480333 |
> |
(from)g(the)2042 2113 y(TIP3P)44 b(w)n(ater)h(mo)r(del,)50 |
| 480334 |
|
b(whic)n(h)c(at)f(2.35)f(D)j(is)e(signi\014can)n(tly)2042 |
| 480335 |
< |
3641 y(greater)24 b(than)h(the)h(exp)r(erimen)n(tal)g(gas)e(phase)h(v) |
| 480336 |
< |
-5 b(alue)26 b(of)f(1.84)g(D.)2042 3736 y(The)33 b(larger)e(dip)r(ole)j |
| 480335 |
> |
2208 y(greater)24 b(than)h(the)h(exp)r(erimen)n(tal)g(gas)e(phase)h(v) |
| 480336 |
> |
-5 b(alue)26 b(of)f(1.84)g(D.)2042 2304 y(The)33 b(larger)e(dip)r(ole)j |
| 480337 |
|
(momen)n(t)f(is)g(a)g(more)f(realistic)g(v)-5 b(alue)33 |
| 480338 |
< |
b(and)2042 3831 y(impro)n(v)n(e)24 b(the)i(dielectric)g(prop)r(erties)f |
| 480339 |
< |
(of)h(the)g(\015uid.)37 b(Both)26 b(theo-)2042 3927 y(retical)h(and)i |
| 480338 |
> |
b(and)2042 2399 y(impro)n(v)n(e)24 b(the)i(dielectric)g(prop)r(erties)f |
| 480339 |
> |
(of)h(the)g(\015uid.)37 b(Both)26 b(theo-)2042 2495 y(retical)h(and)i |
| 480340 |
|
(exp)r(erimen)n(tal)e(measuremen)n(ts)h(indicate)g(a)g(liquid)2042 |
| 480341 |
< |
4022 y(phase)18 b(dip)r(ole)i(momen)n(t)f(ranging)e(from)i(2.4)f(D)i |
| 480342 |
< |
(to)f(v)-5 b(alues)19 b(as)f(high)2042 4118 y(as)29 b(3.11)g(D,)i(so)e |
| 480341 |
> |
2590 y(phase)18 b(dip)r(ole)i(momen)n(t)f(ranging)e(from)i(2.4)f(D)i |
| 480342 |
> |
(to)f(v)-5 b(alues)19 b(as)f(high)2042 2686 y(as)29 b(3.11)g(D,)i(so)e |
| 480343 |
|
(there)h(is)g(quite)g(a)g(range)f(a)n(v)-5 b(ailable)29 |
| 480344 |
< |
b(for)g(adjust-)2042 4213 y(ing)c(the)i(dip)r(ole)e(momen)n(t.)2880 |
| 480345 |
< |
4183 y Fn(26)q({29)3076 4213 y Fu(The)h(increasing)e(of)i(the)g(dip)r |
| 480346 |
< |
(ole)2042 4309 y(momen)n(ts)34 b(to)g(2.418)f(and)h(2.48)f(D)i(for)e |
| 480347 |
< |
(SSD/E)h(and)h(SSD/RF)2042 4404 y(resp)r(ectiv)n(ely)c(is)g(mo)r |
| 480344 |
> |
b(for)g(adjust-)2042 2781 y(ing)c(the)i(dip)r(ole)e(momen)n(t.)2880 |
| 480345 |
> |
2751 y Fn(26)q({29)3076 2781 y Fu(The)h(increasing)e(of)i(the)g(dip)r |
| 480346 |
> |
(ole)2042 2877 y(momen)n(ts)34 b(to)g(2.418)f(and)h(2.48)f(D)i(for)e |
| 480347 |
> |
(SSD/E)h(and)h(SSD/RF)2042 2972 y(resp)r(ectiv)n(ely)c(is)g(mo)r |
| 480348 |
|
(derate)h(in)g(the)g(range)f(of)g(the)i(exp)r(erimen-)2042 |
| 480349 |
< |
4500 y(tal)27 b(v)-5 b(alues;)27 b(ho)n(w)n(ev)n(er,)f(it)i(leads)f(to) |
| 480350 |
< |
g(signi\014can)n(t)g(c)n(hanges)f(in)i(the)2042 4595 |
| 480349 |
> |
3068 y(tal)27 b(v)-5 b(alues;)27 b(ho)n(w)n(ev)n(er,)f(it)i(leads)f(to) |
| 480350 |
> |
g(signi\014can)n(t)g(c)n(hanges)f(in)i(the)2042 3163 |
| 480351 |
|
y(densit)n(y)f(and)h(transp)r(ort)e(of)i(the)g(w)n(ater)e(mo)r(dels.) |
| 480352 |
< |
2125 4691 y(In)31 b(order)e(to)i(demonstrate)f(the)i(b)r(ene\014ts)f |
| 480353 |
< |
(of)g(this)g(reparam-)2042 4786 y(eterization,)i(a)g(series)f(of)h(NPT) |
| 480354 |
< |
g(and)g(NVE)g(sim)n(ulations)f(w)n(ere)2042 4882 y(p)r(erformed)25 |
| 480352 |
> |
2125 3259 y(In)31 b(order)e(to)i(demonstrate)f(the)i(b)r(ene\014ts)f |
| 480353 |
> |
(of)g(this)g(reparam-)2042 3354 y(eterization,)i(a)g(series)f(of)h(NPT) |
| 480354 |
> |
g(and)g(NVE)g(sim)n(ulations)f(w)n(ere)2042 3450 y(p)r(erformed)25 |
| 480355 |
|
b(to)h(prob)r(e)g(the)g(densit)n(y)g(and)g(transp)r(ort)f(prop)r |
| 480356 |
< |
(erties)2042 4977 y(of)37 b(the)h(adapted)f(mo)r(dels)h(and)f(compare)f |
| 480357 |
< |
(the)i(results)f(to)h(the)2042 5073 y(original)26 b(SSD)j(mo)r(del.)37 |
| 480356 |
> |
(erties)2042 3545 y(of)37 b(the)h(adapted)f(mo)r(dels)h(and)f(compare)f |
| 480357 |
> |
(the)i(results)f(to)h(the)2042 3641 y(original)26 b(SSD)j(mo)r(del.)37 |
| 480358 |
|
b(This)28 b(comparison)e(in)n(v)n(olv)n(ed)h(full)h(NPT)2042 |
| 480359 |
< |
5168 y(melting)f(sequences)f(for)g(b)r(oth)i(SSD/E)e(and)h(SSD/RF,)g |
| 480360 |
< |
(as)f(w)n(ell)2042 5264 y(as)19 b(NVE)i(transp)r(ort)e(calculations)g |
| 480361 |
< |
(at)h(b)r(oth)h(self-consisten)n(t)e(and)2042 5359 y(exp)r(erimen)n |
| 480359 |
> |
3736 y(melting)f(sequences)f(for)g(b)r(oth)i(SSD/E)e(and)h(SSD/RF,)g |
| 480360 |
> |
(as)f(w)n(ell)2042 3831 y(as)19 b(NVE)i(transp)r(ort)e(calculations)g |
| 480361 |
> |
(at)h(b)r(oth)h(self-consisten)n(t)e(and)2042 3927 y(exp)r(erimen)n |
| 480362 |
|
(tal)j(densities.)35 b(Again,)24 b(the)f(results)g(come)f(from)h(\014v) |
| 480363 |
< |
n(e)p eop |
| 480363 |
> |
n(e)2042 4022 y(separate)37 b(sim)n(ulations)h(of)h(1024)e(particle)h |
| 480364 |
> |
(systems,)j(and)e(the)2042 4118 y(melting)23 b(sequences)f(w)n(ere)g |
| 480365 |
> |
(started)g(from)h(di\013eren)n(t)g(ice)g Fj(I)3844 4130 |
| 480366 |
> |
y Fi(h)3910 4118 y Fu(crys-)2042 4213 y(tals)30 b(constructed)f(as)h |
| 480367 |
> |
(stated)g(previously)-7 b(.)44 b(Lik)n(e)30 b(b)r(efore,)g(all)g(of) |
| 480368 |
> |
2042 4309 y(the)e(NPT)f(sim)n(ulations)f(w)n(ere)h(equilibrated)f(for)h |
| 480369 |
> |
(100)f(ps)h(b)r(efore)2042 4404 y(a)36 b(200)f(ps)h(data)g(collection)g |
| 480370 |
> |
(run,)i(and)e(they)h(used)f(the)h(previ-)2042 4500 y(ous)25 |
| 480371 |
> |
b(temp)r(erature's)g(\014nal)g(con\014guration)f(as)g(a)h(starting)g(p) |
| 480372 |
> |
r(oin)n(t.)2042 4595 y(All)e(of)g(the)g(NVE)g(sim)n(ulations)f(had)h |
| 480373 |
> |
(the)g(same)f(thermalization,)2042 4691 y(equilibration,)30 |
| 480374 |
> |
b(and)g(data)f(collection)h(times)g(stated)g(earlier)f(in)2042 |
| 480375 |
> |
4786 y(this)f(pap)r(er.)2125 4882 y(Figure)i(8)g(sho)n(ws)g(the)h |
| 480376 |
> |
(densit)n(y)f(pro\014le)h(for)f(the)h(SSD/E)f(w)n(a-)2042 |
| 480377 |
> |
4977 y(ter)j(mo)r(del)g(in)h(comparison)e(to)h(the)h(original)e(SSD)i |
| 480378 |
> |
(without)g(a)2042 5073 y(reaction)k(\014eld,)k(exp)r(erimen)n(t,)g(and) |
| 480379 |
> |
d(the)g(other)g(common)f(w)n(a-)2042 5168 y(ter)g(mo)r(dels)g |
| 480380 |
> |
(considered)f(previously)-7 b(.)67 b(The)39 b(calculated)e(den-)2042 |
| 480381 |
> |
5264 y(sities)d(ha)n(v)n(e)e(increased)h(signi\014can)n(tly)g(o)n(v)n |
| 480382 |
> |
(er)f(the)i(original)e(SSD)2042 5359 y(mo)r(del)c(and)g(matc)n(h)g(the) |
| 480383 |
> |
h(exp)r(erimen)n(tal)f(v)-5 b(alue)28 b(just)h(b)r(elo)n(w)f(298)p |
| 480384 |
> |
eop |
| 480385 |
|
%%Page: 8 8 |
| 480386 |
|
8 7 bop 4043 -299 a Fu(8)-133 2245 y @beginspecial 44 |
| 480387 |
|
@llx 93 @lly 517 @urx 661 @ury 2409 @rwi @setspecial |
| 488877 |
|
%%EOF |
| 488878 |
|
|
| 488879 |
|
%%EndDocument |
| 488880 |
< |
@endspecial -150 2415 a Fr(FIG.)34 b(9:)50 b(Comparison)34 |
| 488880 |
> |
@endspecial -150 2415 a Fr(FIG.)34 b(8:)50 b(Comparison)34 |
| 488881 |
|
b(of)h(densities)f(calculated)g(with)g(SSD/E)f(to)-150 |
| 488882 |
|
2502 y(SSD)c(without)i(a)g(reaction)g(\014eld,)h(TIP4P)1102 |
| 488883 |
|
2471 y Fc(19)1168 2502 y Fr(,)g(TIP3P)1446 2471 y Fc(19)1512 |
| 488886 |
|
y Fr(.)49 b(The)31 b(upp)r(er)f(plot)g(includes)h(error)g(bars,)i(and) |
| 488887 |
|
-150 2677 y(the)23 b(calculated)h(results)f(from)g(the)g(other)g |
| 488888 |
|
(references)h(w)n(ere)g(remo)n(v)n(ed)-150 2764 y(for)i(clarit)n(y)-6 |
| 488889 |
< |
b(.)-150 3044 y Fu(separate)37 b(sim)n(ulations)h(of)h(1024)e(particle) |
| 488890 |
< |
h(systems,)j(and)e(the)-150 3140 y(melting)23 b(sequences)f(w)n(ere)g |
| 488891 |
< |
(started)h(from)f(di\013eren)n(t)h(ice)g Fj(I)1652 3152 |
| 488892 |
< |
y Fi(h)1719 3140 y Fu(crys-)-150 3235 y(tals)30 b(constructed)g(as)f |
| 488893 |
< |
(stated)h(previously)-7 b(.)44 b(Lik)n(e)30 b(b)r(efore,)g(all)g(of) |
| 488894 |
< |
-150 3331 y(the)e(NPT)f(sim)n(ulations)f(w)n(ere)h(equilibrated)g(for)f |
| 488895 |
< |
(100)g(ps)i(b)r(efore)-150 3426 y(a)36 b(200)f(ps)h(data)g(collection)g |
| 488896 |
< |
(run,)i(and)f(they)f(used)g(the)h(previ-)-150 3522 y(ous)25 |
| 488897 |
< |
b(temp)r(erature's)g(\014nal)g(con\014guration)f(as)h(a)g(starting)f(p) |
| 488898 |
< |
r(oin)n(t.)-150 3617 y(All)f(of)g(the)g(NVE)g(sim)n(ulations)f(had)h |
| 497279 |
< |
(the)g(same)f(thermalization,)-150 3713 y(equilibration,)30 |
| 497280 |
< |
b(and)g(data)g(collection)f(times)h(stated)h(earlier)d(in)-150 |
| 497281 |
< |
3808 y(this)g(pap)r(er.)-67 3903 y(Figure)i(9)g(sho)n(ws)g(the)h |
| 497282 |
< |
(densit)n(y)g(pro\014le)f(for)g(the)h(SSD/E)g(w)n(a-)-150 |
| 497283 |
< |
3999 y(ter)i(mo)r(del)h(in)f(comparison)f(to)h(the)h(original)e(SSD)i |
| 497284 |
< |
(without)g(a)-150 4094 y(reaction)k(\014eld,)k(exp)r(erimen)n(t,)g(and) |
| 497285 |
< |
d(the)g(other)g(common)g(w)n(a-)-150 4190 y(ter)f(mo)r(dels)g |
| 497286 |
< |
(considered)f(previously)-7 b(.)68 b(The)38 b(calculated)g(den-)-150 |
| 497287 |
< |
4285 y(sities)c(ha)n(v)n(e)e(increased)h(signi\014can)n(tly)g(o)n(v)n |
| 497288 |
< |
(er)f(the)i(original)f(SSD)-150 4381 y(mo)r(del)28 b(and)h(matc)n(h)f |
| 497289 |
< |
(the)g(exp)r(erimen)n(tal)g(v)-5 b(alue)28 b(just)h(b)r(elo)n(w)f(298) |
| 497290 |
< |
-150 4476 y(K.)20 b(A)n(t)h(298)f(K,)g(the)h(densit)n(y)g(of)f(SSD/E)h |
| 497291 |
< |
(is)f(0.995)p Ff(\006)p Fu(0.001)d(g/cm)1833 4446 y Fn(3)1869 |
| 497292 |
< |
4476 y Fu(,)-150 4572 y(whic)n(h)k(compares)e(w)n(ell)h(with)i(the)f |
| 497293 |
< |
(exp)r(erimen)n(tal)f(v)-5 b(alue)21 b(of)f(0.997)-150 |
| 497294 |
< |
4667 y(g/cm)40 4637 y Fn(3)118 4667 y Fu(and)41 b(is)h(considerably)e |
| 497295 |
< |
(b)r(etter)i(than)f(the)h(SSD)h(v)-5 b(alue)-150 4763 |
| 497296 |
< |
y(of)43 b(0.967)p Ff(\006)p Fu(0.003)38 b(g/cm)635 4733 |
| 497297 |
< |
y Fn(3)671 4763 y Fu(.)82 b(The)43 b(increased)f(dip)r(ole)g(momen)n(t) |
| 497298 |
< |
-150 4858 y(in)33 b(SSD/E)f(has)f(help)r(ed)i(to)f(\015atten)h(out)f |
| 497299 |
< |
(the)h(curv)n(e)e(at)h(higher)-150 4954 y(temp)r(eratures,)25 |
| 488889 |
> |
b(.)-150 3044 y Fu(K.)20 b(A)n(t)h(298)f(K,)g(the)h(densit)n(y)g(of)f |
| 488890 |
> |
(SSD/E)h(is)f(0.995)p Ff(\006)p Fu(0.001)d(g/cm)1833 |
| 488891 |
> |
3014 y Fn(3)1869 3044 y Fu(,)-150 3140 y(whic)n(h)k(compares)e(w)n(ell) |
| 488892 |
> |
h(with)i(the)f(exp)r(erimen)n(tal)f(v)-5 b(alue)21 b(of)f(0.997)-150 |
| 488893 |
> |
3235 y(g/cm)40 3205 y Fn(3)118 3235 y Fu(and)41 b(is)h(considerably)e |
| 488894 |
> |
(b)r(etter)i(than)f(the)h(SSD)h(v)-5 b(alue)-150 3331 |
| 488895 |
> |
y(of)43 b(0.967)p Ff(\006)p Fu(0.003)38 b(g/cm)635 3300 |
| 488896 |
> |
y Fn(3)671 3331 y Fu(.)82 b(The)43 b(increased)f(dip)r(ole)g(momen)n(t) |
| 488897 |
> |
-150 3426 y(in)33 b(SSD/E)f(has)f(help)r(ed)i(to)f(\015atten)h(out)f |
| 488898 |
> |
(the)h(curv)n(e)e(at)h(higher)-150 3522 y(temp)r(eratures,)25 |
| 488899 |
|
b(only)g(the)h(impro)n(v)n(emen)n(t)e(is)i(marginal)e(at)h(b)r(est.) |
| 488900 |
< |
-150 5049 y(This)30 b(steep)f(drop)h(in)f(densities)h(is)g(due)g(to)f |
| 488901 |
< |
(the)h(dip)r(olar)f(rather)-150 5145 y(than)24 b(c)n(harge)e(based)i |
| 488900 |
> |
-150 3617 y(This)30 b(steep)f(drop)h(in)f(densities)h(is)g(due)g(to)f |
| 488901 |
> |
(the)h(dip)r(olar)f(rather)-150 3713 y(than)24 b(c)n(harge)e(based)i |
| 488902 |
|
(in)n(teractions)e(whic)n(h)i(deca)n(y)f(more)g(rapidly)-150 |
| 488903 |
< |
5240 y(at)k(longer)g(distances.)-67 5336 y(By)35 b(monitoring)g(Cp)g |
| 488904 |
< |
(throughout)g(these)g(sim)n(ulations,)i(the)2059 2245 |
| 488905 |
< |
y @beginspecial 44 @llx 93 @lly 517 @urx 661 @ury 2409 |
| 488906 |
< |
@rwi @setspecial |
| 488903 |
> |
3808 y(at)k(longer)g(distances.)-67 3903 y(By)35 b(monitoring)g(Cp)g |
| 488904 |
> |
(throughout)g(these)g(sim)n(ulations,)i(the)-150 3999 |
| 488905 |
> |
y(melting)42 b(transition)f(for)g(SSD/E)g(w)n(as)g(observ)n(ed)f(at)h |
| 488906 |
> |
(230)g(K,)-150 4094 y(ab)r(out)35 b(5)f(degrees)f(lo)n(w)n(er)g(than)i |
| 488907 |
> |
(SSD.)g(The)g(resulting)f(densit)n(y)-150 4190 y(maxim)n(um)41 |
| 488908 |
> |
b(is)g(lo)r(cated)g(at)g(240)f(K,)h(again)f(ab)r(out)h(5)g(degrees)-150 |
| 488909 |
> |
4285 y(lo)n(w)n(er)33 b(than)j(the)f(SSD)h(v)-5 b(alue)35 |
| 488910 |
> |
b(of)g(245)f(K.)g(Though)h(there)g(is)g(a)-150 4381 y(decrease)30 |
| 488911 |
> |
b(in)h(b)r(oth)h(of)f(these)h(v)-5 b(alues,)32 b(the)f(corrected)f |
| 488912 |
> |
(densities)-150 4476 y(near)d(ro)r(om)f(temp)r(erature)i(justify)g(the) |
| 488913 |
> |
g(mo)r(di\014cations)f(tak)n(en.)-67 4572 y(Figure)22 |
| 488914 |
> |
b(9)f(sho)n(ws)g(a)h(densit)n(y)g(comparison)f(b)r(et)n(w)n(een)h |
| 488915 |
> |
(SSD/RF)-150 4667 y(and)28 b(SSD)h(with)f(an)g(activ)n(e)f(reaction)g |
| 488916 |
> |
(\014eld.)39 b(Lik)n(e)27 b(in)h(the)h(sim)n(u-)-150 |
| 488917 |
> |
4763 y(lations)c(of)g(SSD/E,)g(the)h(densities)g(sho)n(w)e(a)h |
| 488918 |
> |
(dramatic)g(increase)-150 4858 y(o)n(v)n(er)34 b(normal)g(SSD.)i(A)n(t) |
| 488919 |
> |
g(298)e(K,)h(SSD/RF)h(has)f(a)g(densit)n(y)g(of)-150 |
| 488920 |
> |
4954 y(0.997)p Ff(\006)p Fu(0.001)g(g/cm)522 4924 y Fn(3)559 |
| 488921 |
> |
4954 y Fu(,)42 b(righ)n(t)d(in)h(line)f(with)h(exp)r(erimen)n(t)g(and) |
| 488922 |
> |
-150 5049 y(considerably)33 b(b)r(etter)h(than)g(the)h(SSD)g(v)-5 |
| 488923 |
> |
b(alue)34 b(of)g(0.941)p Ff(\006)p Fu(0.001)-150 5145 |
| 488924 |
> |
y(g/cm)40 5115 y Fn(3)76 5145 y Fu(.)55 b(The)33 b(melting)h(p)r(oin)n |
| 488925 |
> |
(t)g(is)f(observ)n(ed)f(at)h(240)f(K,)h(whic)n(h)-150 |
| 488926 |
> |
5240 y(is)j(5)g(degrees)g(lo)n(w)n(er)e(than)j(SSD)g(with)g(a)f |
| 488927 |
> |
(reaction)g(\014eld,)j(and)-150 5336 y(the)e(densit)n(y)g(maxim)n(um)g |
| 488928 |
> |
(at)g(255)f(K,)h(again)f(5)g(degrees)g(lo)n(w)n(er)2059 |
| 488929 |
> |
2245 y @beginspecial 44 @llx 93 @lly 517 @urx 661 @ury |
| 488930 |
> |
2409 @rwi @setspecial |
| 488931 |
|
%%BeginDocument: ssdrfcompare.epsi |
| 488932 |
|
%!PS-Adobe-2.0 EPSF-1.2 |
| 488933 |
|
%%Title: ssdrfcompare.ps |
| 497483 |
|
%%EOF |
| 497484 |
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|
| 497485 |
|
%%EndDocument |
| 497486 |
< |
@endspecial 2042 2415 a Fr(FIG.)23 b(10:)34 b(Comparison)23 |
| 497487 |
< |
b(of)g(densities)h(calculated)f(with)g(SSD/RF)f(to)2042 |
| 497488 |
< |
2502 y(SSD)i(with)i(a)g(reaction)g(\014eld,)g(TIP4P)3157 |
| 497486 |
> |
@endspecial 2042 2415 a Fr(FIG.)28 b(9:)38 b(Comparison)28 |
| 497487 |
> |
b(of)g(densities)g(calculated)h(with)e(SSD/RF)g(to)2042 |
| 497488 |
> |
2502 y(SSD)d(with)i(a)g(reaction)g(\014eld,)g(TIP4P)3157 |
| 497489 |
|
2471 y Fc(19)3223 2502 y Fr(,)g(TIP3P)3495 2471 y Fc(19)3561 |
| 497490 |
|
2502 y Fr(,)g(SPC/E)3848 2471 y Fc(20)3914 2502 y Fr(,)f(and)2042 |
| 497491 |
|
2590 y(Exp)r(erimen)n(t)2435 2558 y Fc(21)2498 2590 y |
| 497492 |
|
Fr(.)55 b(The)32 b(upp)r(er)f(plot)i(includes)f(error)h(bars,)i(and)c |
| 497493 |
|
(the)2042 2677 y(calculated)26 b(results)f(from)g(the)f(other)h |
| 497494 |
|
(references)h(w)n(ere)g(remo)n(v)n(ed)d(for)2042 2764 |
| 497495 |
< |
y(clarit)n(y)-6 b(.)2042 3044 y Fu(melting)42 b(transition)f(for)g |
| 497496 |
< |
(SSD/E)g(w)n(as)g(observ)n(ed)f(at)h(230)f(K,)2042 3140 |
| 497497 |
< |
y(ab)r(out)34 b(5)g(degrees)g(lo)n(w)n(er)f(than)h(SSD.)i(The)e |
| 497498 |
< |
(resulting)g(densit)n(y)2042 3235 y(maxim)n(um)41 b(is)g(lo)r(cated)g |
| 497499 |
< |
(at)g(240)f(K,)h(again)f(ab)r(out)h(5)g(degrees)2042 |
| 497500 |
< |
3331 y(lo)n(w)n(er)33 b(than)i(the)h(SSD)g(v)-5 b(alue)35 |
| 497501 |
< |
b(of)g(245)e(K.)i(Though)g(there)g(is)g(a)2042 3426 y(decrease)30 |
| 505879 |
< |
b(in)h(b)r(oth)h(of)f(these)h(v)-5 b(alues,)32 b(the)f(corrected)f |
| 505880 |
< |
(densities)2042 3522 y(near)d(ro)r(om)f(temp)r(erature)h(justify)i(the) |
| 505881 |
< |
f(mo)r(di\014cations)f(tak)n(en.)2125 3617 y(Figure)70 |
| 505882 |
< |
b(10)g(sho)n(ws)g(a)h(densit)n(y)g(comparison)e(b)r(et)n(w)n(een)2042 |
| 505883 |
< |
3713 y(SSD/RF)41 b(and)f(SSD)h(with)g(an)g(activ)n(e)e(reaction)h |
| 505884 |
< |
(\014eld.)76 b(Lik)n(e)2042 3808 y(in)35 b(the)g(sim)n(ulations)f(of)g |
| 505885 |
< |
(SSD/E,)h(the)g(densities)f(sho)n(w)g(a)g(dra-)2042 3903 |
| 505886 |
< |
y(matic)26 b(increase)e(o)n(v)n(er)g(normal)h(SSD.)h(A)n(t)h(298)d(K,)h |
| 505887 |
< |
(SSD/RF)i(has)2042 3999 y(a)37 b(densit)n(y)g(of)h(0.997)p |
| 505888 |
< |
Ff(\006)p Fu(0.001)33 b(g/cm)3192 3969 y Fn(3)3229 3999 |
| 505889 |
< |
y Fu(,)40 b(righ)n(t)d(in)h(line)g(with)g(ex-)2042 4094 |
| 505890 |
< |
y(p)r(erimen)n(t)28 b(and)g(considerably)e(b)r(etter)j(than)f(the)h |
| 505891 |
< |
(SSD)f(v)-5 b(alue)28 b(of)2042 4190 y(0.941)p Ff(\006)p |
| 505892 |
< |
Fu(0.001)34 b(g/cm)2713 4160 y Fn(3)2750 4190 y Fu(.)70 |
| 505893 |
< |
b(The)38 b(melting)h(p)r(oin)n(t)g(is)f(observ)n(ed)f(at)2042 |
| 505894 |
< |
4285 y(240)21 b(K,)i(whic)n(h)g(is)g(5)g(degrees)f(lo)n(w)n(er)f(than)i |
| 505895 |
< |
(SSD)h(with)g(a)e(reaction)2042 4381 y(\014eld,)h(and)e(the)g(densit)n |
| 505896 |
< |
(y)h(maxim)n(um)f(at)g(255)f(K,)h(again)f(5)h(degrees)2042 |
| 505897 |
< |
4476 y(lo)n(w)n(er)26 b(than)j(SSD.)g(The)f(densit)n(y)g(at)g(higher)g |
| 505898 |
< |
(temp)r(erature)g(still)2042 4572 y(drops)c(o\013)g(more)g(rapidly)g |
| 505899 |
< |
(than)h(the)g(c)n(harge)e(based)h(mo)r(dels)h(but)2042 |
| 505900 |
< |
4667 y(is)i(in)h(b)r(etter)g(agreemen)n(t)e(than)i(SSD/E.)2125 |
| 505901 |
< |
4763 y(The)e(reparameterization)e(of)i(the)g(SSD)h(w)n(ater)e(mo)r |
| 505902 |
< |
(del,)i(b)r(oth)2042 4858 y(for)34 b(use)g(with)h(and)g(without)f(an)h |
| 505903 |
< |
(applied)f(long-range)e(correc-)2042 4954 y(tion,)41 |
| 497495 |
> |
y(clarit)n(y)-6 b(.)2042 3044 y Fu(than)27 b(SSD.)h(The)f(densit)n(y)g |
| 497496 |
> |
(at)g(higher)f(temp)r(erature)h(still)g(drops)2042 3140 |
| 497497 |
> |
y(o\013)i(more)g(rapidly)g(than)h(the)g(c)n(harge)e(based)h(mo)r(dels)g |
| 497498 |
> |
(but)h(is)g(in)2042 3235 y(b)r(etter)e(agreemen)n(t)e(than)i(SSD/E.) |
| 497499 |
> |
2125 3331 y(The)e(reparameterization)e(of)i(the)g(SSD)h(w)n(ater)e(mo)r |
| 497500 |
> |
(del,)i(b)r(oth)2042 3426 y(for)34 b(use)g(with)h(and)g(without)f(an)h |
| 497501 |
> |
(applied)f(long-range)e(correc-)2042 3522 y(tion,)41 |
| 497502 |
|
b(brough)n(t)c(the)i(densities)f(up)h(to)f(what)g(is)g(exp)r(ected)h |
| 497503 |
< |
(for)2042 5049 y(sim)n(ulating)f(liquid)i(w)n(ater.)70 |
| 497504 |
< |
b(In)40 b(addition)f(to)g(impro)n(ving)f(the)2042 5145 |
| 497503 |
> |
(for)2042 3617 y(sim)n(ulating)f(liquid)i(w)n(ater.)70 |
| 497504 |
> |
b(In)40 b(addition)f(to)g(impro)n(ving)f(the)2042 3713 |
| 497505 |
|
y(densities,)23 b(it)f(is)g(imp)r(ortan)n(t)f(that)h(particle)g(transp) |
| 497506 |
< |
r(ort)e(b)r(e)j(main-)2042 5240 y(tained)f(or)f(impro)n(v)n(ed.)34 |
| 497507 |
< |
b(Figure)22 b(11)f(compares)g(the)i(temp)r(erature)2042 |
| 497508 |
< |
5336 y(dep)r(endence)35 b(of)g(the)g(di\013usion)g(constan)n(t)f(of)g |
| 497509 |
< |
(SSD/E)h(to)f(SSD)p eop |
| 497506 |
> |
r(ort)e(b)r(e)j(main-)2042 3808 y(tained)f(or)f(impro)n(v)n(ed.)34 |
| 497507 |
> |
b(Figure)22 b(10)f(compares)g(the)i(temp)r(erature)2042 |
| 497508 |
> |
3903 y(dep)r(endence)35 b(of)g(the)g(di\013usion)g(constan)n(t)f(of)g |
| 497509 |
> |
(SSD/E)h(to)f(SSD)2042 3999 y(without)41 b(an)f(activ)n(e)g(reaction)f |
| 497510 |
> |
(\014eld,)44 b(b)r(oth)d(at)f(the)h(densities)2042 4094 |
| 497511 |
> |
y(calculated)24 b(at)g(1)g(atm)h(and)f(at)h(the)g(exp)r(erimen)n(tally) |
| 497512 |
> |
f(calculated)2042 4190 y(densities)h(for)g(sup)r(er-co)r(oled)g(and)g |
| 497513 |
> |
(liquid)h(w)n(ater.)35 b(In)26 b(the)g(upp)r(er)2042 |
| 497514 |
> |
4285 y(plot,)35 b(the)f(di\013usion)g(constan)n(t)f(for)g(SSD/E)g(is)h |
| 497515 |
> |
(consisten)n(tly)f(a)2042 4381 y(little)27 b(faster)g(than)g(exp)r |
| 497516 |
> |
(erimen)n(t,)g(while)g(SSD)h(starts)e(o\013)h(slo)n(w)n(er)2042 |
| 497517 |
> |
4476 y(than)39 b(exp)r(erimen)n(t)g(and)g(crosses)e(to)i(merge)f(with)i |
| 497518 |
> |
(SSD/E)e(at)2042 4572 y(high)24 b(temp)r(eratures.)35 |
| 497519 |
> |
b(Both)24 b(mo)r(dels)g(follo)n(w)g(the)h(exp)r(erimen)n(tal)2042 |
| 497520 |
> |
4667 y(trend)18 b(w)n(ell,)j(but)e(di\013use)g(to)r(o)f(rapidly)g(at)h |
| 497521 |
> |
(higher)f(temp)r(eratures.)2042 4763 y(This)23 b(abnormally)f(fast)h |
| 497522 |
> |
(di\013usion)h(is)f(caused)g(b)n(y)g(the)h(decreased)2042 |
| 497523 |
> |
4858 y(system)h(densit)n(y)-7 b(.)37 b(Since)26 b(the)g(densities)g(of) |
| 497524 |
> |
g(SSD/E)f(don't)i(devi-)2042 4954 y(ate)h(as)f(m)n(uc)n(h)h(from)g(exp) |
| 497525 |
> |
r(erimen)n(t)g(as)f(those)h(of)g(SSD,)h(it)f(follo)n(ws)2042 |
| 497526 |
> |
5049 y(the)f(exp)r(erimen)n(tal)g(trend)g(more)f(closely)-7 |
| 497527 |
> |
b(.)36 b(This)27 b(observ)-5 b(ation)25 b(is)2042 5145 |
| 497528 |
> |
y(bac)n(k)n(ed)35 b(up)i(b)n(y)g(lo)r(oking)e(at)i(the)g(lo)n(w)n(er)e |
| 497529 |
> |
(plot.)64 b(The)37 b(di\013usion)2042 5240 y(constan)n(ts)27 |
| 497530 |
> |
b(for)h(SSD/E)g(trac)n(k)g(with)h(the)g(exp)r(erimen)n(tal)f(v)-5 |
| 497531 |
> |
b(alues)2042 5336 y(while)28 b(SSD)g(deviates)f(on)h(the)g(lo)n(w)f |
| 497532 |
> |
(side)g(of)h(the)g(trend)g(with)g(in-)p eop |
| 497533 |
|
%%Page: 9 9 |
| 497534 |
|
9 8 bop 4043 -299 a Fu(9)-133 2393 y @beginspecial 63 |
| 497535 |
|
@llx 92 @lly 515 @urx 668 @ury 2409 @rwi @setspecial |
| 506026 |
|
%%EOF |
| 506027 |
|
|
| 506028 |
|
%%EndDocument |
| 506029 |
< |
@endspecial -150 2563 a Fr(FIG.)42 b(11:)66 b(Plots)42 |
| 506029 |
> |
@endspecial -150 2563 a Fr(FIG.)42 b(10:)66 b(Plots)42 |
| 506030 |
|
b(of)g(the)f(di\013usion)g(constan)n(ts)g(calculated)h(from)-150 |
| 506031 |
|
2650 y(SSD/E)36 b(and)g(SSD,)f(b)r(oth)h(without)h(a)f(reaction)i |
| 506032 |
|
(\014eld)e(along)h(with)-150 2737 y(exp)r(erimen)n(tal)e(results)i |
| 506036 |
|
(calculated)h(from)f(the)f(NPT)h(sim)n(ula-)-150 2912 |
| 506037 |
|
y(tions)f(at)h(a)f(pressure)g(of)h(1)f(atm,)h(while)g(the)f(lo)n(w)n |
| 506038 |
|
(er)h(plot)f(is)h(at)f(the)-150 2999 y(exp)r(erimen)n(tally)25 |
| 506039 |
< |
b(calculated)h(densities.)-150 3279 y Fu(without)41 b(an)f(activ)n(e)g |
| 506040 |
< |
(reaction)f(\014eld,)44 b(b)r(oth)d(at)g(the)f(densities)-150 |
| 506041 |
< |
3374 y(calculated)24 b(at)g(1)h(atm)f(and)h(at)f(the)h(exp)r(erimen)n |
| 506042 |
< |
(tally)f(calculated)-150 3470 y(densities)i(for)f(sup)r(er-co)r(oled)f |
| 514422 |
< |
(and)h(liquid)h(w)n(ater.)36 b(In)25 b(the)h(upp)r(er)-150 |
| 514423 |
< |
3565 y(plot,)35 b(the)f(di\013usion)g(constan)n(t)f(for)g(SSD/E)g(is)h |
| 514424 |
< |
(consisten)n(tly)f(a)-150 3661 y(little)28 b(faster)e(than)h(exp)r |
| 514425 |
< |
(erimen)n(t,)g(while)g(SSD)h(starts)e(o\013)h(slo)n(w)n(er)-150 |
| 514426 |
< |
3756 y(than)39 b(exp)r(erimen)n(t)g(and)g(crosses)e(to)i(merge)f(with)i |
| 514427 |
< |
(SSD/E)f(at)-150 3852 y(high)24 b(temp)r(eratures.)35 |
| 514428 |
< |
b(Both)24 b(mo)r(dels)h(follo)n(w)e(the)i(exp)r(erimen)n(tal)-150 |
| 514429 |
< |
3947 y(trend)19 b(w)n(ell,)h(but)f(di\013use)g(to)r(o)g(rapidly)f(at)g |
| 514430 |
< |
(higher)g(temp)r(eratures.)-150 4043 y(This)23 b(abnormally)f(fast)h |
| 514431 |
< |
(di\013usion)h(is)f(caused)g(b)n(y)g(the)h(decreased)-150 |
| 514432 |
< |
4138 y(system)i(densit)n(y)-7 b(.)36 b(Since)26 b(the)g(densities)g(of) |
| 514433 |
< |
g(SSD/E)g(don't)g(devi-)-150 4234 y(ate)i(as)f(m)n(uc)n(h)h(from)g(exp) |
| 514434 |
< |
r(erimen)n(t)g(as)f(those)h(of)g(SSD,)h(it)f(follo)n(ws)-150 |
| 514435 |
< |
4329 y(the)f(exp)r(erimen)n(tal)g(trend)g(more)f(closely)-7 |
| 514436 |
< |
b(.)36 b(This)27 b(observ)-5 b(ation)26 b(is)-150 4425 |
| 514437 |
< |
y(bac)n(k)n(ed)36 b(up)h(b)n(y)f(lo)r(oking)g(at)g(the)h(lo)n(w)n(er)e |
| 514438 |
< |
(plot.)64 b(The)37 b(di\013usion)-150 4520 y(constan)n(ts)27 |
| 514439 |
< |
b(for)h(SSD/E)h(trac)n(k)e(with)i(the)g(exp)r(erimen)n(tal)f(v)-5 |
| 514440 |
< |
b(alues)-150 4616 y(while)28 b(SSD)g(deviates)g(on)f(the)h(lo)n(w)f |
| 514441 |
< |
(side)h(of)f(the)i(trend)e(with)h(in-)-150 4711 y(creasing)d(temp)r |
| 514442 |
< |
(erature.)36 b(This)27 b(is)g(again)f(a)g(pro)r(duct)h(of)g(SSD/E)-150 |
| 514443 |
< |
4807 y(ha)n(ving)g(densities)i(closer)e(to)h(exp)r(erimen)n(t,)h(and)f |
| 514444 |
< |
(not)h(deviating)-150 4902 y(to)22 b(lo)n(w)n(er)e(densities)j(with)f |
| 506039 |
> |
b(calculated)h(densities.)-150 3279 y Fu(creasing)f(temp)r(erature.)36 |
| 506040 |
> |
b(This)27 b(is)g(again)f(a)g(pro)r(duct)h(of)g(SSD/E)-150 |
| 506041 |
> |
3374 y(ha)n(ving)g(densities)i(closer)e(to)h(exp)r(erimen)n(t,)h(and)f |
| 506042 |
> |
(not)h(deviating)-150 3470 y(to)22 b(lo)n(w)n(er)e(densities)j(with)f |
| 506043 |
|
(increasing)f(temp)r(erature)h(as)f(rapidly)-7 b(.)-67 |
| 506044 |
< |
4997 y(In)36 b(\014gure)f(12,)i(the)f(di\013usion)g(constan)n(ts)f(for) |
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g(SSD/RF)h(are)-150 5093 y(compared)k(with)j(SSD)f(with)g(an)g(activ)n |
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(e)e(reaction)h(\014eld.)79 b(In)-150 5188 y(the)39 b(upp)r(er)g(plot,) |
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3565 y(In)36 b(\014gure)f(11,)i(the)f(di\013usion)g(constan)n(ts)f(for) |
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g(SSD/RF)h(are)-150 3661 y(compared)k(with)j(SSD)f(with)g(an)g(activ)n |
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(e)e(reaction)h(\014eld.)79 b(In)-150 3756 y(the)39 b(upp)r(er)g(plot,) |
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j(SSD/RF)e(trac)n(ks)d(with)j(the)f(exp)r(erimen)n(tal)-150 |
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5284 y(results)27 b(incredibly)g(w)n(ell,)g(iden)n(tical)h(within)g |
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(error)d(throughout)-150 5379 y(the)f(temp)r(erature)f(range)g(and)g |
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(only)h(sho)n(wing)e(a)i(sligh)n(t)f(increas-)2059 2393 |
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y @beginspecial 63 @llx 92 @lly 515 @urx 668 @ury 2409 |
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@rwi @setspecial |
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3852 y(results)27 b(incredibly)g(w)n(ell,)g(iden)n(tical)h(within)g |
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> |
(error)d(throughout)-150 3947 y(the)f(temp)r(erature)f(range)g(and)g |
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(only)h(sho)n(wing)e(a)i(sligh)n(t)f(increas-)-150 4043 |
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y(ing)g(trend)g(at)g(higher)g(temp)r(eratures.)34 b(SSD)24 |
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b(also)e(trac)n(ks)g(exp)r(er-)-150 4138 y(imen)n(t)35 |
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b(w)n(ell,)h(only)e(it)h(tends)g(to)f(di\013use)h(a)f(little)i(more)d |
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(slo)n(wly)-150 4234 y(at)f(lo)n(w)g(temp)r(eratures)g(and)g(deviates)g |
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(to)g(di\013use)h(to)r(o)f(rapidly)-150 4329 y(at)26 |
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> |
b(high)h(temp)r(eratures.)35 b(As)27 b(w)n(as)e(stated)i(in)f(the)h |
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(SSD/E)f(com-)-150 4425 y(parisons,)f(this)i(deviation)f(a)n(w)n(a)n(y) |
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f(from)h(the)i(ideal)e(trend)h(is)f(due)-150 4520 y(to)38 |
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b(a)g(rapid)g(decrease)f(in)i(densit)n(y)f(at)g(higher)g(temp)r |
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(eratures.)-150 4616 y(SSD/RF)k(do)r(esn't)f(su\013er)h(from)f(this)g |
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(problem)g(as)g(m)n(uc)n(h)g(as)-150 4711 y(SSD,)36 b(b)r(ecause)f(the) |
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g(calculated)g(densities)g(are)f(more)g(true)i(to)-150 |
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4807 y(exp)r(erimen)n(t.)42 b(This)30 b(is)f(again)f(emphasized)h(in)h |
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(the)f(lo)n(w)n(er)f(plot,)-150 4902 y(where)d(SSD/RF)g(trac)n(ks)f |
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(the)h(exp)r(erimen)n(tal)g(di\013usion)g(exactly)-150 |
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> |
4997 y(while)20 b(SSD's)g(di\013usion)g(constan)n(ts)f(are)f(sligh)n |
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(tly)h(to)r(o)h(lo)n(w)f(due)h(to)-150 5093 y(its)26 |
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> |
b(need)g(for)g(a)f(lo)n(w)n(er)g(densit)n(y)g(at)h(the)h(sp)r |
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(eci\014ed)f(temp)r(erature.)2059 2393 y @beginspecial |
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> |
63 @llx 92 @lly 515 @urx 668 @ury 2409 @rwi @setspecial |
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%%BeginDocument: ssdrfdiffuse.epsi |
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%%Title: ssdrfdiffuse.ps |
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@endspecial 2042 2563 a Fr(FIG.)41 b(12:)66 b(Plots)43 |
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> |
@endspecial 2042 2563 a Fr(FIG.)41 b(11:)66 b(Plots)43 |
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|
b(of)f(the)e(di\013usion)i(constan)n(ts)f(calculated)h(from)2042 |
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2650 y(SSD/RF)31 b(and)i(SSD,)e(b)r(oth)i(with)g(an)f(activ)n(e)h |
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(reaction)h(\014eld)e(along)2042 2737 y(with)38 b(exp)r(erimen)n(tal)e |
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2824 y(The)27 b(upp)r(er)g(plot)g(is)h(at)f(densities)h(calculated)g |
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(from)f(the)g(NPT)g(sim-)2042 2912 y(ulations)f(at)f(a)h(pressure)f(of) |
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h(1)g(atm,)f(while)h(the)f(lo)n(w)n(er)h(plot)f(is)h(at)f(the)2042 |
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2999 y(exp)r(erimen)n(tally)g(calculated)h(densities.)2042 |
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3279 y Fu(ing)d(trend)g(at)g(higher)f(temp)r(eratures.)35 |
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b(SSD)24 b(also)e(trac)n(ks)g(exp)r(er-)2042 3374 y(imen)n(t)35 |
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b(w)n(ell,)h(only)e(it)h(tends)g(to)f(di\013use)h(a)f(little)i(more)d |
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(slo)n(wly)2042 3470 y(at)f(lo)n(w)g(temp)r(eratures)g(and)g(deviates)g |
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(to)g(di\013use)h(to)r(o)f(rapidly)2042 3565 y(at)26 |
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b(high)g(temp)r(eratures.)36 b(As)27 b(w)n(as)e(stated)h(in)h(the)g |
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(SSD/E)f(com-)2042 3661 y(parisons,)f(this)i(deviation)f(a)n(w)n(a)n(y) |
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f(from)h(the)h(ideal)g(trend)f(is)h(due)2042 3756 y(to)38 |
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b(a)g(rapid)g(decrease)f(in)i(densit)n(y)f(at)g(higher)g(temp)r |
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(eratures.)2042 3852 y(SSD/RF)k(do)r(esn't)f(su\013er)g(from)g(this)h |
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(problem)f(as)g(m)n(uc)n(h)g(as)2042 3947 y(SSD,)36 b(b)r(ecause)e(the) |
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i(calculated)f(densities)g(are)f(more)g(true)h(to)2042 |
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4043 y(exp)r(erimen)n(t.)42 b(This)29 b(is)h(again)e(emphasized)h(in)g |
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(the)h(lo)n(w)n(er)e(plot,)2042 4138 y(where)c(SSD/RF)i(trac)n(ks)e |
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(the)h(exp)r(erimen)n(tal)g(di\013usion)g(exactly)2042 |
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4234 y(while)20 b(SSD's)g(di\013usion)g(constan)n(ts)e(are)h(sligh)n |
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(tly)g(to)r(o)g(lo)n(w)g(due)h(to)2042 4329 y(its)26 |
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b(need)g(for)f(a)h(lo)n(w)n(er)e(densit)n(y)i(at)g(the)g(sp)r |
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(eci\014ed)h(temp)r(erature.)2508 4605 y Fo(E.)88 b(Additional)32 |
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b(Observ)-5 b(ations)2125 4819 y Fu(While)45 b(p)r(erforming)f(the)g |
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(melting)h(sequences)f(of)g(SSD/E,)2042 4914 y(some)29 |
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b(in)n(teresting)g(observ)-5 b(ations)28 b(w)n(ere)h(made.)43 |
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b(After)30 b(melting)2042 5010 y(at)k(230)f(K,)h(t)n(w)n(o)g(of)g(the)h |
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(systems)f(underw)n(en)n(t)g(crystallization)2042 5105 |
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y(ev)n(en)n(ts)23 b(near)h(245)f(K.)h(As)g(the)h(heating)f(pro)r(cess)f |
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(con)n(tin)n(ued,)i(the)2042 5201 y(t)n(w)n(o)c(systems)g(remained)g |
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(crystalline)f(un)n(til)i(\014nally)f(melting)h(b)r(e-)2042 |
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5296 y(t)n(w)n(een)32 b(320)g(and)g(330)f(K.)i(These)f(sim)n(ulations)g |
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(w)n(ere)g(excluded)2042 5392 y(from)k(the)g(data)g(set)g(sho)n(wn)f |
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(in)h(\014gure)g(9)g(and)f(replaced)h(with)p eop |
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2999 y(exp)r(erimen)n(tally)g(calculated)h(densities.)2508 |
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> |
3279 y Fo(E.)88 b(Additional)32 b(Observ)-5 b(ations)2125 |
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> |
3493 y Fu(While)45 b(p)r(erforming)f(the)g(melting)h(sequences)f(of)g |
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> |
(SSD/E,)2042 3588 y(some)29 b(in)n(teresting)g(observ)-5 |
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> |
b(ations)28 b(w)n(ere)h(made.)43 b(After)30 b(melting)2042 |
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3683 y(at)k(230)f(K,)h(t)n(w)n(o)g(of)g(the)h(systems)f(underw)n(en)n |
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> |
(t)g(crystallization)2042 3779 y(ev)n(en)n(ts)23 b(near)h(245)f(K.)h |
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> |
(As)g(the)h(heating)f(pro)r(cess)f(con)n(tin)n(ued,)i(the)2042 |
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3874 y(t)n(w)n(o)c(systems)g(remained)g(crystalline)f(un)n(til)i |
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> |
(\014nally)f(melting)h(b)r(e-)2042 3970 y(t)n(w)n(een)32 |
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> |
b(320)g(and)g(330)f(K.)i(These)f(sim)n(ulations)g(w)n(ere)g(excluded) |
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2042 4065 y(from)k(the)g(data)g(set)g(sho)n(wn)f(in)h(\014gure)g(8)g |
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(and)f(replaced)h(with)2042 4161 y(t)n(w)n(o)f(additional)g(melting)g |
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(sequences)g(that)h(did)g(not)f(undergo)2042 4256 y(this)j(anomalous)e |
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(phase)h(transition,)i(while)f(this)g(crystalliza-)2042 |
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4352 y(tion)27 b(ev)n(en)n(t)h(w)n(as)e(in)n(v)n(estigated)g |
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(separately)-7 b(.)2125 4447 y(The)21 b(\014nal)g(con\014gurations)f |
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(of)h(these)g(t)n(w)n(o)g(melting)g(sequences)2042 4543 |
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y(sho)n(ws)d(an)h(expanded)f(zeolite-lik)n(e)g(crystal)h(structure)f |
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(that)i(do)r(es)2042 4638 y(not)39 b(corresp)r(ond)e(to)i(an)n(y)f(kno) |
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> |
n(wn)h(form)f(of)h(ice.)71 b(F)-7 b(or)39 b(con)n(v)n(e-)2042 |
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> |
4734 y(nience)23 b(and)h(to)f(help)h(distinguish)g(it)g(from)f(the)h |
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> |
(exp)r(erimen)n(tally)2042 4829 y(observ)n(ed)32 b(forms)i(of)g(ice,)h |
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(this)g(crystal)e(structure)g(will)i(hence-)2042 4925 |
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y(forth)29 b(b)r(e)h(referred)e(to)h(as)g(ice-zero)f(\(ice)i(0\).)42 |
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> |
b(The)29 b(crystallinit)n(y)2042 5020 y(w)n(as)d(extensiv)n(e)g(enough) |
| 514588 |
> |
g(than)h(a)f(near)g(ideal)h(crystal)f(structure)2042 |
| 514589 |
> |
5116 y(could)31 b(b)r(e)h(obtained.)49 b(Figure)31 b(12)f(sho)n(ws)h |
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> |
(the)h(rep)r(eating)e(crys-)2042 5211 y(tal)37 b(structure)f(of)h(a)g |
| 514591 |
> |
(t)n(ypical)f(crystal)g(at)h(5)g(K.)f(The)i(unit)f(cell)2042 |
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> |
5307 y(con)n(tains)27 b(eigh)n(t)i(molecules,)f(and)g(\014gure)g(13)g |
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(sho)n(ws)f(a)h(unit)h(cell)2042 5402 y(built)34 b(from)g(the)g(w)n |
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(ater)f(particle)g(cen)n(ter)h(of)g(masses)e(that)j(can)p |
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> |
eop |
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10 9 bop 4001 -299 a Fu(10)-133 1529 y @beginspecial |
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0 @llx 0 @lly 1169 @urx 987 @ury 2409 @rwi @setspecial |
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%%EOF |
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@endspecial -150 1699 a Fr(FIG.)26 b(13:)35 b(Crystal)26 |
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@endspecial -150 1699 a Fr(FIG.)26 b(12:)35 b(Crystal)26 |
| 619541 |
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b(structure)e(of)i(an)g(ice)f(0)h(lattice)g(sho)n(wn)g(from)f(the)-150 |
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1787 y(\(001\))i(face.)-150 2071 y Fu(t)n(w)n(o)35 b(additional)g |
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(melting)g(sequences)g(that)h(did)g(not)g(undergo)-150 |
| 627925 |
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2166 y(this)i(anomalous)e(phase)h(transition,)j(while)d(this)h |
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(crystalliza-)-150 2262 y(tion)28 b(ev)n(en)n(t)f(w)n(as)f(in)n(v)n |
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(estigated)h(separately)-7 b(.)-67 2357 y(The)21 b(\014nal)g |
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(con\014gurations)f(of)h(these)g(t)n(w)n(o)g(melting)g(sequences)-150 |
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2453 y(sho)n(ws)d(an)h(expanded)g(zeolite-lik)n(e)f(crystal)g |
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(structure)g(that)i(do)r(es)-150 2548 y(not)39 b(corresp)r(ond)e(to)i |
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(an)n(y)g(kno)n(wn)f(form)h(of)g(ice.)71 b(F)-7 b(or)38 |
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b(con)n(v)n(e-)-150 2644 y(nience)24 b(and)f(to)g(help)h(distinguish)g |
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(it)g(from)f(the)h(exp)r(erimen)n(tally)-150 2739 y(observ)n(ed)32 |
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b(forms)i(of)g(ice,)i(this)e(crystal)f(structure)g(will)i(hence-)-150 |
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2835 y(forth)29 b(b)r(e)h(referred)e(to)i(as)e(ice-zero)g(\(ice)i(0\).) |
| 627936 |
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42 b(The)29 b(crystallinit)n(y)-150 2930 y(w)n(as)d(extensiv)n(e)g |
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(enough)g(than)h(a)g(near)f(ideal)g(crystal)g(structure)-150 |
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3026 y(could)31 b(b)r(e)h(obtained.)49 b(Figure)31 b(13)f(sho)n(ws)h |
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(the)h(rep)r(eating)f(crys-)-150 3121 y(tal)37 b(structure)f(of)h(a)g |
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(t)n(ypical)g(crystal)e(at)i(5)g(K.)g(The)g(unit)g(cell)-150 |
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3217 y(con)n(tains)28 b(eigh)n(t)g(molecules,)g(and)g(\014gure)g(14)g |
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(sho)n(ws)f(a)h(unit)h(cell)-150 3312 y(built)35 b(from)e(the)h(w)n |
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(ater)f(particle)h(cen)n(ter)f(of)h(masses)f(that)h(can)-150 |
| 627944 |
< |
3408 y(b)r(e)i(used)f(to)g(construct)g(a)g(rep)r(eating)f(lattice,)j |
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| 627949 |
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| 627950 |
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3789 y(tetrahedral)c(geometry)g(ab)r(out)h(the)h(cen)n(tral)e |
| 627951 |
< |
(molecule.)42 b(Lo)r(ok-)-150 3885 y(ing)36 b(bac)n(k)f(at)h(\014gure)g |
| 627952 |
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| 627953 |
< |
3980 y(h)n(ydrogen)20 b(b)r(onds)i(are)f(allo)n(w)n(ed)f(in)i(that)g |
| 627954 |
< |
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| 627955 |
< |
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| 627956 |
< |
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| 627957 |
< |
(\015exed)f(h)n(ydrogen)-150 4267 y(b)r(onds)e(are)f(fa)n(v)n(orable)f |
| 627958 |
< |
(enough)h(to)h(stabilize)g(an)g(en)n(tire)g(crystal)-150 |
| 627959 |
< |
4362 y(generated)22 b(around)h(them.)36 b(In)24 b(fact,)h(the)f(imp)r |
| 627960 |
< |
(erfect)g(ice)f(0)h(crys-)-150 4458 y(tals)e(w)n(ere)g(so)f(stable)h |
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| 627965 |
< |
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< |
(b)r(et)n(w)n(een)f(near)g(ideal)g(crystals)f(of)-150 |
| 627967 |
< |
4935 y(ice)24 b Fj(I)7 4947 y Fi(h)50 4935 y Fu(,)h(ice)f |
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< |
Fj(I)255 4947 y Fi(c)289 4935 y Fu(,)h(and)f(ice)f(0)h(at)g(constan)n |
| 627969 |
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(t)f(pressure)f(with)j(SSD/E,)-150 5031 y(SSD/RF,)e(and)g(SSD.)g(Near)f |
| 627970 |
< |
(ideal)h(v)n(ersions)d(of)j(the)g(three)f(t)n(yp)r(es)-150 |
| 627971 |
< |
5126 y(of)32 b(crystals)f(w)n(ere)g(co)r(oled)g(to)64 |
| 627972 |
< |
b(1)31 b(K,)h(and)g(the)g(p)r(oten)n(tial)g(ener-)-150 |
| 627973 |
< |
5222 y(gies)25 b(of)g(eac)n(h)g(w)n(ere)f(compared)h(using)g(all)g |
| 627974 |
< |
(three)g(w)n(ater)f(mo)r(dels.)-150 5317 y(With)d(ev)n(ery)d(w)n(ater)h |
| 627975 |
< |
(mo)r(del,)i(ice)f(0)f(turned)h(out)g(to)g(ha)n(v)n(e)e(the)i(lo)n(w-) |
| 627976 |
< |
-150 5412 y(est)31 b(p)r(oten)n(tial)h(energy:)43 b(5\045)31 |
| 627977 |
< |
b(lo)n(w)n(er)f(than)h Fj(I)1239 5424 y Fi(h)1314 5412 |
| 627978 |
< |
y Fu(with)h(SSD,)g(6.5\045)2295 1131 y @beginspecial |
| 627979 |
< |
0 @llx 0 @lly 232 @urx 196 @ury 1842 @rwi @setspecial |
| 619542 |
> |
1787 y(\(001\))i(face.)103 3219 y @beginspecial 0 @llx |
| 619543 |
> |
0 @lly 232 @urx 196 @ury 1842 @rwi @setspecial |
| 619544 |
|
%%BeginDocument: ice0cell.eps |
| 619545 |
|
%!PS-Adobe-3.1 EPSF-3.0 |
| 619546 |
|
%%Title: ice0cell.eps |
| 627331 |
|
%AI9_PrivateDataEnd |
| 627332 |
|
|
| 627333 |
|
%%EndDocument |
| 627334 |
< |
@endspecial 2042 1301 a Fr(FIG.)c(14:)39 b(Simple)27 |
| 627335 |
< |
b(unit)h(cell)g(for)h(constructing)f(ice)h(0.)41 b(In)27 |
| 627336 |
< |
b(this)h(cell,)2042 1389 y Fq(c)e Fr(is)g(equal)g(to)f(0)p |
| 627337 |
< |
Fq(:)p Fr(4714)20 b Fa(\002)d Fq(a)p Fr(,)25 b(and)h(a)g(t)n(ypical)f |
| 627338 |
< |
(v)l(alue)h(for)g Fq(a)f Fr(is)i(8.25)3956 1376 y(\027)3956 |
| 627339 |
< |
1389 y(A.)2042 1669 y Fu(lo)n(w)n(er)g(with)h(SSD/E,)h(and)f(7.5\045)f |
| 627340 |
< |
(lo)n(w)n(er)g(with)i(SSD/RF.)g(In)f(all)2042 1764 y(three)35 |
| 627341 |
< |
b(of)g(these)h(w)n(ater)e(mo)r(dels,)k(ice)d Fj(I)3302 |
| 627342 |
< |
1776 y Fi(c)3372 1764 y Fu(w)n(as)g(observ)n(ed)e(to)j(b)r(e)2042 |
| 627343 |
< |
1860 y(2\045)23 b(less)g(stable)h(than)g(ice)f Fj(I)2908 |
| 627344 |
< |
1872 y Fi(h)2952 1860 y Fu(.)36 b(In)23 b(addition)h(to)g(ha)n(ving)e |
| 627345 |
< |
(the)i(lo)n(w-)2042 1955 y(est)j(p)r(oten)n(tial)h(energy)-7 |
| 627334 |
> |
@endspecial -150 3389 a(FIG.)h(13:)40 b(Simple)27 b(unit)g(cell)i(for) |
| 627335 |
> |
f(constructing)g(ice)h(0.)41 b(In)27 b(this)h(cell,)-150 |
| 627336 |
> |
3476 y Fq(c)e Fr(is)g(equal)g(to)g(0)p Fq(:)p Fr(4714)19 |
| 627337 |
> |
b Fa(\002)e Fq(a)p Fr(,)25 b(and)h(a)g(t)n(ypical)f(v)l(alue)h(for)g |
| 627338 |
> |
Fq(a)g Fr(is)g(8.25)1764 3463 y(\027)1764 3476 y(A.)-150 |
| 627339 |
> |
3756 y Fu(b)r(e)36 b(used)f(to)g(construct)g(a)g(rep)r(eating)f |
| 627340 |
> |
(lattice,)j(similar)e(to)g(\014g-)-150 3852 y(ure)28 |
| 627341 |
> |
b(12.)38 b(Eac)n(h)27 b(molecule)h(is)h(h)n(ydrogen)d(b)r(onded)j(to)f |
| 627342 |
> |
(four)g(other)-150 3947 y(w)n(ater)c(molecules;)h(ho)n(w)n(ev)n(er,)e |
| 627343 |
> |
(the)i(h)n(ydrogen)e(b)r(onds)i(are)e(\015exed)-150 4043 |
| 627344 |
> |
y(rather)31 b(than)h(p)r(erfectly)g(straigh)n(t.)49 b(This)32 |
| 627345 |
> |
b(results)g(in)g(a)g(sk)n(ew)n(ed)-150 4138 y(tetrahedral)c(geometry)g |
| 627346 |
> |
(ab)r(out)h(the)h(cen)n(tral)e(molecule.)42 b(Lo)r(ok-)-150 |
| 627347 |
> |
4234 y(ing)36 b(bac)n(k)f(at)h(\014gure)g(7,)i(it)e(is)h(easy)e(to)h |
| 627348 |
> |
(see)g(ho)n(w)f(these)h(\015exed)-150 4329 y(h)n(ydrogen)20 |
| 627349 |
> |
b(b)r(onds)i(are)f(allo)n(w)n(ed)f(in)i(that)g(the)g(attractiv)n(e)f |
| 627350 |
> |
(regions)-150 4425 y(are)30 b(conical)f(in)i(shap)r(e,)g(with)g(the)g |
| 627351 |
> |
(greatest)f(attraction)f(in)i(the)-150 4520 y(cen)n(tral)e(region.)44 |
| 627352 |
> |
b(Though)30 b(not)g(ideal,)h(these)g(\015exed)f(h)n(ydrogen)-150 |
| 627353 |
> |
4615 y(b)r(onds)e(are)f(fa)n(v)n(orable)f(enough)h(to)h(stabilize)g(an) |
| 627354 |
> |
g(en)n(tire)g(crystal)-150 4711 y(generated)22 b(around)h(them.)36 |
| 627355 |
> |
b(In)24 b(fact,)h(the)f(imp)r(erfect)g(ice)f(0)h(crys-)-150 |
| 627356 |
> |
4806 y(tals)e(w)n(ere)g(so)f(stable)h(that)h(they)g(melted)g(at)f |
| 627357 |
> |
(greater)f(than)h(ro)r(om)-150 4902 y(temp)r(erature.)-67 |
| 627358 |
> |
4997 y(The)29 b(initial)g(sim)n(ulations)e(indicated)i(that)g(ice)f(0)h |
| 627359 |
> |
(is)f(the)h(pre-)-150 5093 y(ferred)37 b(ice)g(structure)f(for)h(at)g |
| 627360 |
> |
(least)g(SSD/E.)g(T)-7 b(o)37 b(v)n(erify)f(this,)-150 |
| 627361 |
> |
5188 y(a)h(comparison)f(w)n(as)g(made)i(b)r(et)n(w)n(een)f(near)g |
| 627362 |
> |
(ideal)g(crystals)f(of)-150 5284 y(ice)24 b Fj(I)7 5296 |
| 627363 |
> |
y Fi(h)50 5284 y Fu(,)h(ice)f Fj(I)255 5296 y Fi(c)289 |
| 627364 |
> |
5284 y Fu(,)h(and)f(ice)f(0)h(at)g(constan)n(t)f(pressure)f(with)j |
| 627365 |
> |
(SSD/E,)-150 5379 y(SSD/RF,)e(and)g(SSD.)g(Near)f(ideal)h(v)n(ersions)d |
| 627366 |
> |
(of)j(the)g(three)f(t)n(yp)r(es)2042 -83 y(of)32 b(crystals)e(w)n(ere)h |
| 627367 |
> |
(co)r(oled)h(to)64 b(1)31 b(K,)h(and)g(the)g(p)r(oten)n(tial)g(ener-) |
| 627368 |
> |
2042 12 y(gies)25 b(of)g(eac)n(h)g(w)n(ere)f(compared)g(using)h(all)h |
| 627369 |
> |
(three)f(w)n(ater)f(mo)r(dels.)2042 108 y(With)c(ev)n(ery)f(w)n(ater)g |
| 627370 |
> |
(mo)r(del,)i(ice)f(0)f(turned)h(out)g(to)g(ha)n(v)n(e)e(the)i(lo)n(w-) |
| 627371 |
> |
2042 203 y(est)31 b(p)r(oten)n(tial)g(energy:)44 b(5\045)31 |
| 627372 |
> |
b(lo)n(w)n(er)e(than)j Fj(I)3431 215 y Fi(h)3506 203 |
| 627373 |
> |
y Fu(with)g(SSD,)g(6.5\045)2042 299 y(lo)n(w)n(er)27 |
| 627374 |
> |
b(with)h(SSD/E,)h(and)f(7.5\045)f(lo)n(w)n(er)g(with)i(SSD/RF.)g(In)f |
| 627375 |
> |
(all)2042 394 y(three)35 b(of)g(these)h(w)n(ater)e(mo)r(dels,)k(ice)d |
| 627376 |
> |
Fj(I)3302 406 y Fi(c)3372 394 y Fu(w)n(as)g(observ)n(ed)e(to)j(b)r(e) |
| 627377 |
> |
2042 490 y(2\045)23 b(less)g(stable)h(than)g(ice)f Fj(I)2908 |
| 627378 |
> |
502 y Fi(h)2952 490 y Fu(.)36 b(In)23 b(addition)h(to)g(ha)n(ving)e |
| 627379 |
> |
(the)i(lo)n(w-)2042 585 y(est)j(p)r(oten)n(tial)h(energy)-7 |
| 627380 |
|
b(,)26 b(ice)i(0)f(w)n(as)g(the)h(most)f(expanded)g(of)h(the)2042 |
| 627381 |
< |
2051 y(three)i(ice)h(crystals,)60 b(5\045)31 b(less)f(dense)g(than)h |
| 627382 |
< |
(ice)g Fj(I)3633 2063 y Fi(h)3707 2051 y Fu(with)g(all)f(of)2042 |
| 627383 |
< |
2146 y(the)h(w)n(ater)f(mo)r(dels.)47 b(In)31 b(all)g(three)g(w)n(ater) |
| 627384 |
< |
f(mo)r(dels,)i(ice)f Fj(I)3887 2158 y Fi(c)3952 2146 |
| 627385 |
< |
y Fu(w)n(as)2042 2242 y(observ)n(ed)26 b(to)h(b)r(e)56 |
| 627386 |
< |
b(2\045)27 b(more)g(dense)h(than)f(ice)h Fj(I)3553 2254 |
| 627387 |
< |
y Fi(h)3596 2242 y Fu(.)2125 2337 y(In)c(addition)g(to)g(the)h(lo)n(w)e |
| 627388 |
< |
(temp)r(erature)h(comparisons,)f(melt-)2042 2433 y(ing)38 |
| 627389 |
< |
b(sequences)g(w)n(ere)f(p)r(erformed)i(with)g(ice)f(0)g(as)g(the)h |
| 627390 |
< |
(initial)2042 2528 y(con\014guration)19 b(using)h(SSD/E,)h(SSD/RF,)g |
| 627391 |
< |
(and)g(SSD)g(b)r(oth)h(with)2042 2624 y(and)k(without)h(a)f(reaction)f |
| 627392 |
< |
(\014eld.)36 b(The)27 b(melting)f(transitions)g(for)2042 |
| 627393 |
< |
2719 y(b)r(oth)20 b(SSD/E)g(and)f(SSD)i(without)f(a)g(reaction)e |
| 627394 |
< |
(\014eld)j(o)r(ccurred)d(at)2042 2814 y(temp)r(erature)29 |
| 627395 |
< |
b(in)g(excess)g(of)g(375)f(K.)h(SSD/RF)h(and)g(SSD)g(with)2042 |
| 627396 |
< |
2910 y(a)c(reaction)f(\014eld)i(had)f(more)g(reasonable)e(melting)j |
| 627397 |
< |
(transitions,)2042 3005 y(do)n(wn)h(near)f(325)g(K.)h(These)g(melting)h |
| 627398 |
< |
(p)r(oin)n(t)g(observ)-5 b(ations)26 b(em-)2042 3101 |
| 627399 |
< |
y(phasize)34 b(ho)n(w)h(preferred)f(this)h(crystal)f(structure)h(is)g |
| 627400 |
< |
(o)n(v)n(er)e(the)2042 3196 y(most)27 b(common)h(t)n(yp)r(es)f(of)h |
| 627401 |
< |
(ice)g(when)g(using)f(these)h(single)f(p)r(oin)n(t)2042 |
| 627402 |
< |
3292 y(w)n(ater)f(mo)r(dels.)2125 3387 y(Recognizing)c(that)i(the)h(ab) |
| 627403 |
< |
r(o)n(v)n(e)d(tests)i(sho)n(w)f(ice)h(0)f(to)h(b)r(e)g(b)r(oth)2042 |
| 627404 |
< |
3483 y(the)32 b(most)f(stable)h(and)f(lo)n(w)n(est)g(densit)n(y)g |
| 627405 |
< |
(crystal)g(structure)g(for)2042 3578 y(these)26 b(single)g(p)r(oin)n(t) |
| 627406 |
< |
h(w)n(ater)f(mo)r(dels,)h(it)g(is)f(in)n(teresting)g(to)g(sp)r(ec-)2042 |
| 627407 |
< |
3674 y(ulate)c(on)g(the)g(fa)n(v)n(orabilit)n(y)e(of)i(this)h(crystal)e |
| 627408 |
< |
(structure)g(with)i(the)2042 3769 y(di\013eren)n(t)33 |
| 627409 |
< |
b(c)n(harge)e(based)i(mo)r(dels.)53 b(As)33 b(a)f(quic)n(k)h(test,)i |
| 627410 |
< |
(these)e(3)2042 3865 y(crystal)28 b(t)n(yp)r(es)h(w)n(ere)f(con)n(v)n |
| 627411 |
< |
(erted)f(from)i(SSD)h(t)n(yp)r(e)f(particles)f(to)2042 |
| 627412 |
< |
3960 y(TIP3P)h(w)n(aters)h(and)h(read)f(in)n(to)h(CHARMM.)3527 |
| 627413 |
< |
3930 y Fn(30)3629 3960 y Fu(Iden)n(tical)f(en-)2042 4056 |
| 627414 |
< |
y(ergy)f(minimizations)i(w)n(ere)e(p)r(erformed)i(on)f(all)g(of)h |
| 627415 |
< |
(these)f(crys-)2042 4151 y(tals)36 b(to)g(compare)e(the)j(system)f |
| 627416 |
< |
(energies.)61 b(Again,)38 b(ice)e(0)f(w)n(as)2042 4247 |
| 627417 |
< |
y(observ)n(ed)23 b(to)i(ha)n(v)n(e)f(the)h(lo)n(w)n(est)f(total)h |
| 627418 |
< |
(system)g(energy)-7 b(.)35 b(The)25 b(to-)2042 4342 y(tal)c(energy)e |
| 627419 |
< |
(of)i(ice)g(0)f(w)n(as)41 b(2\045)21 b(lo)n(w)n(er)e(than)i(ice)g |
| 627420 |
< |
Fj(I)3543 4354 y Fi(h)3586 4342 y Fu(,)h(whic)n(h)f(w)n(as)f(in)2042 |
| 627421 |
< |
4438 y(turn)50 b(3\045)25 b(lo)n(w)n(er)e(than)i(ice)g |
| 627422 |
< |
Fj(I)2948 4450 y Fi(c)2983 4438 y Fu(.)36 b(F)-7 b(rom)24 |
| 627423 |
< |
b(these)h(initial)h(results,)f(w)n(e)2042 4533 y(w)n(ould)g(not)h(b)r |
| 627381 |
> |
681 y(three)i(ice)h(crystals,)60 b(5\045)31 b(less)f(dense)g(than)h |
| 627382 |
> |
(ice)g Fj(I)3633 693 y Fi(h)3707 681 y Fu(with)g(all)f(of)2042 |
| 627383 |
> |
776 y(the)h(w)n(ater)f(mo)r(dels.)47 b(In)31 b(all)g(three)g(w)n(ater)f |
| 627384 |
> |
(mo)r(dels,)i(ice)f Fj(I)3887 788 y Fi(c)3952 776 y Fu(w)n(as)2042 |
| 627385 |
> |
872 y(observ)n(ed)26 b(to)h(b)r(e)56 b(2\045)27 b(more)g(dense)h(than)f |
| 627386 |
> |
(ice)h Fj(I)3553 884 y Fi(h)3596 872 y Fu(.)2125 967 |
| 627387 |
> |
y(In)c(addition)g(to)g(the)h(lo)n(w)e(temp)r(erature)h(comparisons,)f |
| 627388 |
> |
(melt-)2042 1063 y(ing)38 b(sequences)g(w)n(ere)f(p)r(erformed)i(with)g |
| 627389 |
> |
(ice)f(0)g(as)g(the)h(initial)2042 1158 y(con\014guration)19 |
| 627390 |
> |
b(using)h(SSD/E,)h(SSD/RF,)g(and)g(SSD)g(b)r(oth)h(with)2042 |
| 627391 |
> |
1254 y(and)k(without)h(a)f(reaction)f(\014eld.)36 b(The)27 |
| 627392 |
> |
b(melting)f(transitions)g(for)2042 1349 y(b)r(oth)20 |
| 627393 |
> |
b(SSD/E)g(and)f(SSD)i(without)f(a)g(reaction)e(\014eld)j(o)r(ccurred)d |
| 627394 |
> |
(at)2042 1445 y(temp)r(erature)29 b(in)g(excess)g(of)g(375)f(K.)h |
| 627395 |
> |
(SSD/RF)h(and)g(SSD)g(with)2042 1540 y(a)c(reaction)f(\014eld)i(had)f |
| 627396 |
> |
(more)g(reasonable)e(melting)j(transitions,)2042 1636 |
| 627397 |
> |
y(do)n(wn)h(near)f(325)g(K.)h(These)g(melting)h(p)r(oin)n(t)g(observ)-5 |
| 627398 |
> |
b(ations)26 b(em-)2042 1731 y(phasize)34 b(ho)n(w)h(preferred)f(this)h |
| 627399 |
> |
(crystal)f(structure)h(is)g(o)n(v)n(er)e(the)2042 1826 |
| 627400 |
> |
y(most)27 b(common)h(t)n(yp)r(es)f(of)h(ice)g(when)g(using)f(these)h |
| 627401 |
> |
(single)f(p)r(oin)n(t)2042 1922 y(w)n(ater)f(mo)r(dels.)2125 |
| 627402 |
> |
2017 y(Recognizing)c(that)i(the)h(ab)r(o)n(v)n(e)d(tests)i(sho)n(w)f |
| 627403 |
> |
(ice)h(0)f(to)h(b)r(e)g(b)r(oth)2042 2113 y(the)32 b(most)f(stable)h |
| 627404 |
> |
(and)f(lo)n(w)n(est)g(densit)n(y)g(crystal)g(structure)g(for)2042 |
| 627405 |
> |
2208 y(these)26 b(single)g(p)r(oin)n(t)h(w)n(ater)f(mo)r(dels,)h(it)g |
| 627406 |
> |
(is)f(in)n(teresting)g(to)g(sp)r(ec-)2042 2304 y(ulate)c(on)g(the)g(fa) |
| 627407 |
> |
n(v)n(orabilit)n(y)e(of)i(this)h(crystal)e(structure)g(with)i(the)2042 |
| 627408 |
> |
2399 y(di\013eren)n(t)33 b(c)n(harge)e(based)i(mo)r(dels.)53 |
| 627409 |
> |
b(As)33 b(a)f(quic)n(k)h(test,)i(these)e(3)2042 2495 |
| 627410 |
> |
y(crystal)28 b(t)n(yp)r(es)h(w)n(ere)f(con)n(v)n(erted)f(from)i(SSD)h |
| 627411 |
> |
(t)n(yp)r(e)f(particles)f(to)2042 2590 y(TIP3P)h(w)n(aters)h(and)h |
| 627412 |
> |
(read)f(in)n(to)h(CHARMM.)3527 2560 y Fn(30)3629 2590 |
| 627413 |
> |
y Fu(Iden)n(tical)f(en-)2042 2686 y(ergy)f(minimizations)i(w)n(ere)e(p) |
| 627414 |
> |
r(erformed)i(on)f(all)g(of)h(these)f(crys-)2042 2781 |
| 627415 |
> |
y(tals)36 b(to)g(compare)e(the)j(system)f(energies.)61 |
| 627416 |
> |
b(Again,)38 b(ice)e(0)f(w)n(as)2042 2877 y(observ)n(ed)23 |
| 627417 |
> |
b(to)i(ha)n(v)n(e)f(the)h(lo)n(w)n(est)f(total)h(system)g(energy)-7 |
| 627418 |
> |
b(.)35 b(The)25 b(to-)2042 2972 y(tal)c(energy)e(of)i(ice)g(0)f(w)n(as) |
| 627419 |
> |
41 b(2\045)21 b(lo)n(w)n(er)e(than)i(ice)g Fj(I)3543 |
| 627420 |
> |
2984 y Fi(h)3586 2972 y Fu(,)h(whic)n(h)f(w)n(as)f(in)2042 |
| 627421 |
> |
3068 y(turn)50 b(3\045)25 b(lo)n(w)n(er)e(than)i(ice)g |
| 627422 |
> |
Fj(I)2948 3080 y Fi(c)2983 3068 y Fu(.)36 b(F)-7 b(rom)24 |
| 627423 |
> |
b(these)h(initial)h(results,)f(w)n(e)2042 3163 y(w)n(ould)g(not)h(b)r |
| 627424 |
|
(e)g(surprised)e(if)i(results)f(from)h(the)g(other)f(common)2042 |
| 627425 |
< |
4628 y(w)n(ater)35 b(mo)r(dels)i(sho)n(w)e(ice)i(0)f(to)g(b)r(e)h(the)g |
| 627426 |
< |
(lo)n(w)n(est)e(energy)g(crys-)2042 4724 y(tal)26 b(structure.)36 |
| 627425 |
> |
3259 y(w)n(ater)35 b(mo)r(dels)i(sho)n(w)e(ice)i(0)f(to)g(b)r(e)h(the)g |
| 627426 |
> |
(lo)n(w)n(est)e(energy)g(crys-)2042 3354 y(tal)26 b(structure.)36 |
| 627427 |
|
b(A)27 b(con)n(tin)n(uation)f(on)g(w)n(ork)f(studing)h(ice)h(0)f(with) |
| 627428 |
< |
2042 4819 y(m)n(ultip)r(oin)n(t)35 b(w)n(ater)f(mo)r(dels)h(will)g(b)r |
| 627429 |
< |
(e)g(published)g(in)g(a)g(coming)2042 4915 y(article.)p |
| 627430 |
< |
eop |
| 627428 |
> |
2042 3450 y(m)n(ultip)r(oin)n(t)35 b(w)n(ater)f(mo)r(dels)h(will)g(b)r |
| 627429 |
> |
(e)g(published)g(in)g(a)g(coming)2042 3545 y(article.)2631 |
| 627430 |
> |
3821 y Fo(IV.)88 b(CONCLUSIONS)2125 4035 y Fu(The)49 |
| 627431 |
> |
b(densit)n(y)g(maxim)n(um)f(and)h(temp)r(erature)g(dep)r(enden)n(t)2042 |
| 627432 |
> |
4130 y(transp)r(ort)25 b(for)h(the)g(SSD)h(w)n(ater)e(mo)r(del,)i(b)r |
| 627433 |
> |
(oth)f(with)h(and)f(with-)2042 4226 y(out)j(the)g(use)g(of)g(reaction)e |
| 627434 |
> |
(\014eld,)j(w)n(ere)e(studied)h(via)g(a)f(series)g(of)2042 |
| 627435 |
> |
4321 y(NPT)h(and)g(NVE)g(sim)n(ulations.)41 b(The)29 |
| 627436 |
> |
b(constan)n(t)g(pressure)e(sim-)2042 4417 y(ulations)34 |
| 627437 |
> |
b(of)h(the)h(melting)f(of)g(b)r(oth)g Fj(I)3264 4429 |
| 627438 |
> |
y Fi(h)3343 4417 y Fu(and)g Fj(I)3548 4429 y Fi(c)3617 |
| 627439 |
> |
4417 y Fu(ice)g(sho)n(w)n(ed)f(a)2042 4512 y(densit)n(y)c(maxim)n(um)f |
| 627440 |
> |
(near)h(260)e(K.)i(In)g(most)g(cases,)g(the)g(calcu-)2042 |
| 627441 |
> |
4608 y(lated)25 b(densities)f(w)n(ere)g(signi\014can)n(tly)g(lo)n(w)n |
| 627442 |
> |
(er)f(than)i(the)g(densities)2042 4703 y(calculated)k(in)h(sim)n |
| 627443 |
> |
(ulations)f(of)h(other)f(w)n(ater)g(mo)r(dels.)44 b(Analy-)2042 |
| 627444 |
> |
4799 y(sis)24 b(of)g(particle)f(di\013usion)i(sho)n(w)n(ed)e(SSD)i(to)f |
| 627445 |
> |
(capture)g(the)g(trans-)2042 4894 y(p)r(ort)d(prop)r(erties)f(of)i(exp) |
| 627446 |
> |
r(erimen)n(tal)f(v)n(ery)f(w)n(ell)h(in)h(b)r(oth)g(the)f(nor-)2042 |
| 627447 |
> |
4990 y(mal)27 b(and)h(sup)r(er-co)r(oled)e(liquid)i(regimes.)37 |
| 627448 |
> |
b(In)28 b(order)e(to)i(correct)2042 5085 y(the)35 b(densit)n(y)g(b)r |
| 627449 |
> |
(eha)n(vior,)h(SSD)g(w)n(as)e(reparameterized)g(for)g(use)2042 |
| 627450 |
> |
5180 y(b)r(oth)h(with)g(and)f(without)h(a)f(long-range)f(in)n |
| 627451 |
> |
(teraction)g(correc-)2042 5276 y(tion,)39 b(SSD/RF)e(and)f(SSD/E)g |
| 627452 |
> |
(resp)r(ectiv)n(ely)-7 b(.)63 b(In)37 b(addition)f(to)2042 |
| 627453 |
> |
5371 y(correcting)c(the)h(abnormally)g(lo)n(w)f(densities,)j(these)f |
| 627454 |
> |
(new)g(v)n(er-)p eop |
| 627455 |
|
%%Page: 11 11 |
| 627456 |
< |
11 10 bop 4001 -299 a Fu(11)439 -83 y Fo(IV.)88 b(CONCLUSIONS)-67 |
| 627457 |
< |
131 y Fu(The)49 b(densit)n(y)g(maxim)n(um)f(and)h(temp)r(erature)g(dep) |
| 627458 |
< |
r(enden)n(t)-150 226 y(transp)r(ort)25 b(for)h(the)g(SSD)h(w)n(ater)e |
| 627459 |
< |
(mo)r(del,)i(b)r(oth)g(with)f(and)g(with-)-150 322 y(out)j(the)g(use)g |
| 635838 |
< |
(of)g(reaction)f(\014eld,)h(w)n(ere)f(studied)i(via)e(a)h(series)e(of) |
| 635839 |
< |
-150 417 y(NPT)i(and)g(NVE)g(sim)n(ulations.)41 b(The)29 |
| 635840 |
< |
b(constan)n(t)g(pressure)f(sim-)-150 512 y(ulations)34 |
| 635841 |
< |
b(of)h(the)h(melting)f(of)g(b)r(oth)g Fj(I)1072 524 y |
| 635842 |
< |
Fi(h)1151 512 y Fu(and)g Fj(I)1356 524 y Fi(c)1425 512 |
| 635843 |
< |
y Fu(ice)g(sho)n(w)n(ed)f(a)-150 608 y(densit)n(y)c(maxim)n(um)g(near)f |
| 635844 |
< |
(260)f(K.)i(In)g(most)g(cases,)g(the)g(calcu-)-150 703 |
| 635845 |
< |
y(lated)25 b(densities)g(w)n(ere)e(signi\014can)n(tly)h(lo)n(w)n(er)f |
| 635846 |
< |
(than)i(the)g(densities)-150 799 y(calculated)k(in)h(sim)n(ulations)f |
| 635847 |
< |
(of)h(other)g(w)n(ater)e(mo)r(dels.)44 b(Analy-)-150 |
| 635848 |
< |
894 y(sis)24 b(of)g(particle)g(di\013usion)g(sho)n(w)n(ed)f(SSD)i(to)f |
| 635849 |
< |
(capture)g(the)g(trans-)-150 990 y(p)r(ort)d(prop)r(erties)g(of)g(exp)r |
| 635850 |
< |
(erimen)n(tal)g(v)n(ery)f(w)n(ell)h(in)h(b)r(oth)g(the)g(nor-)-150 |
| 635851 |
< |
1085 y(mal)28 b(and)f(sup)r(er-co)r(oled)g(liquid)h(regimes.)36 |
| 635852 |
< |
b(In)28 b(order)e(to)i(correct)-150 1181 y(the)36 b(densit)n(y)f(b)r |
| 635853 |
< |
(eha)n(vior,)h(SSD)f(w)n(as)g(reparameterized)e(for)i(use)-150 |
| 635854 |
< |
1276 y(b)r(oth)g(with)g(and)g(without)g(a)f(long-range)e(in)n |
| 635855 |
< |
(teraction)h(correc-)-150 1372 y(tion,)39 b(SSD/RF)e(and)f(SSD/E)h |
| 635856 |
< |
(resp)r(ectiv)n(ely)-7 b(.)62 b(In)37 b(addition)g(to)-150 |
| 635857 |
< |
1467 y(correcting)32 b(the)i(abnormally)e(lo)n(w)h(densities,)i(these)e |
| 635858 |
< |
(new)h(v)n(er-)-150 1563 y(sions)28 b(w)n(ere)f(sho)n(w)h(to)g(main)n |
| 635859 |
< |
(tain)g(or)g(impro)n(v)n(e)f(up)r(on)i(the)f(trans-)-150 |
| 635860 |
< |
1658 y(p)r(ort)f(and)f(structural)h(features)f(of)h(the)g(original)e(w) |
| 635861 |
< |
n(ater)h(mo)r(del,)-150 1754 y(all)19 b(while)h(main)n(taining)e(the)i |
| 627456 |
> |
11 10 bop 4001 -299 a Fu(11)-150 -83 y(sions)28 b(w)n(ere)f(sho)n(w)h |
| 627457 |
> |
(to)g(main)n(tain)g(or)g(impro)n(v)n(e)f(up)r(on)i(the)f(trans-)-150 |
| 627458 |
> |
12 y(p)r(ort)f(and)f(structural)h(features)f(of)h(the)g(original)e(w)n |
| 627459 |
> |
(ater)h(mo)r(del,)-150 108 y(all)19 b(while)h(main)n(taining)e(the)i |
| 627460 |
|
(fast)f(p)r(erformance)f(of)i(the)f(SSD)i(w)n(a-)-150 |
| 627461 |
< |
1849 y(ter)30 b(mo)r(del.)46 b(This)30 b(w)n(ork)f(sho)n(ws)g(these)i |
| 627462 |
< |
(simple)f(w)n(ater)f(mo)r(dels,)-150 1945 y(and)36 b(in)g(particular)f |
| 627461 |
> |
203 y(ter)30 b(mo)r(del.)46 b(This)30 b(w)n(ork)f(sho)n(ws)g(these)i |
| 627462 |
> |
(simple)f(w)n(ater)f(mo)r(dels,)-150 299 y(and)36 b(in)g(particular)f |
| 627463 |
|
(SSD/E)g(and)h(SSD/RF,)h(to)e(b)r(e)i(excellen)n(t)-150 |
| 627464 |
< |
2040 y(c)n(hoices)31 b(to)g(represen)n(t)g(explicit)h(w)n(ater)e(in)i |
| 627465 |
< |
(future)g(sim)n(ulations)-150 2136 y(of)c(bio)r(c)n(hemical)f(systems.) |
| 627466 |
< |
286 2412 y Fo(V.)87 b(A)n(CKNO)n(WLEDGMENTS)-67 2625 |
| 627467 |
< |
y Fu(The)29 b(authors)f(w)n(ould)g(lik)n(e)g(to)h(thank)g(the)g |
| 627468 |
< |
(National)f(Science)-150 2721 y(F)-7 b(oundation)21 b(for)f(funding)h |
| 627469 |
< |
(under)g(gran)n(t)e(CHE-0134881.)31 b(Com-)-150 2816 |
| 627470 |
< |
y(putation)19 b(time)h(w)n(as)e(pro)n(vided)g(b)n(y)g(the)i(Notre)e |
| 627471 |
< |
(Dame)h(Bunc)n(h-of-)-150 2912 y(Bo)n(xes)29 b(\(B.o.B\))i(computer)g |
| 627472 |
< |
(cluster)f(under)h(NSF)g(gran)n(t)f(DMR)-150 3007 y(00)d(79647.)570 |
| 627473 |
< |
3283 y Fo(REFERENCES)-117 3467 y Fn(1)-46 3497 y Fu(W.)39 |
| 627464 |
> |
394 y(c)n(hoices)31 b(to)g(represen)n(t)g(explicit)h(w)n(ater)e(in)i |
| 627465 |
> |
(future)g(sim)n(ulations)-150 490 y(of)c(bio)r(c)n(hemical)f(systems.) |
| 627466 |
> |
286 766 y Fo(V.)87 b(A)n(CKNO)n(WLEDGMENTS)-67 980 y |
| 627467 |
> |
Fu(Supp)r(ort)27 b(for)g(this)g(pro)5 b(ject)26 b(w)n(as)g(pro)n(vided) |
| 627468 |
> |
g(b)n(y)h(the)g(National)-150 1075 y(Science)i(F)-7 b(oundation)29 |
| 627469 |
> |
b(under)g(gran)n(t)e(CHE-0134881.)38 b(Compu-)-150 1171 |
| 627470 |
> |
y(tation)30 b(time)h(w)n(as)f(pro)n(vided)f(b)n(y)i(the)g(Notre)f(Dame) |
| 627471 |
> |
g(Bunc)n(h-of-)-150 1266 y(Bo)n(xes)f(\(B.o.B\))i(computer)g(cluster)f |
| 627472 |
> |
(under)h(NSF)g(gran)n(t)f(DMR)-150 1361 y(00)d(79647.)570 |
| 627473 |
> |
1638 y Fo(REFERENCES)-117 1821 y Fn(1)-46 1851 y Fu(W.)39 |
| 627474 |
|
b(L.)g(Jorgensen,)h(J.)f(Chandrasekhar,)h(J.)f(D.)g(Madura,)-46 |
| 627475 |
< |
3592 y(R.)c(W.)h(Imp)r(ey)-7 b(,)38 b(and)d(M.)g(L.)h(Klein,)h(J.)e |
| 627476 |
< |
(Chem.)g(Ph)n(ys.)g Fh(79)p Fu(,)-46 3688 y(926)26 b(\(1983\).)-117 |
| 627477 |
< |
3753 y Fn(2)-46 3783 y Fu(H.)62 b(J.)f(C.)h(Berendsen,)69 |
| 627475 |
> |
1947 y(R.)c(W.)h(Imp)r(ey)-7 b(,)38 b(and)d(M.)g(L.)h(Klein,)h(J.)e |
| 627476 |
> |
(Chem.)g(Ph)n(ys.)g Fh(79)p Fu(,)-46 2042 y(926)26 b(\(1983\).)-117 |
| 627477 |
> |
2107 y Fn(2)-46 2138 y Fu(H.)62 b(J.)f(C.)h(Berendsen,)69 |
| 627478 |
|
b(J.)62 b(R.)g(Grigera,)68 b(and)62 b(T.)g(P)-7 b(.)-46 |
| 627479 |
< |
3879 y(Straatsma,)26 b(J.)h(Ph)n(ys.)g(Chem.)h Fh(91)p |
| 627480 |
< |
Fu(,)f(6269)f(\(1987\).)-117 3944 y Fn(3)-46 3974 y Fu(M.)c(W.)h |
| 627479 |
> |
2233 y(Straatsma,)26 b(J.)h(Ph)n(ys.)g(Chem.)h Fh(91)p |
| 627480 |
> |
Fu(,)f(6269)f(\(1987\).)-117 2298 y Fn(3)-46 2329 y Fu(M.)c(W.)h |
| 627481 |
|
(Mahoney)e(and)h(W.)g(L.)h(Jorgensen,)e(J.)h(Chem.)g(Ph)n(ys.)-46 |
| 627482 |
< |
4070 y Fh(112)p Fu(\(20\),)k(8910)g(\(2000\).)-117 4135 |
| 627483 |
< |
y Fn(4)-46 4165 y Fu(M.)c(W.)h(Mahoney)e(and)h(W.)g(L.)h(Jorgensen,)e |
| 627484 |
< |
(J.)h(Chem.)g(Ph)n(ys.)-46 4261 y Fh(114)p Fu(\(1\),)27 |
| 627485 |
< |
b(363)f(\(2001\).)-117 4326 y Fn(5)-46 4356 y Fu(Y.)19 |
| 627482 |
> |
2424 y Fh(112)p Fu(\(20\),)k(8910)g(\(2000\).)-117 2489 |
| 627483 |
> |
y Fn(4)-46 2520 y Fu(M.)c(W.)h(Mahoney)e(and)h(W.)g(L.)h(Jorgensen,)e |
| 627484 |
> |
(J.)h(Chem.)g(Ph)n(ys.)-46 2615 y Fh(114)p Fu(\(1\),)27 |
| 627485 |
> |
b(363)f(\(2001\).)-117 2680 y Fn(5)-46 2710 y Fu(Y.)19 |
| 627486 |
|
b(Liu)g(and)g(T.)g(Ic)n(hiy)n(e,)h(J.)e(Ph)n(ys.)g(Chem.)i |
| 627487 |
< |
Fh(100)p Fu(,)g(2723)d(\(1996\).)-117 4422 y Fn(6)-46 |
| 627488 |
< |
4452 y Fu(D.)36 b(Bratk)n(o,)h(L.)f(Blum,)j(and)d(A.)h(Luzar,)h(J.)e |
| 627489 |
< |
(Chem.)g(Ph)n(ys.)-46 4547 y Fh(83)p Fu(\(12\),)26 b(6367)g(\(1985\).) |
| 627490 |
< |
2075 -113 y Fn(7)2145 -83 y Fu(L.)32 b(Blum,)i(F.)e(V)-7 |
| 627491 |
< |
b(ericat,)33 b(and)f(D.)h(Bratk)n(o,)e(J.)h(Chem.)g(Ph)n(ys.)2145 |
| 627492 |
< |
12 y Fh(102)p Fu(\(3\),)27 b(1461)f(\(1995\).)2075 78 |
| 627493 |
< |
y Fn(8)2145 108 y Fu(A.)40 b(Chandra)d(and)i(T.)g(Ic)n(hiy)n(e,)i(J.)e |
| 627494 |
< |
(Chem.)g(Ph)n(ys.)f Fh(111)p Fu(\(6\),)2145 203 y(2701)26 |
| 627495 |
< |
b(\(1999\).)2075 269 y Fn(9)2145 299 y Fu(C.)46 b(Sagui)e(and)h(T.)g |
| 627496 |
< |
(A.)h(Darden,)j(Ann)n(u.)d(Rev.)f(Bioph)n(ys.)2145 394 |
| 627497 |
< |
y(Biomol.)27 b(Struct.)h Fh(28)p Fu(,)f(155)g(\(1999\).)2042 |
| 627498 |
< |
460 y Fn(10)2145 490 y Fu(M.-L.)k(T)-7 b(an,)31 b(J.)f(T.)g(Fisc)n |
| 627499 |
< |
(her,)h(A.)g(Chandra,)f(B.)g(R.)h(Bro)r(oks,)2145 585 |
| 627500 |
< |
y(and)d(T.)f(Ic)n(hiy)n(e,)g(Chem.)h(Ph)n(ys.)f(Lett.)h |
| 627501 |
< |
Fh(376)p Fu(,)f(646)f(\(2003\).)2042 651 y Fn(11)2145 |
| 627502 |
< |
681 y Fu(M.)f(P)-7 b(.)24 b(Allen)h(and)g(D.)g(J.)f(Tildesley)-7 |
| 627503 |
< |
b(,)25 b Fm(Computer)j(Simulation)2145 776 y(of)d(Liquids)k |
| 627487 |
> |
Fh(100)p Fu(,)g(2723)d(\(1996\).)-117 2776 y Fn(6)-46 |
| 627488 |
> |
2806 y Fu(D.)36 b(Bratk)n(o,)h(L.)f(Blum,)j(and)d(A.)h(Luzar,)h(J.)e |
| 627489 |
> |
(Chem.)g(Ph)n(ys.)-46 2901 y Fh(83)p Fu(\(12\),)26 b(6367)g(\(1985\).) |
| 627490 |
> |
-117 2967 y Fn(7)-46 2997 y Fu(L.)32 b(Blum,)h(F.)f(V)-7 |
| 627491 |
> |
b(ericat,)33 b(and)f(D.)h(Bratk)n(o,)e(J.)h(Chem.)g(Ph)n(ys.)-46 |
| 627492 |
> |
3092 y Fh(102)p Fu(\(3\),)27 b(1461)e(\(1995\).)-117 |
| 627493 |
> |
3158 y Fn(8)-46 3188 y Fu(A.)39 b(Chandra)f(and)g(T.)h(Ic)n(hiy)n(e,)i |
| 627494 |
> |
(J.)e(Chem.)g(Ph)n(ys.)f Fh(111)p Fu(\(6\),)-46 3283 |
| 627495 |
> |
y(2701)25 b(\(1999\).)-117 3349 y Fn(9)-46 3379 y Fu(C.)45 |
| 627496 |
> |
b(Sagui)f(and)h(T.)h(A.)f(Darden,)50 b(Ann)n(u.)45 b(Rev.)g(Bioph)n |
| 627497 |
> |
(ys.)-46 3474 y(Biomol.)26 b(Struct.)i Fh(28)p Fu(,)g(155)e(\(1999\).) |
| 627498 |
> |
-150 3540 y Fn(10)-46 3570 y Fu(M.-L.)k(T)-7 b(an,)31 |
| 627499 |
> |
b(J.)f(T.)h(Fisc)n(her,)f(A.)h(Chandra,)f(B.)g(R.)h(Bro)r(oks,)-46 |
| 627500 |
> |
3665 y(and)c(T.)h(Ic)n(hiy)n(e,)f(Chem.)g(Ph)n(ys.)g(Lett.)h |
| 627501 |
> |
Fh(376)p Fu(,)f(646)f(\(2003\).)2042 -113 y Fn(11)2145 |
| 627502 |
> |
-83 y Fu(M.)f(P)-7 b(.)24 b(Allen)h(and)g(D.)g(J.)f(Tildesley)-7 |
| 627503 |
> |
b(,)25 b Fm(Computer)j(Simulation)2145 12 y(of)d(Liquids)k |
| 627504 |
|
Fu(\(Oxford)20 b(Univ)n(ersit)n(y)g(Press,)h(New)g(Y)-7 |
| 627505 |
< |
b(ork,)22 b(1987\).)2042 842 y Fn(12)2145 872 y Fu(D.)42 |
| 627505 |
> |
b(ork,)22 b(1987\).)2042 78 y Fn(12)2145 108 y Fu(D.)42 |
| 627506 |
|
b(v)-5 b(an)41 b(der)f(Sp)r(o)r(el,)45 b(P)-7 b(.)41 |
| 627507 |
|
b(J.)f(v)-5 b(an)41 b(Maaren,)i(and)e(H.)g(J.)g(C.)2145 |
| 627508 |
< |
967 y(Berendsen,)27 b(J.)h(Chem.)g(Ph)n(ys.)e Fh(111)p |
| 627509 |
< |
Fu(\(6\),)h(10220)e(\(1998\).)2042 1033 y Fn(13)2145 |
| 627510 |
< |
1063 y Fu(W.)j(G.)g(Ho)r(o)n(v)n(er,)e(Ph)n(ys.)h(Rev.)g(A)h |
| 627511 |
< |
Fh(31)p Fu(\(3\),)g(1695)d(\(1985\).)2042 1128 y Fn(14)2145 |
| 627512 |
< |
1158 y Fu(W.)j(G.)g(Ho)r(o)n(v)n(er,)e(Ph)n(ys.)h(Rev.)g(A)h |
| 627513 |
< |
Fh(34)p Fu(\(3\),)g(2499)d(\(1986\).)2042 1224 y Fn(15)2145 |
| 627514 |
< |
1254 y Fu(A.)35 b(Dullw)n(eb)r(er,)h(B.)d(Leimkuhler,)j(and)e(R.)g |
| 627515 |
< |
(McLac)n(hlan,)g(J.)2145 1349 y(Chem.)28 b(Ph)n(ys.)f |
| 627516 |
< |
Fh(107)p Fu(\(15\),)f(5840)g(\(1997\).)2042 1414 y Fn(16)2145 |
| 627517 |
< |
1445 y Fu(A.)31 b(Kol,)f(B.)g(B.)g(Laird,)g(and)g(B.)g(J.)g |
| 627518 |
< |
(Leimkuhler,)h(J.)f(Chem.)2145 1540 y(Ph)n(ys.)d Fh(107)p |
| 627519 |
< |
Fu(\(7\),)g(2580)f(\(1997\).)2042 1605 y Fn(17)2145 1636 |
| 627520 |
< |
y Fu(J.)g(D.)g(Bernal)f(and)h(R.)g(H.)g(F)-7 b(o)n(wler,)26 |
| 627521 |
< |
b(J.)f(Chem.)i(Ph)n(ys.)d Fh(1)p Fu(,)j(515)2145 1731 |
| 627522 |
< |
y(\(1933\).)2042 1796 y Fn(18)2145 1826 y Fu(A.)20 b(Rahman)f(and)g(F.) |
| 627523 |
< |
g(H.)h(Stillinger,)h(J.)e(Chem.)g(Ph)n(ys.)g Fh(57)p |
| 627524 |
< |
Fu(\(9\),)2145 1922 y(4009)26 b(\(1972\).)2042 1987 y |
| 627525 |
< |
Fn(19)2145 2017 y Fu(W.)37 b(L.)f(Jorgensen)f(and)h(C.)g(Jenson,)i(J.)e |
| 627526 |
< |
(Comput.)h(Chem.)2145 2113 y Fh(19)p Fu(\(10\),)27 b(1179)f(\(1998\).) |
| 627527 |
< |
2042 2178 y Fn(20)2145 2208 y Fu(L.)35 b(A.)g(B\023)-42 |
| 627528 |
< |
b(aez)34 b(and)h(P)-7 b(.)35 b(Clancy)-7 b(,)36 b(J.)e(Chem.)h(Ph)n |
| 627529 |
< |
(ys.)f Fh(101)p Fu(\(11\),)2145 2304 y(9837)26 b(\(1994\).)2042 |
| 627530 |
< |
2369 y Fn(21)2145 2399 y Fu(R.)37 b(C.)g(W)-7 b(east,)39 |
| 627531 |
< |
b(ed.,)h Fm(CR)n(C)e(Handb)l(o)l(ok)h(of)g(Chemistry)h(and)2145 |
| 627532 |
< |
2495 y(Physics)50 b Fu(\(CR)n(C)41 b(Press,)j(Inc.,)h(Bo)r(ca)40 |
| 627533 |
< |
b(Raton,)k(FL,)e(1980\),)2145 2590 y(60th)27 b(ed.)2042 |
| 627534 |
< |
2656 y Fn(22)2145 2686 y Fu(Gillen,)33 b(Douglas,)f(and)f(Ho)r(c)n(h,)h |
| 627535 |
< |
(J.)g(Chem.)g(Ph)n(ys.)e Fh(57)p Fu(,)i(5117)2145 2781 |
| 627536 |
< |
y(\(1972\).)2042 2847 y Fn(23)2145 2877 y Fu(R.)c(Mills,)g(J.)f(Ph)n |
| 627537 |
< |
(ys.)g(Chem.)h Fh(77)p Fu(\(5\),)f(685)f(\(1973\).)2042 |
| 627538 |
< |
2942 y Fn(24)2145 2972 y Fu(G.)d(Hura,)g(J.)f(M.)h(Sorenson,)f(R.)g(M.) |
| 627539 |
< |
h(Glaeser,)f(and)g(T.)h(Head-)2145 3068 y(Gordon,)k(J.)g(Chem.)h(Ph)n |
| 627540 |
< |
(ys.)f Fh(113)p Fu(\(20\),)f(9140)g(\(2000\).)2042 3133 |
| 627541 |
< |
y Fn(25)2145 3163 y Fu(A.)h(K.)e(Sop)r(er)h(and)g(M.)g(G.)g(Phillips,)g |
| 627542 |
< |
(Chem.)h(Ph)n(ys.)e Fh(107)p Fu(\(1\),)2145 3259 y(47)i(\(1986\).)2042 |
| 627543 |
< |
3324 y Fn(26)2145 3354 y Fu(M.)h(Sprik,)g(J.)f(Chem.)h(Ph)n(ys.)e |
| 627544 |
< |
Fh(95)p Fu(\(9\),)i(6762)d(\(1991\).)2042 3419 y Fn(27)2145 |
| 627545 |
< |
3450 y Fu(A.)36 b(V.)g(Gubsk)-5 b(a)n(y)n(a)35 b(and)g(P)-7 |
| 627546 |
< |
b(.)35 b(G.)h(Kusalik,)h(J.)e(Chem.)h(Ph)n(ys.)2145 3545 |
| 627547 |
< |
y Fh(117)p Fu(\(11\),)27 b(5290)f(\(2002\).)2042 3610 |
| 627548 |
< |
y Fn(28)2145 3641 y Fu(Y.)e(S.)f(Bady)n(al,)g(M.)g(L.)g(Sab)r(oungi,)g |
| 627549 |
< |
(D.)h(L.)f(Price,)g(S.)g(D.)h(Shas-)2145 3736 y(tri,)30 |
| 627508 |
> |
203 y(Berendsen,)27 b(J.)h(Chem.)g(Ph)n(ys.)e Fh(111)p |
| 627509 |
> |
Fu(\(6\),)h(10220)e(\(1998\).)2042 269 y Fn(13)2145 299 |
| 627510 |
> |
y Fu(W.)j(G.)g(Ho)r(o)n(v)n(er,)e(Ph)n(ys.)h(Rev.)g(A)h |
| 627511 |
> |
Fh(31)p Fu(\(3\),)g(1695)d(\(1985\).)2042 364 y Fn(14)2145 |
| 627512 |
> |
394 y Fu(W.)j(G.)g(Ho)r(o)n(v)n(er,)e(Ph)n(ys.)h(Rev.)g(A)h |
| 627513 |
> |
Fh(34)p Fu(\(3\),)g(2499)d(\(1986\).)2042 460 y Fn(15)2145 |
| 627514 |
> |
490 y Fu(A.)35 b(Dullw)n(eb)r(er,)h(B.)d(Leimkuhler,)j(and)e(R.)g |
| 627515 |
> |
(McLac)n(hlan,)g(J.)2145 585 y(Chem.)28 b(Ph)n(ys.)f |
| 627516 |
> |
Fh(107)p Fu(\(15\),)f(5840)g(\(1997\).)2042 651 y Fn(16)2145 |
| 627517 |
> |
681 y Fu(A.)31 b(Kol,)f(B.)g(B.)g(Laird,)g(and)g(B.)g(J.)g(Leimkuhler,) |
| 627518 |
> |
h(J.)f(Chem.)2145 776 y(Ph)n(ys.)d Fh(107)p Fu(\(7\),)g(2580)f |
| 627519 |
> |
(\(1997\).)2042 842 y Fn(17)2145 872 y Fu(J.)g(D.)g(Bernal)f(and)h(R.)g |
| 627520 |
> |
(H.)g(F)-7 b(o)n(wler,)26 b(J.)f(Chem.)i(Ph)n(ys.)d Fh(1)p |
| 627521 |
> |
Fu(,)j(515)2145 967 y(\(1933\).)2042 1033 y Fn(18)2145 |
| 627522 |
> |
1063 y Fu(A.)20 b(Rahman)f(and)g(F.)g(H.)h(Stillinger,)h(J.)e(Chem.)g |
| 627523 |
> |
(Ph)n(ys.)g Fh(57)p Fu(\(9\),)2145 1158 y(4009)26 b(\(1972\).)2042 |
| 627524 |
> |
1224 y Fn(19)2145 1254 y Fu(W.)37 b(L.)f(Jorgensen)f(and)h(C.)g |
| 627525 |
> |
(Jenson,)i(J.)e(Comput.)h(Chem.)2145 1349 y Fh(19)p Fu(\(10\),)27 |
| 627526 |
> |
b(1179)f(\(1998\).)2042 1414 y Fn(20)2145 1445 y Fu(L.)35 |
| 627527 |
> |
b(A.)g(B\023)-42 b(aez)34 b(and)h(P)-7 b(.)35 b(Clancy)-7 |
| 627528 |
> |
b(,)36 b(J.)e(Chem.)h(Ph)n(ys.)f Fh(101)p Fu(\(11\),)2145 |
| 627529 |
> |
1540 y(9837)26 b(\(1994\).)2042 1605 y Fn(21)2145 1636 |
| 627530 |
> |
y Fu(R.)37 b(C.)g(W)-7 b(east,)39 b(ed.,)h Fm(CR)n(C)e(Handb)l(o)l(ok)h |
| 627531 |
> |
(of)g(Chemistry)h(and)2145 1731 y(Physics)50 b Fu(\(CR)n(C)41 |
| 627532 |
> |
b(Press,)j(Inc.,)h(Bo)r(ca)40 b(Raton,)k(FL,)e(1980\),)2145 |
| 627533 |
> |
1826 y(60th)27 b(ed.)2042 1892 y Fn(22)2145 1922 y Fu(Gillen,)33 |
| 627534 |
> |
b(Douglas,)f(and)f(Ho)r(c)n(h,)h(J.)g(Chem.)g(Ph)n(ys.)e |
| 627535 |
> |
Fh(57)p Fu(,)i(5117)2145 2017 y(\(1972\).)2042 2083 y |
| 627536 |
> |
Fn(23)2145 2113 y Fu(R.)c(Mills,)g(J.)f(Ph)n(ys.)g(Chem.)h |
| 627537 |
> |
Fh(77)p Fu(\(5\),)f(685)f(\(1973\).)2042 2178 y Fn(24)2145 |
| 627538 |
> |
2208 y Fu(G.)d(Hura,)g(J.)f(M.)h(Sorenson,)f(R.)g(M.)h(Glaeser,)f(and)g |
| 627539 |
> |
(T.)h(Head-)2145 2304 y(Gordon,)k(J.)g(Chem.)h(Ph)n(ys.)f |
| 627540 |
> |
Fh(113)p Fu(\(20\),)f(9140)g(\(2000\).)2042 2369 y Fn(25)2145 |
| 627541 |
> |
2399 y Fu(A.)h(K.)e(Sop)r(er)h(and)g(M.)g(G.)g(Phillips,)g(Chem.)h(Ph)n |
| 627542 |
> |
(ys.)e Fh(107)p Fu(\(1\),)2145 2495 y(47)i(\(1986\).)2042 |
| 627543 |
> |
2560 y Fn(26)2145 2590 y Fu(M.)h(Sprik,)g(J.)f(Chem.)h(Ph)n(ys.)e |
| 627544 |
> |
Fh(95)p Fu(\(9\),)i(6762)d(\(1991\).)2042 2656 y Fn(27)2145 |
| 627545 |
> |
2686 y Fu(A.)36 b(V.)g(Gubsk)-5 b(a)n(y)n(a)35 b(and)g(P)-7 |
| 627546 |
> |
b(.)35 b(G.)h(Kusalik,)h(J.)e(Chem.)h(Ph)n(ys.)2145 2781 |
| 627547 |
> |
y Fh(117)p Fu(\(11\),)27 b(5290)f(\(2002\).)2042 2847 |
| 627548 |
> |
y Fn(28)2145 2877 y Fu(Y.)e(S.)f(Bady)n(al,)g(M.)g(L.)g(Sab)r(oungi,)g |
| 627549 |
> |
(D.)h(L.)f(Price,)g(S.)g(D.)h(Shas-)2145 2972 y(tri,)30 |
| 627550 |
|
b(D.)g(R.)f(Hae\013ner,)g(and)g(A.)h(K.)f(Sop)r(er,)g(J.)g(Chem.)g(Ph)n |
| 627551 |
< |
(ys.)2145 3831 y Fh(112)p Fu(\(21\),)e(9206)f(\(2000\).)2042 |
| 627552 |
< |
3897 y Fn(29)2145 3927 y Fu(J.)c(Barriol)d(and)j(A.)g(W)-7 |
| 627551 |
> |
(ys.)2145 3068 y Fh(112)p Fu(\(21\),)e(9206)f(\(2000\).)2042 |
| 627552 |
> |
3133 y Fn(29)2145 3163 y Fu(J.)c(Barriol)d(and)j(A.)g(W)-7 |
| 627553 |
|
b(eisb)r(ec)n(k)n(er,)22 b(Compt.)g(Rend.)g(Acad.)f(Sc.)2145 |
| 627554 |
< |
4022 y(P)n(aris)26 b Fh(259)p Fu(,)h(4643)f(\(1964\).)2042 |
| 627555 |
< |
4088 y Fn(30)2145 4118 y Fu(B.)32 b(R.)g(Bro)r(oks,)g(R.)g(E.)f |
| 627556 |
< |
(Bruccoleri,)h(B.)g(D.)g(Olafson,)g(D.)g(J.)2145 4213 |
| 627554 |
> |
3259 y(P)n(aris)26 b Fh(259)p Fu(,)h(4643)f(\(1964\).)2042 |
| 627555 |
> |
3324 y Fn(30)2145 3354 y Fu(B.)32 b(R.)g(Bro)r(oks,)g(R.)g(E.)f |
| 627556 |
> |
(Bruccoleri,)h(B.)g(D.)g(Olafson,)g(D.)g(J.)2145 3450 |
| 627557 |
|
y(States,)27 b(S.)f(Sw)n(aminathan,)g(and)g(M.)g(Karplus,)f(J.)h |
| 627558 |
< |
(Comput.)2145 4309 y(Chem.)i Fh(4)p Fu(\(2\),)g(187)e(\(1983\).)p |
| 627558 |
> |
(Comput.)2145 3545 y(Chem.)i Fh(4)p Fu(\(2\),)g(187)e(\(1983\).)p |
| 627559 |
|
eop |
| 627560 |
|
%%Trailer |
| 627561 |
|
end |